Adsorption of ethane, ethene, and ethyne on reconstructed Fe3O4(001)

Lee, Christopher J.; Sharp, Marcus; Smith, Ronald S.; Kay, Bruce D.; Dohnalek, Zdenek

doi:10.1016/j.susc.2021.121932

Title: Adsorption of ethane, ethene, and ethyne on reconstructed Fe₃O₄(001)

Journal Article · Sun Aug 29 00:00:00 EDT 2021 · Surface Science

DOI:https://doi.org/10.1016/j.susc.2021.121932· OSTI ID:1836239

Lee, Christopher J. ^[1]; Sharp, Marcus ^[2];

^[1];

^[2]

Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Institute for Integrated Catalysis
Pacific Northwest National Lab. (PNNL), Richland, WA (United States). Institute for Integrated Catalysis; Washington State Univ., Pullman, WA (United States)

The adsorption of the C2 hydrocarbons including ethane, ethene, and ethyne are studied on magnetite Fe₃O₄(001) by a combination of molecular beam dosing, temperature programmed desorption, and X-ray photoelectron spectroscopy. The ethane desorption profile has a single temperature invariant peak at 100 K while ethene and ethyne exhibit additional peaks at ~120 K and ~135 K. An inversion analysis is used to extract coverage dependent desorption energies as well as coverage-averaged prefactors for each molecule. Ethene and ethyne exhibit moderate coverage dependent desorption energies decreasing from ~80 to ~30 kJ/mol at saturation while ethane shows a relatively coverage invariant desorption energy ~28 kJ/mol. The desorption energies of the C2 hydrocarbons increase in order of increasing bond order. This is likely due to the enhanced interaction of the ethene and ethyne p system to the coordinatively unsaturated octahedral Fe sites (Fe_oct) on the ¬oxide surface. The saturation coverages of each C2 hydrocarbon at 82 K were also determined. Furthermore, these match well with the 2-dimensional spacing determined from their liquid densities.

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Research Organization:: Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Biological and Environmental Research (BER); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-76RL01830

OSTI ID:: 1836239

Alternate ID(s):: OSTI ID: 1894409

Report Number(s):: PNNL-SA-161889

Journal Information:: Surface Science, Vol. 714; ISSN 0039-6028

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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