Structural and Rotational Dynamics of Carbon Dioxide in 1-Alkyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide Ionic Liquids: The Effect of Chain Length

Giammanco, Chiara H.; Yamada, Steven A.; Kramer, Patrick L.; Tamimi, Amr; Fayer, Michael D.

doi:10.1021/acs.jpcb.6b03971

Title: Structural and Rotational Dynamics of Carbon Dioxide in 1-Alkyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide Ionic Liquids: The Effect of Chain Length

Journal Article · Sun Jun 05 00:00:00 EDT 2016 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry

DOI:https://doi.org/10.1021/acs.jpcb.6b03971· OSTI ID:1804755

Giammanco, Chiara H. ^[1]; Yamada, Steven A. ^[1]; Kramer, Patrick L. ^[1]; Tamimi, Amr ^[1]; Fayer, Michael D. ^[1]

Stanford Univ., CA (United States)

Ionic liquids (ILs) have been proposed as possible carbon dioxide (CO₂) carbon capture media, and so it is useful to understand the dynamics of both the dissolved gas and its IL environment as well as how altering the IL affects these dynamics. With increasing alkyl chain length, it is well established that ILs obtain a mesoscopic structural feature assigned to polarapolar segregation, and the change in structure with chain length affects dynamics. In this work, the dynamics of CO₂ in a series of 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide ionic liquids (ILs), where alkyl is ethyl, butyl, hexyl, or decyl, were investigated using ultrafast infrared spectroscopy by measuring the reorientation and spectral diffusion of carbon dioxide in the ILs. It was found that reorientation of the carbon dioxide occurs on 3 timescales, which correspond to 2 different timescales of restricted wobbling-in-a-cone motions and a long time complete diffusive reorientation. The complete reorientation slows with increasing chain length but less than the increases in viscosity of the bulk liquids. Spectral diffusion, measured with 2D IR spectroscopy, is caused by a combination of the liquids’ structural fluctuations and reorientation of the CO₂. The data were analyzed using recent theory that takes into account both contributions to spectral diffusion and extracts the structural spectral diffusion. Different components of the structural fluctuations have distinct dependences on the alkyl chain length. All of the dynamics are fast compared to the complete orientational randomization of the bulk ILs, as measured with optical heterodyne detected optical Kerr effect measurements. The results indicate a hierarchy of constraint releases in the liquids that give rise to increasingly slower dynamics.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Stanford Univ., CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)

Grant/Contract Number:: FG02-84ER13251; CHE-1461477

OSTI ID:: 1804755

Journal Information:: Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry, Vol. 120, Issue 27; ISSN 1520-6106

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (77)

Room-Temperature Ionic Liquids: Solvents for Synthesis and Catalysis. 2 Hallett, Jason P.; Welton, Tom Chemical Reviews, Vol. 111, Issue 5 https://doi.org/10.1021/cr1003248	journal	May 2011
Ionic-liquid materials for the electrochemical challenges of the future Armand, Michel; Endres, Frank; MacFarlane, Douglas R. Nature Materials, Vol. 8, Issue 8, p. 621-629 https://doi.org/10.1038/nmat2448	journal	July 2009
Comparisons of 2D IR measured spectral diffusion in rotating frames using pulse shaping and in the stationary frame using the standard method Karthick Kumar, S. K.; Tamimi, A.; Fayer, M. D. The Journal of Chemical Physics, Vol. 137, Issue 18 https://doi.org/10.1063/1.4764470	journal	November 2012
Viscosity dependence of the rotational reorientation of rhodamine B in mono- and polyalcohols. Picosecond transient grating experiments Moog, R. S.; Ediger, M. D.; Boxer, S. G. The Journal of Physical Chemistry, Vol. 86, Issue 24 https://doi.org/10.1021/j100221a011	journal	November 1982
Rotational friction coefficients for spheroids with the slipping boundary condition Hu, Chih‐Ming; Zwanzig, Robert The Journal of Chemical Physics, Vol. 60, Issue 11 https://doi.org/10.1063/1.1680910	journal	June 1974
Comment on: Rotational friction coefficients for ellipsoids and chemical molecules with slip boundary conditions Sension, Roseanne J.; Hochstrasser, Robin M. The Journal of Chemical Physics, Vol. 98, Issue 3 https://doi.org/10.1063/1.465075	journal	February 1993
CO ₂ Capture in Ionic Liquids: A Review of Solubilities and Experimental Methods Torralba-Calleja, Elena; Skinner, James; Gutiérrez-Tauste, David Journal of Chemistry, Vol. 2013 https://doi.org/10.1155/2013/473584	journal	January 2013
Structure and Aggregation in the 1-Alkyl-3-Methylimidazolium Bis(trifluoromethylsulfonyl)imide Ionic Liquid Homologous Series Shimizu, Karina; Bernardes, Carlos E. S.; Canongia Lopes, José N. The Journal of Physical Chemistry B, Vol. 118, Issue 2 https://doi.org/10.1021/jp409987d	journal	January 2014
High-Accuracy Vapor Pressure Data of the Extended [C _n C ₁ im][Ntf ₂ ] Ionic Liquid Series: Trend Changes and Structural Shifts Rocha, Marisa A. A.; Lima, Carlos F. R. A. C.; Gomes, Lígia R. The Journal of Physical Chemistry B, Vol. 115, Issue 37 https://doi.org/10.1021/jp2049316	journal	September 2011
STARK SPECTROSCOPY: Applications in Chemistry, Biology, and Materials Science Bublitz, Gerold U.; Boxer, Steven G. Annual Review of Physical Chemistry, Vol. 48, Issue 1 https://doi.org/10.1146/annurev.physchem.48.1.213	journal	October 1997
Gas permeabilities, solubilities, diffusivities, and diffusivity correlations for ammonium-based room temperature ionic liquids with comparison to imidazolium and phosphonium RTIL data Condemarin, Ricardo; Scovazzo, Paul Chemical Engineering Journal, Vol. 147, Issue 1 https://doi.org/10.1016/j.cej.2008.11.015	journal	April 2009
Taking apart the two-dimensional infrared vibrational echo spectra: More information and elimination of distortions Kwak, Kyungwon; Rosenfeld, Daniel E.; Fayer, M. D. The Journal of Chemical Physics, Vol. 128, Issue 20 https://doi.org/10.1063/1.2927906	journal	May 2008
Effect of librational motion on fluorescence depolarization and nuclear magnetic resonance relaxation in macromolecules and membranes Lipari, G.; Szabo, A. Biophysical Journal, Vol. 30, Issue 3 https://doi.org/10.1016/S0006-3495(80)85109-5	journal	June 1980
Frequency-frequency correlation functions and apodization in two-dimensional infrared vibrational echo spectroscopy: A new approach Kwak, Kyungwon; Park, Sungnam; Finkelstein, Ilya J. The Journal of Chemical Physics, Vol. 127, Issue 12 https://doi.org/10.1063/1.2772269	journal	September 2007
Effect of CO2 dissolution on electrical conductivity and self-diffusion coefficients of 1-butyl-3-methylimidazolium hexafluorophosphate ionic liquid Umecky, Tatsuya; Kanakubo, Mitsuhiro; Makino, Takashi Fluid Phase Equilibria, Vol. 357 https://doi.org/10.1016/j.fluid.2013.05.023	journal	November 2013
Why Is CO ₂ So Soluble in Imidazolium-Based Ionic Liquids? Cadena, Cesar; Anthony, Jennifer L.; Shah, Jindal K. Journal of the American Chemical Society, Vol. 126, Issue 16 https://doi.org/10.1021/ja039615x	journal	April 2004
Properties of Alkylimidazoles as Solvents for CO ₂ Capture and Comparisons to Imidazolium-Based Ionic Liquids Shannon, Matthew S.; Bara, Jason E. Industrial & Engineering Chemistry Research, Vol. 50, Issue 14 https://doi.org/10.1021/ie200259h	journal	July 2011
How Is Diffusion of Neutral and Charged Tracers Related to the Structure and Dynamics of a Room-Temperature Ionic Liquid? Large Deviations from Stokes–Einstein Behavior Explained Araque, Juan C.; Yadav, Sharad K.; Shadeck, Michael The Journal of Physical Chemistry B, Vol. 119, Issue 23 https://doi.org/10.1021/acs.jpcb.5b01093	journal	April 2015
State-of-the-Art of CO ₂ Capture with Ionic Liquids Ramdin, Mahinder; de Loos, Theo W.; Vlugt, Thijs J. H. Industrial & Engineering Chemistry Research, Vol. 51, Issue 24 https://doi.org/10.1021/ie3003705	journal	June 2012
Room-Temperature Ionic Liquids and Composite Materials: Platform Technologies for CO ₂ Capture Bara, Jason E.; Camper, Dean E.; Gin, Douglas L. Accounts of Chemical Research, Vol. 43, Issue 1 https://doi.org/10.1021/ar9001747	journal	January 2010
Femtosecond pulse shaping directly in the mid-IR using acousto-optic modulation Shim, Sang-Hee; Strasfeld, David B.; Fulmer, Eric C. Optics Letters, Vol. 31, Issue 6 https://doi.org/10.1364/OL.31.000838	journal	January 2006
Ionic Liquid Dynamics Measured with 2D IR and IR Pump–Probe Experiments on a Linear Anion and the Influence of Potassium Cations Tamimi, Amr; Fayer, Michael D. The Journal of Physical Chemistry B, Vol. 120, Issue 26 https://doi.org/10.1021/acs.jpcb.6b00409	journal	February 2016
Orientational dynamics of water confined on a nanometer length scale in reverse micelles Tan, Howe-Siang; Piletic, Ivan R.; Fayer, M. D. The Journal of Chemical Physics, Vol. 122, Issue 17 https://doi.org/10.1063/1.1883605	journal	May 2005
Ultrafast vibrational spectroscopy (2D-IR) of CO ₂ in ionic liquids: Carbon capture from carbon dioxide’s point of view Brinzer, Thomas; Berquist, Eric J.; Dutta, Samrat The Journal of Chemical Physics, Vol. 142, Issue 21 https://doi.org/10.1063/1.4917467	journal	June 2015
Coupling of Carbon Dioxide Stretch and Bend Vibrations Reveals Thermal Population Dynamics in an Ionic Liquid Giammanco, Chiara H.; Kramer, Patrick L.; Yamada, Steven A. The Journal of Physical Chemistry B, Vol. 120, Issue 3 https://doi.org/10.1021/acs.jpcb.5b11454	journal	January 2016
Why Is the Partial Molar Volume of CO ₂ So Small When Dissolved in a Room Temperature Ionic Liquid? Structure and Dynamics of CO ₂ Dissolved in [Bmim ⁺ ] [PF ₆ ^- ] Huang, Xuhui; Margulis, Claudio J.; Li, Yuhui Journal of the American Chemical Society, Vol. 127, Issue 50 https://doi.org/10.1021/ja055315z	journal	December 2005
Stark Realities ^† Boxer, Steven G. The Journal of Physical Chemistry B, Vol. 113, Issue 10 https://doi.org/10.1021/jp8067393	journal	March 2009
Applications of ionic liquids in the chemical industry Plechkova, Natalia V.; Seddon, Kenneth R. Chem. Soc. Rev., Vol. 37, Issue 1 https://doi.org/10.1039/B006677J	journal	January 2008
Alkylimidazolium Based Ionic Liquids: Impact of Cation Symmetry on Their Nanoscale Structural Organization Rocha, Marisa A. A.; Neves, Catarina M. S. S.; Freire, Mara G. The Journal of Physical Chemistry B, Vol. 117, Issue 37 https://doi.org/10.1021/jp406374a	journal	September 2013
Physical and Chemical Absorptions of Carbon Dioxide in Room-Temperature Ionic Liquids Yokozeki, A.; Shiflett, Mark B.; Junk, Christopher P. The Journal of Physical Chemistry B, Vol. 112, Issue 51 https://doi.org/10.1021/jp805784u	journal	December 2008
Dynamics of water, methanol, and ethanol in a room temperature ionic liquid Kramer, Patrick L.; Giammanco, Chiara H.; Fayer, Michael D. The Journal of Chemical Physics, Vol. 142, Issue 21 https://doi.org/10.1063/1.4914156	journal	June 2015
Carbon capture with ionic liquids: overview and progress Zhang, Xiangping; Zhang, Xiaochun; Dong, Haifeng Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21152a	journal	January 2012
Experimental Measurement of the Solubility and Diffusivity of CO ₂ in Room-Temperature Ionic Liquids Using a Transient Thin-Liquid-Film Method Hou, Ying; Baltus, Ruth E. Industrial & Engineering Chemistry Research, Vol. 46, Issue 24 https://doi.org/10.1021/ie070501u	journal	November 2007
Observation and theory of reorientation-induced spectral diffusion in polarization-selective 2D IR spectroscopy Kramer, Patrick L.; Nishida, Jun; Giammanco, Chiara H. The Journal of Chemical Physics, Vol. 142, Issue 18 https://doi.org/10.1063/1.4920949	journal	May 2015
Purely absorptive three-dimensional infrared spectroscopy Garrett-Roe, Sean; Hamm, Peter The Journal of Chemical Physics, Vol. 130, Issue 16 https://doi.org/10.1063/1.3122982	journal	April 2009
Orientational Dynamics in a Lyotropic Room Temperature Ionic Liquid Sturlaugson, Adam L.; Arima, Aaron Y.; Bailey, Heather E. The Journal of Physical Chemistry B, Vol. 117, Issue 47 https://doi.org/10.1021/jp407325b	journal	November 2013
Carbon capture and storage update Boot-Handford, Matthew E.; Abanades, Juan C.; Anthony, Edward J. Energy Environ. Sci., Vol. 7, Issue 1 https://doi.org/10.1039/C3EE42350F	journal	January 2014
Structure and Nanostructure in Ionic Liquids Hayes, Robert; Warr, Gregory G.; Atkin, Rob Chemical Reviews, Vol. 115, Issue 13 https://doi.org/10.1021/cr500411q	journal	June 2015
Diffusion Coefficients of CO ₂ in Ionic Liquids Estimated by Gravimetry Moya, Cristian; Palomar, Jose; Gonzalez-Miquel, Maria Industrial & Engineering Chemistry Research, Vol. 53, Issue 35 https://doi.org/10.1021/ie501925d	journal	August 2014
Molecular volumes and the Stokes-Einstein equation Edward, John T. Journal of Chemical Education, Vol. 47, Issue 4 https://doi.org/10.1021/ed047p261	journal	April 1970
Precombustion Decarbonisation Processes Eide, L. I.; Bailey, D. W. Oil & Gas Science and Technology, Vol. 60, Issue 3 https://doi.org/10.2516/ogst:2005029	journal	May 2005
Post-Combustion Decarbonisation Processes Bailey, D. W.; Feron, P. H. M. Oil & Gas Science and Technology, Vol. 60, Issue 3 https://doi.org/10.2516/ogst:2005028	journal	May 2005
Two-Dimensional Electronic Correlation and Relaxation Spectra: Theory and Model Calculations Gallagher Faeder, Sarah M.; Jonas, David M. The Journal of Physical Chemistry A, Vol. 103, Issue 49 https://doi.org/10.1021/jp9925738	journal	December 1999
Rotational friction coefficients for ellipsoids and chemical molecules with the slip boundary condition Youngren, G. K.; Acrivos, A. The Journal of Chemical Physics, Vol. 63, Issue 9 https://doi.org/10.1063/1.431879	journal	January 1975
Molecular states of water in room temperature ionic liquidsElectronic Supplementary Information available. See http://www.rsc.org/suppdata/cp/b1/b106900d/ Cammarata, L.; Kazarian, S. G.; Salter, P. A. Physical Chemistry Chemical Physics, Vol. 3, Issue 23 https://doi.org/10.1039/b106900d	journal	November 2001
Negative emissions physically needed to keep global warming below 2 °C Gasser, T.; Guivarch, C.; Tachiiri, K. Nature Communications, Vol. 6, Issue 1 https://doi.org/10.1038/ncomms8958	journal	August 2015
Dynamics in Organic Ionic Liquids in Distinct Regions Using Charged and Uncharged Orientational Relaxation Probes Fruchey, Kendall; Fayer, M. D. The Journal of Physical Chemistry B, Vol. 114, Issue 8 https://doi.org/10.1021/jp911123v	journal	March 2010
Comparison between Dicationic and Monocationic Ionic Liquids: Liquid Density, Thermal Properties, Surface Tension, and Shear Viscosity Shirota, Hideaki; Mandai, Toshihiko; Fukazawa, Hiroki Journal of Chemical & Engineering Data, Vol. 56, Issue 5 https://doi.org/10.1021/je2000183	journal	May 2011
Watching Hydrogen Bonds Break: A Transient Absorption Study of Water Steinel, Tobias; Asbury, John B.; Zheng, Junrong The Journal of Physical Chemistry A, Vol. 108, Issue 50 https://doi.org/10.1021/jp046711r	journal	December 2004
On the wobbling-in-cone analysis of fluorescence anisotropy decay Kinosita, K.; Ikegami, A.; Kawato, S. Biophysical Journal, Vol. 37, Issue 2 https://doi.org/10.1016/S0006-3495(82)84692-4	journal	February 1982
In Situ Attenuated Total Reflection Infrared Spectroscopy of Imidazolium-Based Room-Temperature Ionic Liquids under “Supercritical” CO ₂ Seki, Tsunetake; Grunwaldt, Jan-Dierk; Baiker, Alfons The Journal of Physical Chemistry B, Vol. 113, Issue 1 https://doi.org/10.1021/jp800424d	journal	January 2009
Advances in CO₂ capture technology—The U.S. Department of Energy's Carbon Sequestration Program Figueroa, José D.; Fout, Timothy; Plasynski, Sean International Journal of Greenhouse Gas Control, Vol. 2, Issue 1, p. 9-20 https://doi.org/10.1016/S1750-5836(07)00094-1	journal	January 2008
Water dynamics in small reverse micelles in two solvents: Two-dimensional infrared vibrational echoes with two-dimensional background subtraction Fenn, Emily E.; Wong, Daryl B.; Fayer, M. D. The Journal of Chemical Physics, Vol. 134, Issue 5 https://doi.org/10.1063/1.3532542	journal	February 2011
Solute Diffusion in Ionic Liquids, NMR Measurements and Comparisons to Conventional Solvents Kaintz, Anne; Baker, Gary; Benesi, Alan The Journal of Physical Chemistry B, Vol. 117, Issue 39 https://doi.org/10.1021/jp405393d	journal	September 2013
Carbon Capture and Storage: How Green Can Black Be? Haszeldine, R. S. Science, Vol. 325, Issue 5948 https://doi.org/10.1126/science.1172246	journal	September 2009
Calibration of a reflectance FTIR method for determination of dissolved CO2 concentration in rhyolitic glasses Moore, Gordon; Chizmeshya, Andrew; McMillan, Paul F. Geochimica et Cosmochimica Acta, Vol. 64, Issue 20 https://doi.org/10.1016/S0016-7037(00)00447-6	journal	October 2000
Dynamics of Isolated Water Molecules in a Sea of Ions in a Room Temperature Ionic Liquid Wong, Daryl B.; Giammanco, Chiara H.; Fenn, Emily E. The Journal of Physical Chemistry B, Vol. 117, Issue 2 https://doi.org/10.1021/jp310086s	journal	January 2013
Model-free approach to the interpretation of nuclear magnetic resonance relaxation in macromolecules. 1. Theory and range of validity Lipari, Giovanni; Szabo, Attila Journal of the American Chemical Society, Vol. 104, Issue 17 https://doi.org/10.1021/ja00381a009	journal	August 1982
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis Welton, Thomas Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084 https://doi.org/10.1021/cr980032t	journal	August 1999
Ultrafast 2D-IR vibrational echo spectroscopy: a probe of molecular dynamics Park, S.; Kwak, K.; Fayer, M. D. Laser Physics Letters, Vol. 4, Issue 10 https://doi.org/10.1002/lapl.200710046	journal	October 2007
Theory of vibrational relaxation of polyatomic molecules in liquids Kenkre, V. M.; Tokmakoff, A.; Fayer, M. D. The Journal of Chemical Physics, Vol. 101, Issue 12 https://doi.org/10.1063/1.467876	journal	December 1994
Vibrational Stark Effects of Nitriles I. Methods and Experimental Results Andrews, Steven S.; Boxer, Steven G. The Journal of Physical Chemistry A, Vol. 104, Issue 51 https://doi.org/10.1021/jp002242r	journal	December 2000
Morphology and intermolecular dynamics of 1-alkyl-3-methylimidazolium bis{(trifluoromethane)sulfonyl}amide ionic liquids: structural and dynamic evidence of nanoscale segregation Russina, Olga; Triolo, Alessandro; Gontrani, Lorenzo Journal of Physics: Condensed Matter, Vol. 21, Issue 42 https://doi.org/10.1088/0953-8984/21/42/424121	journal	September 2009
Diffusivities of Gases in Room-Temperature Ionic Liquids: Data and Correlations Obtained Using a Lag-Time Technique Morgan, David; Ferguson, Lee; Scovazzo, Paul Industrial & Engineering Chemistry Research, Vol. 44, Issue 13 https://doi.org/10.1021/ie048825v	journal	June 2005
Determination of the diffusion coefficient of CO2 in the ionic liquid EMIM NTf2 using online FTIR measurements Kortenbruck, K.; Pohrer, B.; Schluecker, E. The Journal of Chemical Thermodynamics, Vol. 47 https://doi.org/10.1016/j.jct.2011.09.025	journal	April 2012
Diffusion and Solubility Measurements in Room Temperature Ionic Liquids Camper, Dean; Becker, Collin; Koval, Carl Industrial & Engineering Chemistry Research, Vol. 45, Issue 1 https://doi.org/10.1021/ie0506668	journal	January 2006
Spectroscopy of Hydrothermal Reactions. Part XI: Infrared Absorptivity of CO ₂ and N ₂ O in Water at Elevated Temperature and Pressure Maiella, P. G.; Schoppelrei, J. W.; Brill, T. B. Applied Spectroscopy, Vol. 53, Issue 3 https://doi.org/10.1366/0003702991946578	journal	March 1999
Power plant post-combustion carbon dioxide capture: An opportunity for membranes Merkel, Tim C.; Lin, Haiqing; Wei, Xiaotong Journal of Membrane Science, Vol. 359, Issue 1-2, p. 126-139 https://doi.org/10.1016/j.memsci.2009.10.041	journal	September 2010
Heat capacities at 298.15K of the extended [CnC1im][Ntf2] ionic liquid series Rocha, Marisa A. A.; Bastos, Margarida; Coutinho, João A. P. The Journal of Chemical Thermodynamics, Vol. 53 https://doi.org/10.1016/j.jct.2012.04.025	journal	October 2012
Carbon dioxide in an ionic liquid: Structural and rotational dynamics Giammanco, Chiara H.; Kramer, Patrick L.; Yamada, Steven A. The Journal of Chemical Physics, Vol. 144, Issue 10 https://doi.org/10.1063/1.4943390	journal	March 2016
Diffusivity of Carbon Dioxide in Room-Temperature Ionic Liquids Moganty, Surya S.; Baltus, Ruth E. Industrial & Engineering Chemistry Research, Vol. 49, Issue 19 https://doi.org/10.1021/ie101260j	journal	October 2010
Vapor–liquid equilibria of mixtures containing alkanes, carbon dioxide, and nitrogen Potoff, Jeffrey J.; Siepmann, J. Ilja AIChE Journal, Vol. 47, Issue 7, p. 1676-1682 https://doi.org/10.1002/aic.690470719	journal	July 2001
Separation of experimental 2D IR frequency-frequency correlation functions into structural and reorientation-induced contributions Kramer, Patrick L.; Nishida, Jun; Fayer, Michael D. The Journal of Chemical Physics, Vol. 143, Issue 12 https://doi.org/10.1063/1.4931402	journal	September 2015
CO₂ Capture by a Task-Specific Ionic Liquid Bates, Eleanor D.; Mayton, Rebecca D.; Ntai, Ioanna Journal of the American Chemical Society, Vol. 124, Issue 6, p. 926-927 https://doi.org/10.1021/ja017593d	journal	February 2002
On the orientational relaxation of HDO in liquid water Rezus, Y. L. A.; Bakker, H. J. The Journal of Chemical Physics, Vol. 123, Issue 11 https://doi.org/10.1063/1.2009729	journal	September 2005
Time‐correlation functions for restricted rotational diffusion Wang, C. C.; Pecora, R. The Journal of Chemical Physics, Vol. 72, Issue 10 https://doi.org/10.1063/1.439024	journal	May 1980
Combined Application of High-Field Diffusion NMR and Molecular Dynamics Simulations To Study Dynamics in a Mixture of Carbon Dioxide and an Imidazolium-Based Ionic Liquid Hazelbaker, Eric D.; Budhathoki, Samir; Katihar, Aakanksha The Journal of Physical Chemistry B, Vol. 116, Issue 30 https://doi.org/10.1021/jp304528d	journal	July 2012

Cited By (1)

Dynamics of Dicyanamide in Ionic Liquids is Dominated by Local Interactions Hunger, Johannes; Roy, Soham; Grechko, Maksim The Journal of Physical Chemistry B, Vol. 123, Issue 8 https://doi.org/10.1021/acs.jpcb.8b10849	journal	February 2019

Similar Records

Water Dynamics in 1-Alkyl-3-methylimidazolium Tetrafluoroborate Ionic Liquids

Journal Article · Tue Oct 11 00:00:00 EDT 2016 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1804755

Giammanco, Chiara H.; Kramer, Patrick L.; Wong, Daryl B.; +1 more

The Influence of Water on the Alkyl Region Structure in Variable Chain Length Imidazolium-Based Ionic Liquid/Water Mixtures

Journal Article · Tue Sep 27 00:00:00 EDT 2016 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1804755

Thomaz, Joseph E.; Lawler, Christian M.; Fayer, Michael D.

Carbon dioxide in an ionic liquid: Structural and rotational dynamics

Journal Article · Fri Mar 11 00:00:00 EST 2016 · Journal of Chemical Physics · OSTI ID:1804755

Giammanco, Chiara H.; Kramer, Patrick L.; Yamada, Steven A.; +3 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Oxides
Diffusion
Inorganic carbon compounds
Solvents
Probes

Title: Structural and Rotational Dynamics of Carbon Dioxide in 1-Alkyl-3-methylimidazolium Bis(trifluoromethylsulfonyl)imide Ionic Liquids: The Effect of Chain Length

Citation Formats

References (77)

Cited By (1)

Similar Records

Related Subjects