Monitoring structural variation on Gd ratio of La modified bismuth ferrite ceramics with enhanced magnetization

Bozgeyik, Mehmet S.; Kirkgecit, Nurvet; Katiyar, Rajesh K.; Katiyar, Ram S.

doi:10.1016/j.jallcom.2019.153050

Title: Monitoring structural variation on Gd ratio of La modified bismuth ferrite ceramics with enhanced magnetization

Journal Article · Mon Nov 18 00:00:00 EST 2019 · Journal of Alloys and Compounds

DOI:https://doi.org/10.1016/j.jallcom.2019.153050· OSTI ID:1800581

^[1]; Kirkgecit, Nurvet ^[2]; Katiyar, Rajesh K. ^[3]; Katiyar, Ram S. ^[3]

Univ. of Puerto Rico, San Juan, PR (United States); Kahramanmaras Sutcu Imam Univ., Kahramanmaras (Turkey)
Kahramanmaras Sutcu Imam Univ., Kahramanmaras (Turkey)
Univ. of Puerto Rico, San Juan, PR (United States)

Critical structural variation and dielectric properties were investigated in Lanthanum and Gadolinium co-substituted bismuth ferrite (Bi_0.9La_0.1Fe_1-xGd_xO₃ (x = 0.01, 0.03, 0.05, 0.07, 0.1, and 0.15). Conventional solid state reaction technique was used to synthesize ceramic samples. To investigate the influence of co-substitution on the phase formation and crystal structure, X-ray diffraction method (XRD), Scanning electron microscopy (SEM) and Raman spectroscopy were utilized. Probing the structural properties by changing Gd ratio was carried out to ensure single phase of rhombohedral R3c structure. Hence, the exploration of dielectric properties of single phase modified BiFeO₃ (BFO) ceramic was executed by room temperature capacitance and loss tangent measurements. It was found that by substitution of 10 mol% La for Bi and up to 5 mol% Gd for Bi, perovskite structure of rhombohedral symmetry and R3c space group were formed. This possessed enhanced magnetization and reduced dielectric loss compared to pure BFO.

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Research Organization:: Univ. of Puerto Rico, San Juan, PR (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-08ER46526

OSTI ID:: 1800581

Alternate ID(s):: OSTI ID: 1702831

Journal Information:: Journal of Alloys and Compounds, Vol. 819; ISSN 0925-8388

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (42)

Improved magnetic properties of bismuth ferrite ceramics by La and Gd co-substitution Bozgeyik, Mehmet S.; Katiyar, Rajesh K.; Katiyar, Ram S. Journal of Electroceramics, Vol. 40, Issue 3 https://doi.org/10.1007/s10832-018-0126-1	journal	February 2018
Effect of BaTiO3 buffer layer on multiferroic properties of BiFeO3 thin films Yang, Pan; Kim, Kyung Man; Joh, Young-Gull Journal of Applied Physics, Vol. 105, Issue 6 https://doi.org/10.1063/1.3055413	journal	March 2009
Doping strategies for increased performance in BiFeO3 Khomchenko, V. A.; Kiselev, D. A.; Kopcewicz, M. Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 11 https://doi.org/10.1016/j.jmmm.2009.02.008	journal	June 2009
Towards a magnetoelectric memory Bibes, Manuel; Barthélémy, Agnès Nature Materials, Vol. 7, Issue 6 https://doi.org/10.1038/nmat2189	journal	June 2008
Epitaxially grown YMnO ₃ film: New candidate for nonvolatile memory devices Fujimura, Norifumi; Ishida, Tadashi; Yoshimura, Takeshi Applied Physics Letters, Vol. 69, Issue 7 https://doi.org/10.1063/1.117969	journal	August 1996
Phase evolution, magnetic and electrical properties in Sm-doped bismuth ferrite Nalwa, Kanwar Singh; Garg, Ashish Journal of Applied Physics, Vol. 103, Issue 4 https://doi.org/10.1063/1.2838483	journal	February 2008
Observation of magnetoelectric coupling in Bi0.7Dy0.3FeO3 thin films at room temperature Palkar, V. R.; Prashanthi, K. Applied Physics Letters, Vol. 93, Issue 13 https://doi.org/10.1063/1.2994692	journal	September 2008
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Polarization fatigue in ferroelectric films: Basic experimental findings, phenomenological scenarios, and microscopic features Tagantsev, A. K.; Stolichnov, I.; Colla, E. L. Journal of Applied Physics, Vol. 90, Issue 3 https://doi.org/10.1063/1.1381542	journal	August 2001
Microstructure, enhanced electric and magnetic properties of Bi0.9La0.1FeO3 ceramics prepared by microwave sintering Cai, Wei; Gao, Rongli; Fu, Chunlin Journal of Alloys and Compounds, Vol. 774 https://doi.org/10.1016/j.jallcom.2018.09.316	journal	February 2019
Effects of Nb-doping on electric and magnetic properties in multi-ferroic BiFeO3 ceramics Jun, Youn-Ki; Moon, Won-Taek; Chang, Chae-Myung Solid State Communications, Vol. 135, Issue 1-2 https://doi.org/10.1016/j.ssc.2005.03.038	journal	July 2005
Greatly reduced leakage current and conduction mechanism in aliovalent-ion-doped BiFeO3 Qi, Xiaoding; Dho, Joonghoe; Tomov, Rumen Applied Physics Letters, Vol. 86, Issue 6 https://doi.org/10.1063/1.1862336	journal	February 2005
The single-phase multiferroic oxides: from bulk to thin film Prellier, W.; Singh, M. P.; Murugavel, P. Journal of Physics: Condensed Matter, Vol. 17, Issue 48 https://doi.org/10.1088/0953-8984/17/48/C01	journal	November 2005
Magnetoelectricity at room temperature in the ${Bi}_{0.9 - x} {Tb}_{x} {La}_{0.1} {FeO}_{3}$ system Palkar, V. R.; Kundaliya, Darshan C.; Malik, S. K. Physical Review B, Vol. 69, Issue 21 https://doi.org/10.1103/PhysRevB.69.212102	journal	June 2004
Enhanced Photocatalytic Activity and Ferromagnetism in Gd Doped BiFeO ₃ Nanoparticles Guo, Renqing; Fang, Liang; Dong, Wen The Journal of Physical Chemistry C, Vol. 114, Issue 49 https://doi.org/10.1021/jp104660a	journal	November 2010
Magnetoelectric Devices for Spintronics Fusil, S.; Garcia, V.; Barthélémy, A. Annual Review of Materials Research, Vol. 44, Issue 1 https://doi.org/10.1146/annurev-matsci-070813-113315	journal	July 2014
Trends in electromechanical transduction Busch‐Vishniac, Ilene The Journal of the Acoustical Society of America, Vol. 103, Issue 5 https://doi.org/10.1121/1.421598	journal	May 1998
Magnetic-field-induced phase transition in ${BiFeO}_{3}$ observed by high-field electron spin resonance: Cycloidal to homogeneous spin order Ruette, Benjamin; Zvyagin, S.; Pyatakov, A. P. Physical Review B, Vol. 69, Issue 6 https://doi.org/10.1103/PhysRevB.69.064114	journal	February 2004
Electrical and memory window properties of Sr0.8-xBaxBi2.2Ta2-yZryO9 ferroelectric gate in metal-ferroelectric-insulator-semiconductor structure Bozgeyik, M. S.; Cross, J. S.; Ishiwara, H. Journal of Electroceramics, Vol. 28, Issue 2-3 https://doi.org/10.1007/s10832-012-9698-3	journal	March 2012
Effect of Cr substitution on the structure and electrical properties of BiFeO ₃ ceramics Chang, Fanggao; Zhang, Na; Yang, Feng Journal of Physics D: Applied Physics, Vol. 40, Issue 24 https://doi.org/10.1088/0022-3727/40/24/031	journal	November 2007
Investigations on the effect of Ba and Zr co-doping on the structural, thermal, electrical and magnetic properties of BiFeO3 multiferroics Abdul Kader, S. M.; Jain Ruth, D. E.; Veera Gajendra Babu, M. Ceramics International, Vol. 43, Issue 17 https://doi.org/10.1016/j.ceramint.2017.08.104	journal	December 2017
Large magnetic moment of gadolinium substituted topological insulator: Bi _1.98 Gd _0.02 Se ₃ Song, Y. R.; Yang, Fang; Yao, Meng-Yu Applied Physics Letters, Vol. 100, Issue 24 https://doi.org/10.1063/1.4729056	journal	June 2012
Strain behavior of lanthanum modified BiFeO3 thin films prepared via soft chemical method Simões, A. Z.; Aguiar, E. C.; Gonzalez, A. H. M. Journal of Applied Physics, Vol. 104, Issue 10 https://doi.org/10.1063/1.3029658	journal	November 2008
Spiral magnetic ordering in bismuth ferrite Sosnowska, I.; Neumaier, T. P.; Steichele, E. Journal of Physics C: Solid State Physics, Vol. 15, Issue 23 https://doi.org/10.1088/0022-3719/15/23/020	journal	August 1982
A Novel Approach to Improve Properties of BiFeO ₃ Nanomultiferroics Arya, Ghanshyam; Kotnala, Ravinder K.; Negi, Nainjeet Singh Journal of the American Ceramic Society, Vol. 97, Issue 5 https://doi.org/10.1111/jace.12782	journal	January 2014
Measurement of the Quadratic Magnetoelectric Effect on Single Crystalline BiFeO ₃ Tabares-Mun̄oz, C.; Rivera, J. -P.; Bezinges, A. Japanese Journal of Applied Physics, Vol. 24, Issue S2 https://doi.org/10.7567/JJAPS.24S2.1051	journal	January 1985
Multiferroics progress and prospects in thin films Ramesh, R.; Spaldin, Nicola A. Nature Materials, Vol. 6, Issue 1, p. 21-29 https://doi.org/10.1038/nmat1805	journal	January 2007
Study of room temperature magnetoelectric coupling in Ti substituted bismuth ferrite system Kumar, Manoj; Yadav, K. L. Journal of Applied Physics, Vol. 100, Issue 7 https://doi.org/10.1063/1.2349491	journal	October 2006
Electrical and nonlinear current-voltage characteristics of La-doped BiFeO 3 ceramics Yotburut, Benjaporn; Thongbai, Prasit; Yamwong, Teerapon Ceramics International, Vol. 43, Issue 7 https://doi.org/10.1016/j.ceramint.2017.01.094	journal	May 2017
Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite Ederer, Claude; Spaldin, Nicola A. Physical Review B, Vol. 71, Issue 6 https://doi.org/10.1103/PhysRevB.71.060401	journal	February 2005
Os doped YMnO3 multiferroic: A study investigating the electrical properties through tuning the doping level Polat, O.; Coskun, M.; Coskun, F. M. Journal of Alloys and Compounds, Vol. 752 https://doi.org/10.1016/j.jallcom.2018.04.200	journal	July 2018
Multiferroicity: the coupling between magnetic and polarization orders Wang, K. F.; Liu, J. -M.; Ren, Z. F. Advances in Physics, Vol. 58, Issue 4 https://doi.org/10.1080/00018730902920554	journal	July 2009
Role of oxygen vacancy and Fe–O–Fe bond angle in compositional, magnetic, and dielectric relaxation on Eu-substituted BiFeO ₃ nanoparticles Tamilselvan, A.; Balakumar, S.; Sakar, M. Dalton Trans., Vol. 43, Issue 15 https://doi.org/10.1039/C3DT52260A	journal	January 2014
Modulation in Multiferroic BiFeO ₃ : Cycloidal, Elliptical or SDW? Przeniosło, R.; Regulski, M.; Sosnowska, I. Journal of the Physical Society of Japan, Vol. 75, Issue 8 https://doi.org/10.1143/JPSJ.75.084718	journal	August 2006
Structural, Raman, and Dielectric Studies on Multiferroic Mn-doped Bi _{1− x} La _x FeO ₃ Ceramics Xing, Zhibiao; Zhu, Xinhua; Zhu, Jianmin Journal of the American Ceramic Society, Vol. 97, Issue 7 https://doi.org/10.1111/jace.12942	journal	April 2014
Controlling Self-Assembled Perovskite−Spinel Nanostructures Zheng, Haimei; Zhan, Qian; Zavaliche, Florin Nano Letters, Vol. 6, Issue 7 https://doi.org/10.1021/nl060401y	journal	July 2006
Thickness dependent ferroelectric and magnetic properties of Bi0.9Gd0.1Fe0.9Co0.1O3 films prepared by RF magnetron sputtering Kuang, Daihong; Tang, Ping; Yang, Shenghong Journal of Magnetism and Magnetic Materials, Vol. 397 https://doi.org/10.1016/j.jmmm.2015.08.083	journal	January 2016
Structure of a ferroelectric and ferroelastic monodomain crystal of the perovskite BiFeO3 Kubel, F.; Schmid, H. Acta Crystallographica Section B Structural Science, Vol. 46, Issue 6 https://doi.org/10.1107/S0108768190006887	journal	December 1990
Dispersion studies of La substitution on dielectric and ferroelectric properties of multiferroic BiFeO3 ceramic Sen, K.; Singh, K.; Gautam, Ashish Ceramics International, Vol. 38, Issue 1 https://doi.org/10.1016/j.ceramint.2011.06.059	journal	January 2012
Multiferroic and magnetoelectric materials Eerenstein, W.; Mathur, N. D.; Scott, J. F. Nature, Vol. 442, Issue 7104 https://doi.org/10.1038/nature05023	journal	August 2006
Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures Wang, J.; Neaton, J. B.; Zheng, H. Science, Vol. 299, Issue 5613, p. 1719-1722 https://doi.org/10.1126/science.1080615	journal	March 2003
Dielectric investigations of polycrystalline samarium bismuth ferrite ceramic Palaimiene, E.; Macutkevic, J.; Karpinsky, D. V. Applied Physics Letters, Vol. 106, Issue 1 https://doi.org/10.1063/1.4905344	journal	January 2015

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Title: Monitoring structural variation on Gd ratio of La modified bismuth ferrite ceramics with enhanced magnetization

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