Synthesis of new two-dimensional titanium carbonitride Ti2C0.5N0.5Tx MXene and its performance as an electrode material for sodium-ion battery

Liang, Kun; Tabassum, Anika; Majed, Ahmad; Dun, Chaochao; Yang, Feipeng; Guo, Jinghua; Prenger, Kaitlyn; Urban, Jeffrey J.; Naguib, Michael

doi:10.1002/inf2.12269

Title: Synthesis of new two-dimensional titanium carbonitride Ti₂C_0.5N_0.5T_x MXene and its performance as an electrode material for sodium-ion battery

Journal Article · Sun Dec 12 00:00:00 EST 2021 · InfoMat

DOI:https://doi.org/10.1002/inf2.12269· OSTI ID:1842650

^[1]; Tabassum, Anika ^[1]; Majed, Ahmad ^[1];

^[2];

^[3]; Guo, Jinghua ^[3];

^[1]; Urban, Jeffrey J. ^[2];

^[1]

Tulane Univ., New Orleans, LA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Molecular Foundry
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Two-dimensional (2D) layered transition metal carbides/nitrides, called MXenes, are attractive alternative electrode materials for electrochemical energy storage. Owing to their metallic electrical conductivity and low ion diffusion barrier, MXenes are promising anode materials for sodium-ion batteries (SIBs). Herein, we report on a new 2D carbonitride MXene, viz., Ti₂C_0.5N_0.5T_x (T_x stands for surface terminations), and the only second carbonitride after Ti₃CNT_x so far. A new type of in situ HF (HCl/KF) etching condition was employed to synthesize multilayer Ti₂C_0.5N_0.5T_x powders from Ti₂AlC_0.5N_0.5. Spontaneous intercalation of tetramethylammonium followed by sonication in water allowed for large-scale delamination of this new titanium carbonitride into 2D sheets. Multilayer Ti₂C_0.5N_0.5T_x powders showed higher specific capacities and larger electroactive surface area than those of Ti₂CT_x powders. Multilayer Ti₂C_0.5N_0.5T_x powders show a specific capacity of 182 mAh g^-1 at 20 mA g^-1, the highest among all reported MXene electrodes as SIBs with excellent cycling stability.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1842650

Journal Information:: InfoMat, Vol. 3, Issue 12; ISSN 2567-3165

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Title: Synthesis of new two-dimensional titanium carbonitride Ti2C0.5N0.5Tx MXene and its performance as an electrode material for sodium-ion battery

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Title: Synthesis of new two-dimensional titanium carbonitride Ti₂C_0.5N_0.5T_x MXene and its performance as an electrode material for sodium-ion battery