Synthesis, characterization, and utility of trifluoroacetic acid lanthanide precursors for production of varied phase fluorinated lanthanide nanomaterials

Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M.; Treadwell, LaRico J.; Bell, Nelson S.; Cramer, Roger E.; Neville, Michael L.; Stillman, Gregory A. K.; Bingham, Samuel P.

doi:10.1016/j.poly.2017.04.032

Title: Synthesis, characterization, and utility of trifluoroacetic acid lanthanide precursors for production of varied phase fluorinated lanthanide nanomaterials

Journal Article · Wed May 10 00:00:00 EDT 2017 · Polyhedron

DOI:https://doi.org/10.1016/j.poly.2017.04.032· OSTI ID:1871978

Boyle, Timothy J. ^[1]; Yonemoto, Daniel T. ^[1]; Sears, Jeremiah M. ^[1]; Treadwell, LaRico J. ^[1]; Bell, Nelson S. ^[1]; Cramer, Roger E. ^[1]; Neville, Michael L. ^[1]; Stillman, Gregory A. K. ^[1]; Bingham, Samuel P. ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

The synthesis of a series of lanthanide trifluoroacetic acid (H-TFA) derivatives which contain only the TFA and its conjugate acid has been developed. From the reaction of Ln(N(SiMe₃)₂)₃ with an excess amount of H-TFA, the products were identified as: [Ln(μ-TFA)₃(H-TFA)₂]n (Ln = Y, Ce, Sm, Eu, Gd, Tb, Dy), [Ln(μ-TFA)₃(μ-H-TFA)]_n·solv (Ln·solv = Pr·2 H-TFA, H₃O⁺, Ho·2py, Er·py, Yb·py, H-TFA), 3[H][(TFA)La(μ-TFA)₃La(TFA)(μ-TFA)₂(μ_c-TFA)₂]_n ½(H₂O) ½(H₂O, H-TFA) (La·½(H₂O) ½(H₂O, H-TFA)), [(k²-TFA)Nd(μ-TFA)₃]_n·H-py⁺ (Nd·H-py⁺), [(py)₂Tm(μ-TFA)₃]_n (Tm), or [Lu(μ-TFA)₄Lu(μ-TFA)₃·H₃O⁺]_n (Lu·H₃O⁺). Here, the majority of samples formed long chain polymers with 3 or 4 μ-TFA ligands. Tm was isolated with py coordinated to the metal, whereas Ho, Er, and Yb were isolated with py located within the lattice. Select samples from this set of compounds were used to generate nanomaterials under solvothermal (SOLVO) conditions using pyridine (py) or octylamine at 185 °C for 24 h. The SOLVO products were isolated as: (i) from py: La – fluocerite (LaF₃, PDF 98-000-0214, R = 9.64%, 35(0) nm), Tb – terbium fluoride (TbF₃, PDF 00-037-1487, R = 4.76%, 21(2) nm), Lu lutetium oxy fluoride (LuOF, PDF 00-052-0779, R = 8.24%, 8(2) nm); (ii) from octylamine: La – fluocerite/lanthanum oxide carbonate (LaF₃, PDF 98-000-0214, R = 7.47%, 5(0) nm; La₂O₂(CO₃), PDF 01-070-5539, R = 12.32%, 12(0) nm), Tb – terbium oxy fluoride (TbOF, PDF 00-008-0230, R = 7.01%, 5(0) nm); Lu – lutetium oxide (Lu₂O₃, PDF 00-012-0728, R = 6.52%, 6(1) nm).

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Research Organization:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA)

Grant/Contract Number:: NA0003525; AC04-94AL85000

OSTI ID:: 1871978

Alternate ID(s):: OSTI ID: 1398055

Report Number(s):: SAND2022-5358J; 705512

Journal Information:: Polyhedron, Vol. 131; ISSN 0277-5387

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 3 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Metal carboxylates
Trifluoroacetic acid
TFA
Scintillators
Crystal structure

CCDC 1510594: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwv1 The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510583: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwhp The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510586: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwls The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510589: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwpw The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510595: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpww2 The current record is supplemented by this dataset	dataset	January 2017
CCDC 1535920: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1nk7t8 The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510587: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwmt The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510590: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwqx The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510593: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwt0 The current record is supplemented by this dataset	dataset	January 2017
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CCDC 1510588: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwnv The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510584: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwjq The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510591: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwry The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510597: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwy4 The current record is supplemented by this dataset	dataset	January 2017
CCDC 1510585: Experimental Crystal Structure Determination Boyle, Timothy J.; Yonemoto, Daniel T.; Sears, Jeremiah M. https://doi.org/10.5517/ccdc.csd.cc1mpwkr The current record is supplemented by this dataset	dataset	January 2017
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Title: Synthesis, characterization, and utility of trifluoroacetic acid lanthanide precursors for production of varied phase fluorinated lanthanide nanomaterials

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