Triblock Colloids for Directed Self-Assembly

Chen, Qian; Diesel, Erich; Whitmer, Jonathan K.; Bae, Sung Chul; Luijten, Erik; Granick, Steve

doi:10.1021/ja202360g

Title: Triblock Colloids for Directed Self-Assembly

Journal Article · Mon Apr 25 00:00:00 EDT 2011 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/ja202360g· OSTI ID:1876587

Chen, Qian ^[1]; Diesel, Erich ^[1]; Whitmer, Jonathan K. ^[1]; Bae, Sung Chul ^[1]; Luijten, Erik ^[1]; Granick, Steve ^[1]

Univ. of Illinois, Urbana, IL (United States); Northwestern Univ., Evanston, IL (United States)

Methods for functionalizing micrometer-sized colloidal spheres with three or more zones of chemical functionality (ABA or ABC) are described. To produce ABA triblock colloids, we functionalized the north pole, south pole, and equator to produce what we call X, Y, and K functionality according to the number of allowed nearest neighbors and their spatial arrangements. Furthermore, these synthesis methods allowed targeting of various lattice structures whose bonding between neighboring particles in liquid suspension was visualized in situ by optical microscopy.

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Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; National Science Foundation (NSF)

Grant/Contract Number:: FG02-07ER46471; CBET-0853737; DMR-0346914; DMR-1006430

OSTI ID:: 1876587

Journal Information:: Journal of the American Chemical Society, Vol. 133, Issue 20; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Title: Triblock Colloids for Directed Self-Assembly

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