Photoinduced reversible phase transition in a phenothiazine-based metal-organic framework

Xiao, Zhifeng; Drake, Hannah F.; Day, Gregory S.; Kuszynski, Jason E.; Lin, Hengyu; Xie, Haomiao; Cai, Peiyu; Ryder, Matthew R.; Zhou, Hong-Cai

doi:10.1016/j.xcrp.2022.101074

Title: Photoinduced reversible phase transition in a phenothiazine-based metal-organic framework

Journal Article · Thu Sep 29 00:00:00 EDT 2022 · Cell Reports Physical Science

DOI:https://doi.org/10.1016/j.xcrp.2022.101074· OSTI ID:1897815

Xiao, Zhifeng ^[1]; Drake, Hannah F. ^[2]; Day, Gregory S. ^[2]; Kuszynski, Jason E. ^[3]; Lin, Hengyu ^[1]; Xie, Haomiao ^[1]; Cai, Peiyu ^[1];

^[4];

^[1]

Texas A & M Univ., College Station, TX (United States)
Texas A & M Univ., College Station, TX (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
Texas A & M Univ., College Station, TX (United States); Florida State Univ., Tallahassee, FL (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division

Photoinduced phase transitions in metal-organic frameworks are provoked by structural changes of photoresponsive linkers within the framework under light irradiation. These transitions are rare but fundamentally important as they can bring about light-switchability on a variety of properties of the materials. In this work, phenothiazine as a photoresponsive unit with distinctive photochemical properties is incorporated into a Zn-based metal-organic framework, PCN-401. The structural characterization of PCN-401 revealed a reversible structural transition upon light irradiation. The mechanisms behind the photoinduced phase transition are studied systematically by spectrometric methods and structural stability characterization. Our mechanistic studies successfully showcased how the phenothiazine unit in the framework undergoes structural transformation under light irradiation and how the reversible phase transition leads to the property changes. The findings have emphasized the significance of phenothiazine in photoresponsive materials and can serve as inspiration for the design and understandings of next-generation photoresponsive metal-organic materials.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; Qatar National Research Fund; Oak Ridge Institute for Science and Education (ORISE); Robert A. Welch Foundation

Grant/Contract Number:: AC05-00OR22725; SC0014664; AC02-05CH11231; SC0001015; NPRP9-377-1-080

OSTI ID:: 1897815

Journal Information:: Cell Reports Physical Science, Vol. 3, Issue 10; ISSN 2666-3864

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Photoinduced reversible phase transition in a phenothiazine-based metal-organic framework

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