Emergent magnetic properties of biphase iron oxide nanorods

Attanayake, S. B.; Chanda, A.; Das, R.; Phan, M. H.; Srikanth, H.

doi:10.1063/9.0000256

Title: Emergent magnetic properties of biphase iron oxide nanorods

Journal Article · Tue Mar 15 00:00:00 EDT 2022 · AIP Advances

DOI:https://doi.org/10.1063/9.0000256· OSTI ID:1979154

^[1]; Chanda, A. ^[1]; Das, R. ^[2];

^[1]; Srikanth, H. ^[1]

University of South Florida, Tampa, FL (United States)
Phenikaa University, Hanoi (Vietnam)

We report on the magnetic properties of biphase iron oxide nanorods (NRs) consisting of ferrimagnetic Fe ₃ O ₄ and antiferromagnetic α-Fe ₂ O ₃ phases. Annealing as-prepared NRs at 250 °C for 5h, significantly improved the crystallinity of the Fe ₃ O ₄ phase and enhanced the volume fraction of the α-Fe ₂ O ₃ phase. Magnetometry data consistently reveal these two magnetically distinct phases, which are not in proximity to each other but separated by a region of disordered spins giving rise to enhanced magnetization at low temperatures when the sample was cooled down from 300 K in the presence of a 1T field to 10 K. This phenomenon which is also known as the pinning effect is much more pronounced in the annealed sample, resulting from the increased volume fraction of the α-Fe ₂ O ₃ phase which could strengthen the interfacial spin frustration between these two phases and enhance the density of disordered spins at the interface.

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Research Organization:: Univ. of South Florida, Tampa, FL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division (MSE); USDOE

Grant/Contract Number:: FG02-07ER46438

OSTI ID:: 1979154

Alternate ID(s):: OSTI ID: 1854954

Journal Information:: AIP Advances, Vol. 12, Issue 3; Conference: 15. Joint MMM-Intermag Conference, New Orleans, LA (United States), 10-14 Jan 2022; ISSN 2158-3226

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Emergent magnetic properties of biphase iron oxide nanorods

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