Spin-Glass-like State and Reversible Room-Temperature Magnetocaloric Effect in Double Distorted Perovskites Nd(Cu3–xMnx)Mn4O12

Zhang, Qiang; Bréard, Yohann; Hardy, Vincent

doi:10.1021/acs.inorgchem.1c03895

Title: Spin-Glass-like State and Reversible Room-Temperature Magnetocaloric Effect in Double Distorted Perovskites Nd(Cu_3–xMn_x)Mn₄O₁₂

Journal Article · Thu Apr 07 00:00:00 EDT 2022 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.1c03895· OSTI ID:1867767

^[1]; Bréard, Yohann ^[2]; Hardy, Vincent ^[2]

Centre National de la Recherche Scientifique (CNRS) (France); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Centre National de la Recherche Scientifique (CNRS) (France)

The preparation, complex magnetic properties and room-temperature magnetocaloric effect in Nd(Cu_3–xMn_x)Mn₄O₁₂ with cation distribution (Nd³⁺)_A(Cu_3–x^2+xMn_x³⁺)_A'(Mn_1+x³⁺Mn_3–x⁴⁺)_BO₁₂^2– (x = 1 and 1.5) have been reported. Both compounds show a sharp paramagnetic-ferromagnetic (FM) transition at T_C of 300 and 280 K, respectively. The substitution of Cu by Mn at the A' site induces the emergence of a spin glass state below ≈63 K for x = 1 and ≈72 K for x = 1.5 compound. Another antiferromagnetic-like magnetic transition is also observed in both compounds at 23 and 28 K, respectively, which is discussed as the antiferromagnetic coupling between Nd³⁺ at the A' site and (Mn³⁺/Mn⁴⁺) at the B site. These two compounds exhibit room-temperature magnetocaloric effect. For a small field of 2 T, the maximum magnetic entropy changes –ΔS_M are 1.5 J/kg K at 300 K and 1.4 J/kg K at 280 K, respectively. Furthermore, the –ΔS_M(T) curves show an asymmetric distribution, resulting in high refrigerant capacity values for both compounds. We further demonstrate the distinct roles of the A'- and B-site spins on the magnetic properties and the origin of the spin-glass-like state in double distorted perovskites Ln(Cu_3–xMn_x)Mn₄O₁₂ family of compounds.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1867767

Journal Information:: Inorganic Chemistry, Vol. 61, Issue 15; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (32)

Large Low-Field Magnetoresistance in Perovskite-type ${CaCu}_{3} {Mn}_{4} O_{12}$ without Double Exchange Zeng, Z.; Greenblatt, M.; Subramanian, M. A. Physical Review Letters, Vol. 82, Issue 15 https://doi.org/10.1103/PhysRevLett.82.3164	journal	April 1999
Review of the magnetocaloric effect in manganite materials Phan, Manh-Huong; Yu, Seong-Cho Journal of Magnetism and Magnetic Materials, Vol. 308, Issue 2 https://doi.org/10.1016/j.jmmm.2006.07.025	journal	January 2007
Neutron-scattering study of the spin-state transition and magnetic correlations in ${La}_{1 - x}$ ${Sr}_{x}$ ${CoO}_{3}$ ( x =0 and 0.08) Asai, Kichizo; Yokokura, Osamu; Nishimori, Nobuhiko Physical Review B, Vol. 50, Issue 5 https://doi.org/10.1103/PhysRevB.50.3025	journal	August 1994
Thermodynamic and neutron diffraction studies on multiferroic NdMn2O5 Chattopadhyay, S.; Balédent, V.; Auban-Senzier, P. Physica B: Condensed Matter, Vol. 460 https://doi.org/10.1016/j.physb.2014.11.074	journal	March 2015
Reduction of hysteresis losses in the magnetic refrigerant Gd5Ge2Si2 by the addition of iron Provenzano, Virgil; Shapiro, Alexander J.; Shull, Robert D. Nature, Vol. 429, Issue 6994 https://doi.org/10.1038/nature02657	journal	June 2004
Evidence of multiferroicity in ${NdMn}_{2} O_{5}$ Chattopadhyay, S.; Balédent, V.; Damay, F. Physical Review B, Vol. 93, Issue 10 https://doi.org/10.1103/PhysRevB.93.104406	journal	March 2016
Magnetocaloric effect in La _{1− x} Pr _x Fe _10.7 Co _0.8 Si _1.5 compounds near room temperature Shen, Jun; Gao, Bo; Dong, Qiao-Yan Journal of Physics D: Applied Physics, Vol. 41, Issue 24 https://doi.org/10.1088/0022-3727/41/24/245005	journal	November 2008
The synthesis and crystal structure of CaCu3Mn4O12: A new ferromagnetic-perovskite-like compound Chenavas, J.; Joubert, J. C.; Marezio, M. Journal of Solid State Chemistry, Vol. 14, Issue 1 https://doi.org/10.1016/0022-4596(75)90358-8	journal	May 1975
Single-crystal neutron diffraction study of Nd magnetic ordering in ${NdFeO}_{3}$ at low temperature Bartolomé, J.; Palacios, E.; Kuz'min, M. D. Physical Review B, Vol. 55, Issue 17 https://doi.org/10.1103/PhysRevB.55.11432	journal	May 1997
Tunable thermal hysteresis in MnFe(P,Ge) compounds Trung, N. T.; Ou, Z. Q.; Gortenmulder, T. J. Applied Physics Letters, Vol. 94, Issue 10 https://doi.org/10.1063/1.3095597	journal	March 2009
Peculiar Magnetic Behavior of the TbCu ₃ Mn ₄ O ₁₂ Complex Perovskite Sánchez-Benítez, J.; Alonso, J. A.; de Andrés, A. Chemistry of Materials, Vol. 17, Issue 20 https://doi.org/10.1021/cm051265l	journal	September 2005
Spin-glass state induced by cobalt substitution in CaRuO ₃ Bréard, Y.; Hardy, V.; Raveau, B. Journal of Physics: Condensed Matter, Vol. 19, Issue 21 https://doi.org/10.1088/0953-8984/19/21/216212	journal	April 2007
Preparation under high pressures and neutron diffraction study of new ferromagnetic RCu ₃ Mn ₄ O ₁₂ (R = Pr, Sm, Eu, Gd, Dy, Ho, Tm, Yb) perovskites Sánchez-Benítez, J.; Alonso, J. A.; Falcón, H. Journal of Physics: Condensed Matter, Vol. 17, Issue 40 https://doi.org/10.1088/0953-8984/17/40/009	journal	September 2005
Recent advances in magnetic structure determination by neutron powder diffraction Rodríguez-Carvajal, Juan Physica B: Condensed Matter, Vol. 192, Issue 1-2 https://doi.org/10.1016/0921-4526(93)90108-I	journal	October 1993
Ferromagnetic oxides Ln3+/Cu3]Mn4O12 (Ln = La TO Lu and Y) Bochu, B.; Joubert, J. C.; Collomb, A. Journal of Magnetism and Magnetic Materials, Vol. 15-18 https://doi.org/10.1016/0304-8853(80)90307-8	journal	January 1980
The correlation of the magnetic properties and the magnetocaloric effect in (Gd1−xErx)NiAl alloys Korte, B. J.; Pecharsky, V. K.; Gschneidner, K. A. Journal of Applied Physics, Vol. 84, Issue 10 https://doi.org/10.1063/1.368830	journal	November 1998
Investigation of the magnetocaloric effect in double distorted perovskites Ca(Cu $_{3 - x}$ Mn $_{x}$ )Mn $_{4}$ O $_{12} (1 ⩽ x ⩽ 2)$ : From standard ferrimagnetism to glassy ferrimagnetism Zhang, Q.; Bréard, Y.; Guillou, F. Physical Review B, Vol. 84, Issue 22 https://doi.org/10.1103/PhysRevB.84.224430	journal	December 2011
Recent Developments in Magnetic Refrigeration Gschneidner Jr., K. A.; Pecharsky, V. K.; Pecharsky, A. O. Materials Science Forum, Vol. 315-317 https://doi.org/10.4028/www.scientific.net/MSF.315-317.69	journal	July 1999
Magnetocaloric effect in Ho2In over a wide temperature range Zhang, Q.; Cho, J. H.; Li, B. Applied Physics Letters, Vol. 94, Issue 18 https://doi.org/10.1063/1.3130090	journal	May 2009
Large magnetocaloric effect in single crystal Pr0.63Sr0.37MnO3 Phan, Manh-Huong; Peng, Hua-Xin; Yu, Seong-Cho Journal of Applied Physics, Vol. 97, Issue 10 https://doi.org/10.1063/1.1849554	journal	May 2005
Coexistence of ferromagnetic and glassy behavior in the ${La}_{0.5} {Sr}_{0.5} {CoO}_{3}$ perovskite compound Nam, D. N. H.; Jonason, K.; Nordblad, P. Physical Review B, Vol. 59, Issue 6 https://doi.org/10.1103/PhysRevB.59.4189	journal	February 1999
Synthesis, composition, and magnetic properties of the ferrimagnetic NdCu3−xMn4+xO12 perovskite-like phases Samaras, D.; Bochu, B.; Joubert, J. C. Journal of Solid State Chemistry, Vol. 53, Issue 3 https://doi.org/10.1016/0022-4596(84)90109-9	journal	July 1984
Excellent magnetocaloric properties of La[sub 0.7]Ca[sub 0.3−x]Sr[sub x]MnO[sub 3] (0.05≤x≤0.25) single crystals Phan, Manh-Huong; Yu, Seong-Cho; Hur, Nam Hwi Applied Physics Letters, Vol. 86, Issue 7 https://doi.org/10.1063/1.1867564	journal	January 2005
Ferromagnetic behavior in La(Cu3−xMnx)Mn4O12 (x=1,2) perovskites Muñoz, A.; Martínez-Lope, M. J.; Retuerto, M. Journal of Applied Physics, Vol. 104, Issue 8 https://doi.org/10.1063/1.3000617	journal	October 2008
A better ferrimagnetic half-metal LuCu3Mn4O12: Predicted from first-principles investigation Lv, Shuhui; Li, Hongping; Han, Deming Journal of Magnetism and Magnetic Materials, Vol. 323, Issue 5 https://doi.org/10.1016/j.jmmm.2010.09.033	journal	March 2011
Magnetocaloric effect in polycrystalline La based manganites modified with Sr Kolano-Burian, A.; Szymczak, R.; Kolano, R. Journal of Physics: Conference Series, Vol. 303 https://doi.org/10.1088/1742-6596/303/1/012070	journal	July 2011
Evidence of two different $Mn$ states in ${CaCu}_{3} {Mn}_{4} O_{12}$ derivatives with colossal magnetoresistance Sánchez-Benítez, J.; Prieto, C.; de Andrés, A. Physical Review B, Vol. 70, Issue 2 https://doi.org/10.1103/PhysRevB.70.024419	journal	July 2004
New functional materials AC3B4O12 (Review) Vasil’ev, A. N.; Volkova, O. S. Low Temperature Physics, Vol. 33, Issue 11 https://doi.org/10.1063/1.2747047	journal	November 2007
Magnetocaloric Materials Gschneidner, K. A.; Pecharsky, V. K. Annual Review of Materials Science, Vol. 30, Issue 1 https://doi.org/10.1146/annurev.matsci.30.1.387	journal	August 2000
Specific heat and magnetic interactions in ${NdCrO}_{3}$ Bartolomé, Fernando; Bartolomé, Juan; Castro, Miguel Physical Review B, Vol. 62, Issue 2 https://doi.org/10.1103/PhysRevB.62.1058	journal	July 2000
Spin glassiness and ferromagnetism in disordered Ni‐Mn (invited) Abdul‐Razzaq, W.; Kouvel, J. S. Journal of Applied Physics, Vol. 55, Issue 6 https://doi.org/10.1063/1.333425	journal	March 1984
Giant Improper Ferroelectricity in the Ferroaxial Magnet ${CaMn}_{7} O_{12}$ Johnson, R. D.; Chapon, L. C.; Khalyavin, D. D. Physical Review Letters, Vol. 108, Issue 6 https://doi.org/10.1103/PhysRevLett.108.067201	journal	February 2012

Similar Records

Effect of Fe Substitution on the Physical Properties of La{sub 0.62}Er{sub 0.05}Ba{sub 0.33}Mn{sub 1−x}Fe{sub x}O{sub 3}(x = 0.00, 0.05 and 0.15)

Journal Article · Fri Feb 15 00:00:00 EST 2019 · Journal of Superconductivity and Novel Magnetism · OSTI ID:1867767

Mounira, Abassi

Giant magnetic coercivity in CaCu{sub 5}-type SmNi{sub 3}TSi (T=Mn–Cu) solid solutions

Journal Article · Tue Dec 15 00:00:00 EST 2015 · Journal of Solid State Chemistry · OSTI ID:1867767

Yao, Jinlei; Yan, Xu

Magnetic properties and magnetocaloric effect of NdMn{sub 2−x}Cu{sub x}Si{sub 2} compounds

Journal Article · Wed May 07 00:00:00 EDT 2014 · Journal of Applied Physics · OSTI ID:1867767

Wang, J. L.; Avdeev, M.; Kennedy, S. J.; +4 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
cations
magnetic properties
perovskites
quantum mechanics
transition metals

Title: Spin-Glass-like State and Reversible Room-Temperature Magnetocaloric Effect in Double Distorted Perovskites Nd(Cu3–xMnx)Mn4O12

Citation Formats

References (32)

Similar Records

Related Subjects

Title: Spin-Glass-like State and Reversible Room-Temperature Magnetocaloric Effect in Double Distorted Perovskites Nd(Cu_3–xMn_x)Mn₄O₁₂