Fundamental spectroscopic studies of carbenes and hydrocarbon radicals

Technical Report · Fri May 01 00:00:00 EDT 1992

DOI:https://doi.org/10.2172/5021895· OSTI ID:5021895

Thaddeus, P; Gottlieb, C

This document details activities during this reporting period topics discussed are: The first spectroscopic identification of the HCCCO and DCCCO radicals; detection of new vibrationally excited states of the carbon chain radicals CCH and CCD and the three-membered carbene ring, cyclopropenylidene; determination of an accurate structure of the cumulene carbene H{sub 2}CCC; analysis the hyperfine structure in the SiC radical; and the undertaking of a systematic search for new sulfur bearing radicals.

• Research Organization: Harvard Univ., Cambridge, MA (United States)
• Sponsoring Organization: USDOE; USDOE, Washington, DC (United States)
• DOE Contract Number: FG02-88ER13912
• OSTI ID: 5021895
• Report Number(s): DOE/ER/13912-4; ON: DE92014989
• Country of Publication: United States
• Language: English

Related Subjects

37 INORGANIC
ORGANIC
PHYSICAL AND ANALYTICAL CHEMISTRY
CARBENES
MICROWAVE SPECTRA
RADICALS
ORGANIC SULFUR COMPOUNDS
PROGRESS REPORT
ROTATION-VIBRATION MODEL
SILICON CARBIDES
STRUCTURAL CHEMICAL ANALYSIS
VIBRATIONAL STATES
CARBIDES
CARBON COMPOUNDS
COLLECTIVE MODEL
DOCUMENT TYPES
ENERGY LEVELS
EXCITED STATES
MATHEMATICAL MODELS
NUCLEAR MODELS
ORGANIC COMPOUNDS
SILICON COMPOUNDS
SPECTRA
400201* - Chemical & Physicochemical Properties