Pyrolysis and gasification of coal at high temperatures

Technical Report · Mon Jan 01 00:00:00 EST 1990

DOI:https://doi.org/10.2172/6782637· OSTI ID:6782637

Zygourakis, K

We made considerable progress towards completing the development of a thermogravimetric reactor with video microscopy imaging capabilities (TGA/VMI). The video micrOSCOPY components were designed, installed and are currently under testing. With the newly developed TGA/VNH apparatus we can directly observe macroscopic changes in the morphology of pyrolyzing particles and thermal ignitions of burning particles while simultaneously monitoring the weight of pyrolyzing or reacting samples. The systematic investigation on the effects of pyrolysis conditions and char macropore structure on char reactivity continued. Pyrolysis and gasification experiments were performed consecutively in our TGA reactor and the char reactivity patterns were measured for a wide range of temperatures (400--600[degrees]C). These conditions cover both the kinetic and the diffusion limited regimes. Our results show conclusively that chars produced at high pyrolysis heating rates (and, therefore, having a more open cellular macropore structure) are more reactive and ignite more easily than chars pyrolyzed at low heating rates. These results have been explained using theoretical models. We also investigated for the first time the effect of coal particle size and external mass transfer limitations on the reactivity patterns and ignition behavior of char particles combusted in air. Finally, we used our hot stage reactor to monitor the structural transformations occurring during pyrolysis via a video microscopy system. Pyrolysis experiments were videotaped and particle swelling and the particle ignitions were determined and analyzed using digitized images from these experiments.

• Research Organization: Rice Univ., Houston, TX (United States). Dept. of Chemical Engineering
• Sponsoring Organization: USDOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG22-87PC79930
• OSTI ID: 6782637
• Report Number(s): DOE/PC/79930-T17; ON: DE93007683
• Country of Publication: United States
• Language: English

Related Subjects

01 COAL, LIGNITE, AND PEAT
CHARS
CHEMICAL REACTION KINETICS
GASIFICATION
COAL
PYROLYSIS
COAL GASIFICATION
COAL RANK
IGNITION
MATHEMATICAL MODELS
MICROSCOPY
PARTICLE SIZE
PROGRESS REPORT
SWELLING
TEMPERATURE DEPENDENCE
THERMAL GRAVIMETRIC ANALYSIS
CARBONACEOUS MATERIALS
CHEMICAL ANALYSIS
CHEMICAL REACTIONS
DECOMPOSITION
DOCUMENT TYPES
ENERGY SOURCES
FOSSIL FUELS
FUELS
GRAVIMETRIC ANALYSIS
KINETICS
MATERIALS
PYROLYSIS PRODUCTS
QUANTITATIVE CHEMICAL ANALYSIS
REACTION KINETICS
SIZE
THERMAL ANALYSIS
THERMOCHEMICAL PROCESSES
010409* - Coal
Lignite
& Peat- Pyrolysis & Carbonization- (1987-)
010404 - Coal
Lignite
& Peat- Gasification