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Title: Stabilization of in-tank residual wastes and external-tank soil contamination for the tank focus area, Hanford tank initiative: Applications to the AX Tank Farm

Technical Report ·
DOI:https://doi.org/10.2172/639699· OSTI ID:639699
; ;  [1];  [2]
  1. Sandia National Labs., Albuquerque, NM (United States)
  2. Alliance for Transportation Research, Albuquerque, NM (United States)

A combined engineering and geochemistry approach is recommended for the stabilization of waste in decommissioned tanks and contaminated soils at the AX Tank Farm, Hanford, WA. A two-part strategy of desiccation and gettering is proposed for treatment of the in-tank residual wastes. Dry portland cement and/or fly ash are suggested as an effective and low-cost desiccant for wicking excess moisture from the upper waste layer. Getters work by either ion exchange or phase precipitation to reduce radionuclide concentrations in solution. The authors recommend the use of specific natural and man-made compounds, appropriately proportioned to the unique inventory of each tank. A filler design consisting of multilayered cementitous grout with interlayered sealant horizons should serve to maintain tank integrity and minimize fluid transport to the residual waste form. External tank soil contamination is best mitigated by placement of grouted skirts under and around each tank, together with installation of a cone-shaped permeable reactive barrier beneath the entire tank farm. Actinide release rates are calculated from four tank closure scenarios ranging from no action to a comprehensive stabilization treatment plan (desiccant/getters/grouting/RCRA cap). Although preliminary, these calculations indicate significant reductions in the potential for actinide transport as compared to the no-treatment option.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE Assistant Secretary for Human Resources and Administration, Washington, DC (United States)
DOE Contract Number:
AC04-94AL85000
OSTI ID:
639699
Report Number(s):
SAND-98-1460; ON: DE98003894; TRN: 98:007842
Resource Relation:
Other Information: PBD: Jul 1998
Country of Publication:
United States
Language:
English