Excited state dynamics of cis, cis -1,3-cyclooctadiene: UV pump VUV probe time-resolved photoelectron spectroscopy

Liu, Yusong; Chakraborty, Pratip; Matsika, Spiridoula; Weinacht, Thomas

doi:10.1063/5.0006920

Title: Excited state dynamics of cis, cis -1,3-cyclooctadiene: UV pump VUV probe time-resolved photoelectron spectroscopy

Journal Article · Fri Aug 21 00:00:00 EDT 2020 · Journal of Chemical Physics

DOI:https://doi.org/10.1063/5.0006920· OSTI ID:1800558

^[1];

^[2];

^[1]

Stony Brook Univ., NY (United States)
Temple Univ., Philadelphia, PA (United States)

We present UV pump, vacuum ultraviolet probe time-resolved photoelectron spectroscopy measurements of the excited state dynamics of cis,cis-1,3-cyclooctadiene. A 4.75 eV deep UV pump pulse launches a vibrational wave packet on the first electronically excited state, and the ensuing dynamics are probed via ionization using a 7.92 eV probe pulse. The experimental results indicate that the wave packet undergoes rapid internal conversion to the ground state in under 100 fs. Comparing the measurements with electronic structure and trajectory surface hopping calculations, we are able to interpret the features in the measured photoelectron spectra in terms of ionization to several states of the molecular cation.

View Accepted Manuscript (DOE)

View Accepted Manuscript (Publisher)

Cite

Export

Save

Research Organization:: Temple Univ., Philadelphia, PA (United States); State Univ. of New York (SUNY), Albany, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: FG02-08ER15983; FG02-08ER15984

OSTI ID:: 1800558

Alternate ID(s):: OSTI ID: 1647675

Journal Information:: Journal of Chemical Physics, Vol. 153, Issue 7; ISSN 0021-9606

Publisher:: American Institute of Physics (AIP)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 7 works

Citation information provided by
Web of Science

References (80)

Excited state non-adiabatic dynamics of the smallest polyene, trans 1,3-butadiene. II. Ab initio multiple spawning simulations Glover, William J.; Mori, Toshifumi; Schuurman, Michael S. The Journal of Chemical Physics, Vol. 148, Issue 16 https://doi.org/10.1063/1.5018130	journal	April 2018
Substituent Effects on Dynamics at Conical Intersections: Cyclopentadienes Schalk, Oliver; Boguslavskiy, Andrey E.; Stolow, Albert The Journal of Physical Chemistry A, Vol. 114, Issue 12 https://doi.org/10.1021/jp911286s	journal	April 2010
Coherent switching with decay of mixing: An improved treatment of electronic coherence for non-Born–Oppenheimer trajectories Zhu, Chaoyuan; Nangia, Shikha; Jasper, Ahren W. The Journal of Chemical Physics, Vol. 121, Issue 16 https://doi.org/10.1063/1.1793991	journal	January 2004
Femtosecond velocity map imaging of dissociative ionization dynamics in CF3IPresented at the Stereodynamics 2000 Conference on Dynamics and Stereodynamics of Chemical Reactions, El Escorial, Madrid, December 1–5, 2000. Roeterdink, Wim G.; Janssen, Maurice H. M. Physical Chemistry Chemical Physics, Vol. 4, Issue 4 https://doi.org/10.1039/b107897f	journal	January 2002
Ab Initio Multiple Spawning Dynamics of Excited Butadiene: Role of Charge Transfer Levine, Benjamin G.; Martínez, Todd J. The Journal of Physical Chemistry A, Vol. 113, Issue 46 https://doi.org/10.1021/jp907111u	journal	November 2009
Cis−Trans Isomerization of Organic Molecules and Biomolecules: Implications and Applications ^† Dugave, Christophe; Demange, Luc Chemical Reviews, Vol. 103, Issue 7 https://doi.org/10.1021/cr0104375	journal	July 2003
Molpro: a general-purpose quantum chemistry program package: Molpro Werner, Hans-Joachim; Knowles, Peter J.; Knizia, Gerald Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 2, Issue 2 https://doi.org/10.1002/wcms.82	journal	July 2011
Excited state dynamics of CH ₂ I ₂ and CH ₂ BrI studied with UV pump VUV probe photoelectron spectroscopy Horton, Spencer L.; Liu, Yusong; Forbes, Ruaridh The Journal of Chemical Physics, Vol. 150, Issue 17 https://doi.org/10.1063/1.5086665	journal	May 2019
From the (1B) Spectroscopic State to the Photochemical Product of the Ultrafast Ring-Opening of 1,3-Cyclohexadiene: A Spectral Observation of the Complete Reaction Path Pemberton, Christine C.; Zhang, Yao; Saita, Kenichiro The Journal of Physical Chemistry A, Vol. 119, Issue 33 https://doi.org/10.1021/acs.jpca.5b05672	journal	August 2015
Analytical Derivative Coupling for Multistate CASPT2 Theory Park, Jae Woo; Shiozaki, Toru Journal of Chemical Theory and Computation, Vol. 13, Issue 6 https://doi.org/10.1021/acs.jctc.7b00018	journal	May 2017
T IME -R ESOLVED P HOTOELECTRON S PECTROSCOPY OF M OLECULES AND C LUSTERS Neumark, Daniel M. Annual Review of Physical Chemistry, Vol. 52, Issue 1 https://doi.org/10.1146/annurev.physchem.52.1.255	journal	October 2001
Dynamics at Conical Intersections Schuurman, Michael S.; Stolow, Albert Annual Review of Physical Chemistry, Vol. 69, Issue 1 https://doi.org/10.1146/annurev-physchem-052516-050721	journal	April 2018
Femtosecond time‐resolved ionization spectroscopy of ultrafast internal‐conversion dynamics in polyatomic molecules: Theory and computational studies Seel, Matthias; Domcke, Wolfgang The Journal of Chemical Physics, Vol. 95, Issue 11 https://doi.org/10.1063/1.461816	journal	December 1991
Gaussian basis sets for use in correlated molecular calculations. I. The atoms boron through neon and hydrogen Dunning, Thom H. The Journal of Chemical Physics, Vol. 90, Issue 2 https://doi.org/10.1063/1.456153	journal	January 1989
Energy Conversion in Natural and Artificial Photosynthesis McConnell, Iain; Li, Gonghu; Brudvig, Gary W. Chemistry & Biology, Vol. 17, Issue 5 https://doi.org/10.1016/j.chembiol.2010.05.005	journal	May 2010
Insights for Light-Driven Molecular Devices from Ab Initio Multiple Spawning Excited-State Dynamics of Organic and Biological Chromophores Martínez, Todd J. Accounts of Chemical Research, Vol. 39, Issue 2 https://doi.org/10.1021/ar040202q	journal	February 2006
Isomerization Through Conical Intersections Levine, Benjamin G.; Martínez, Todd J. Annual Review of Physical Chemistry, Vol. 58, Issue 1 https://doi.org/10.1146/annurev.physchem.57.032905.104612	journal	May 2007
Substituent Effects on Dynamics at Conical Intersections: Cycloheptatrienes Schalk, Oliver; Boguslavskiy, Andrey E.; Schuurman, Michael S. The Journal of Physical Chemistry A, Vol. 117, Issue 40 https://doi.org/10.1021/jp309875m	journal	September 2013
Spectroscopic and Structural Probing of Excited-State Molecular Dynamics with Time-Resolved Photoelectron Spectroscopy and Ultrafast Electron Diffraction Liu, Yusong; Horton, Spencer L.; Yang, Jie Physical Review X, Vol. 10, Issue 2 https://doi.org/10.1103/physrevx.10.021016	journal	April 2020
Perspective: Nonadiabatic dynamics theory Tully, John C. The Journal of Chemical Physics, Vol. 137, Issue 22 https://doi.org/10.1063/1.4757762	journal	December 2012
Excited states dynamics of DNA and RNA bases: Characterization of a stepwise deactivation pathway in the gas phase Canuel, Clélia; Mons, Michel; Piuzzi, François The Journal of Chemical Physics, Vol. 122, Issue 7 https://doi.org/10.1063/1.1850469	journal	February 2005
Direct Observation of Ground-State Product Formation in a 1,3-Cyclohexadiene Ring-Opening Reaction Adachi, Shunsuke; Sato, Motoki; Suzuki, Toshinori The Journal of Physical Chemistry Letters, Vol. 6, Issue 3 https://doi.org/10.1021/jz502487r	journal	January 2015
Photochemistry of ethylene: A multireference configuration interaction investigation of the excited-state energy surfaces Barbatti, M.; Paier, J.; Lischka, H. The Journal of Chemical Physics, Vol. 121, Issue 23 https://doi.org/10.1063/1.1807378	journal	December 2004
Generation of sub-50-fs vacuum ultraviolet pulses by four-wave mixing in argon Beutler, Marcus; Ghotbi, Masood; Noack, Frank Optics Letters, Vol. 35, Issue 9 https://doi.org/10.1364/ol.35.001491	journal	January 2010
Excited state dynamics of cis , cis -1,3-cyclooctadiene: Non-adiabatic trajectory surface hopping Chakraborty, Pratip; Liu, Yusong; Weinacht, Thomas The Journal of Chemical Physics, Vol. 152, Issue 17 https://doi.org/10.1063/5.0005558	journal	May 2020
Ultrafast internal conversion dynamics of highly excited pyrrole studied with VUV/UV pump probe spectroscopy Horton, Spencer L.; Liu, Yusong; Chakraborty, Pratip The Journal of Chemical Physics, Vol. 146, Issue 6 https://doi.org/10.1063/1.4975765	journal	February 2017
Single-State Single-Reference and Multistate Multireference Zeroth-Order Hamiltonians in MS-CASPT2 and Conical Intersections Park, Jae Woo Journal of Chemical Theory and Computation, Vol. 15, Issue 7 https://doi.org/10.1021/acs.jctc.9b00067	journal	May 2019
Detailed Mechanism for Trans−Cis Photoisomerization of Butadiene Following a Femtosecond-Scale Laser Pulse Dou, Yusheng; Torralva, Ben R.; Allen, Roland E. The Journal of Physical Chemistry A, Vol. 107, Issue 42 https://doi.org/10.1021/jp034771b	journal	October 2003
Quantum control of energy flow in light harvesting Herek, Jennifer L.; Wohlleben, Wendel; Cogdell, Richard J. Nature, Vol. 417, Issue 6888, p. 533-535 https://doi.org/10.1038/417533a	journal	May 2002
Pulsed Nd:YAG laser-induced photoreaction of cis,cis-1,3-cyclooctadiene at 266 nm: selective cyclization to cis-bicyclo[4.2.0]oct-7-ene Komori-Orisaku, Keiko; Hirose, Yui; Iwakura, Izumi Photochemical & Photobiological Sciences, Vol. 16, Issue 2 https://doi.org/10.1039/c6pp00323k	journal	January 2017
Time-resolved photoelectron spectroscopy: from wavepackets to observables Wu, Guorong; Hockett, Paul; Stolow, Albert Physical Chemistry Chemical Physics, Vol. 13, Issue 41 https://doi.org/10.1039/c1cp22031d	journal	January 2011
Nuclear Energy Gradients for Internally Contracted Complete Active Space Second-Order Perturbation Theory: Multistate Extensions Vlaisavljevich, Bess; Shiozaki, Toru Journal of Chemical Theory and Computation, Vol. 12, Issue 8 https://doi.org/10.1021/acs.jctc.6b00572	journal	July 2016
BAGEL: Brilliantly Advanced General Electronic-structure Library: BAGEL Shiozaki, Toru Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 8, Issue 1 https://doi.org/10.1002/wcms.1331	journal	August 2017
Femtosecond Time-Resolved Photoelectron Imaging Suzuki, Toshinori Annual Review of Physical Chemistry, Vol. 57, Issue 1 https://doi.org/10.1146/annurev.physchem.57.032905.104601	journal	May 2006
Ultrafast internal conversion in ethylene. I. The excited state lifetime Tao, H.; Allison, T. K.; Wright, T. W. The Journal of Chemical Physics, Vol. 134, Issue 24 https://doi.org/10.1063/1.3604007	journal	June 2011
Extended multi-configuration quasi-degenerate perturbation theory: The new approach to multi-state multi-reference perturbation theory Granovsky, Alexander A. The Journal of Chemical Physics, Vol. 134, Issue 21 https://doi.org/10.1063/1.3596699	journal	June 2011
Communication: Extended multi-state complete active space second-order perturbation theory: Energy and nuclear gradients Shiozaki, Toru; Győrffy, Werner; Celani, Paolo The Journal of Chemical Physics, Vol. 135, Issue 8 https://doi.org/10.1063/1.3633329	journal	August 2011
A complete active space SCF method (CASSCF) using a density matrix formulated super-CI approach Roos, Björn O.; Taylor, Peter R.; Sigbahn, Per E. M. Chemical Physics, Vol. 48, Issue 2 https://doi.org/10.1016/0301-0104(80)80045-0	journal	May 1980
Imaging CF ₃ I conical intersection and photodissociation dynamics with ultrafast electron diffraction Yang, Jie; Zhu, Xiaolei; Wolf, Thomas J. A. Science, Vol. 361, Issue 6397 https://doi.org/10.1126/science.aat0049	journal	July 2018
Strong-field- versus weak-field-ionization pump-probe spectroscopy Horton, Spencer L.; Liu, Yusong; Chakraborty, Pratip Physical Review A, Vol. 98, Issue 5 https://doi.org/10.1103/physreva.98.053416	journal	November 2018
Simulated and Experimental Time-Resolved Photoelectron Spectra of the Intersystem Crossing Dynamics in 2-Thiouracil Mai, Sebastian; Mohamadzade, Abed; Marquetand, Philipp Molecules, Vol. 23, Issue 11 https://doi.org/10.3390/molecules23112836	journal	November 2018
Ultrafast internal conversion and photodissociation of molecules excited by femtosecond 155 nm laser pulses Farmanara, P.; Steinkellner, O.; Wick, M. T. The Journal of Chemical Physics, Vol. 111, Issue 14 https://doi.org/10.1063/1.479932	journal	October 1999
Involvement of a low-lying Rydberg state in the ultrafast relaxation dynamics of ethylene Champenois, Elio G.; Shivaram, Niranjan H.; Wright, Travis W. The Journal of Chemical Physics, Vol. 144, Issue 1 https://doi.org/10.1063/1.4939220	journal	January 2016
Competing ultrafast cis-trans isomerization and ring closure of cyclohepta-1,3-diene and cyclo-octa-1,3-diene Fuß, W.; Panja, S.; Schmid, W. E. Molecular Physics, Vol. 104, Issue 5-7 https://doi.org/10.1080/00268970500417408	journal	March 2006
Coincidence velocity map imaging using a single detector Zhao, Arthur; Sándor, Péter; Weinacht, Thomas The Journal of Chemical Physics, Vol. 147, Issue 1 https://doi.org/10.1063/1.4981917	journal	July 2017
The Ultrafast Pathway of Photon-Induced Electrocyclic Ring-Opening Reactions: The Case of 1,3-Cyclohexadiene Deb, Sanghamitra; Weber, Peter M. Annual Review of Physical Chemistry, Vol. 62, Issue 1 https://doi.org/10.1146/annurev.physchem.012809.103350	journal	May 2011
Role of Rydberg States in the Photochemical Dynamics of Ethylene Mori, Toshifumi; Glover, William J.; Schuurman, Michael S. The Journal of Physical Chemistry A, Vol. 116, Issue 11 https://doi.org/10.1021/jp2097185	journal	December 2011
Nonadiabatic dynamics with trajectory surface hopping method: Dynamics with surface hopping Barbatti, Mario Wiley Interdisciplinary Reviews: Computational Molecular Science, Vol. 1, Issue 4 https://doi.org/10.1002/wcms.64	journal	May 2011
The photochemical ring-opening of 1,3-cyclohexadiene imaged by ultrafast electron diffraction Wolf, T. J. A.; Sanchez, D. M.; Yang, J. Nature Chemistry, Vol. 11, Issue 6 https://doi.org/10.1038/s41557-019-0252-7	journal	April 2019
Femtosecond Time-Resolved Photoelectron Spectroscopy Stolow, Albert; Bragg, Arthur E.; Neumark, Daniel M. Chemical Reviews, Vol. 104, Issue 4 https://doi.org/10.1021/cr020683w	journal	April 2004
Femtosecond photochemical ring opening of 1,3-cyclohexadiene studied by time-resolved intense-field ionization Trushin, S. A.; Fuß, W.; Schikarski, T. The Journal of Chemical Physics, Vol. 106, Issue 22 https://doi.org/10.1063/1.474009	journal	June 1997
On-the-Fly CASPT2 Surface-Hopping Dynamics Park, Jae Woo; Shiozaki, Toru Journal of Chemical Theory and Computation, Vol. 13, Issue 8 https://doi.org/10.1021/acs.jctc.7b00559	journal	July 2017
Vibrationally assisted below-threshold ionization Horton, Spencer L.; Liu, Yusong; Chakraborty, Pratip Physical Review A, Vol. 95, Issue 6 https://doi.org/10.1103/physreva.95.063413	journal	June 2017
Ultrafast photodissociation dynamics and nonadiabatic coupling between excited electronic states of methanol probed by time-resolved photoelectron spectroscopy Champenois, Elio G.; Greenman, Loren; Shivaram, Niranjan The Journal of Chemical Physics, Vol. 150, Issue 11 https://doi.org/10.1063/1.5079549	journal	March 2019
Direct Observation of Electronic Relaxation Dynamics in Adenine via Time-Resolved Photoelectron Spectroscopy Ullrich, Susanne; Schultz, Thomas; Zgierski, Marek Z. Journal of the American Chemical Society, Vol. 126, Issue 8 https://doi.org/10.1021/ja030532q	journal	March 2004
Ab Initio Multiple Spawning Dynamics Using Multi-State Second-Order Perturbation Theory Tao, Hongli; Levine, Benjamin G.; Martínez, Todd J. The Journal of Physical Chemistry A, Vol. 113, Issue 49 https://doi.org/10.1021/jp9063565	journal	December 2009
Steady and Time-Resolved Photoelectron Spectra Based on Nuclear Ensembles Arbelo-González, Wilmer; Crespo-Otero, Rachel; Barbatti, Mario Journal of Chemical Theory and Computation, Vol. 12, Issue 10 https://doi.org/10.1021/acs.jctc.6b00704	journal	September 2016
Control of 1,3-Cyclohexadiene Photoisomerization Using Light-Induced Conical Intersections Kim, Jaehee; Tao, Hongli; White, James L. The Journal of Physical Chemistry A, Vol. 116, Issue 11 https://doi.org/10.1021/jp208384b	journal	December 2011
Molecular basis of photoprotection and control of photosynthetic light-harvesting Pascal, Andrew A.; Liu, Zhenfeng; Broess, Koen Nature, Vol. 436, Issue 7047 https://doi.org/10.1038/nature03795	journal	July 2005
Probing Ultrafast Internal Conversion through Conical Intersection via Time-Energy Map of Photoelectron Angular Anisotropy Horio, Takuya; Fuji, Takao; Suzuki, Yoshi-Ichi Journal of the American Chemical Society, Vol. 131, Issue 30 https://doi.org/10.1021/ja904780b	journal	August 2009
Ultrafast internal conversion in ethylene. II. Mechanisms and pathways for quenching and hydrogen elimination Allison, T. K.; Tao, H.; Glover, W. J. The Journal of Chemical Physics, Vol. 136, Issue 12 https://doi.org/10.1063/1.3697760	journal	March 2012
Femtosecond x-ray spectroscopy of an electrocyclic ring-opening reaction Attar, Andrew R.; Bhattacherjee, Aditi; Pemmaraju, C. D. Science, Vol. 356, Issue 6333 https://doi.org/10.1126/science.aaj2198	journal	April 2017
The origin of fluorescence in DNA thio-analogues Karsili, Tolga N. V.; Thodika, Mushir; Nguyen, Linh Chemical Physics, Vol. 515 https://doi.org/10.1016/j.chemphys.2018.08.049	journal	November 2018
Velocity map imaging of ions and electrons using electrostatic lenses: Application in photoelectron and photofragment ion imaging of molecular oxygen Eppink, André T. J. B.; Parker, David H. Review of Scientific Instruments, Vol. 68, Issue 9 https://doi.org/10.1063/1.1148310	journal	September 1997
Critical appraisal of the fewest switches algorithm for surface hopping Granucci, Giovanni; Persico, Maurizio The Journal of Chemical Physics, Vol. 126, Issue 13 https://doi.org/10.1063/1.2715585	journal	April 2007
Generation of 25 μJ vacuum ultraviolet pulses with sub-50 fs duration by noncollinear four-wave mixing in argon Ghotbi, M.; Beutler, M.; Noack, F. Optics Letters, Vol. 35, Issue 20 https://doi.org/10.1364/ol.35.003492	journal	January 2010
Dynamics of Light Harvesting in Photosynthesis Cheng, Yuan-Chung; Fleming, Graham R. Annual Review of Physical Chemistry, Vol. 60, Issue 1 https://doi.org/10.1146/annurev.physchem.040808.090259	journal	May 2009
Theory and Simulation of the Ultrafast Double-Bond Isomerization of Biological Chromophores Gozem, Samer; Luk, Hoi Ling; Schapiro, Igor Chemical Reviews, Vol. 117, Issue 22 https://doi.org/10.1021/acs.chemrev.7b00177	journal	October 2017
Femtosecond Dynamics of Small Molecules Studied with Vacuum-Ultraviolet Pulse Pairs Allison, T. K.; Wright, T. W.; Stooke, A. M. International Conference on Ultrafast Phenomena https://doi.org/10.1364/UP.2010.WB6	conference	January 2010
DNA/RNA: Building Blocks of Life Under UV Irradiation Gustavsson, Thomas; Improta, Roberto; Markovitsi, Dimitra The Journal of Physical Chemistry Letters, Vol. 1, Issue 13 https://doi.org/10.1021/jz1004973	journal	June 2010
Photoinduced Conversion of Silver Nanospheres to Nanoprisms Jin, R. Science, Vol. 294, Issue 5548 https://doi.org/10.1126/science.1066541	journal	November 2001
Revealing Deactivation Pathways Hidden in Time-Resolved Photoelectron Spectra Ruckenbauer, Matthias; Mai, Sebastian; Marquetand, Philipp Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep35522	journal	October 2016
Molecular dynamics with electronic transitions Tully, John C. The Journal of Chemical Physics, Vol. 93, Issue 2 https://doi.org/10.1063/1.459170	journal	July 1990
Probing ultrafast dynamics with time-resolved multi-dimensional coincidence imaging: butadiene Hockett, Paul; Ripani, Enrico; Rytwinski, Andrew Journal of Modern Optics, Vol. 60, Issue 17 https://doi.org/10.1080/09500340.2013.801525	journal	October 2013
Ab initio multiple spawning on laser-dressed states: a study of 1,3-cyclohexadiene photoisomerization via light-induced conical intersections Kim, Jaehee; Tao, Hongli; Martinez, Todd J. Journal of Physics B: Atomic, Molecular and Optical Physics, Vol. 48, Issue 16 https://doi.org/10.1088/0953-4075/48/16/164003	journal	July 2015
Control of retinal isomerization in bacteriorhodopsin in the high-intensity regime Florean, A. C.; Cardoza, D.; White, J. L. Proceedings of the National Academy of Sciences, Vol. 106, Issue 27 https://doi.org/10.1073/pnas.0904589106	journal	June 2009
Cyclohexadiene Revisited: A Time-Resolved Photoelectron Spectroscopy and ab Initio Study Schalk, Oliver; Geng, Ting; Thompson, Travis The Journal of Physical Chemistry A, Vol. 120, Issue 15 https://doi.org/10.1021/acs.jpca.5b10928	journal	April 2016
Ultrafast Internal Conversion of Electronically Excited RNA and DNA Nucleosides in Water Pecourt, Jean-Marc L.; Peon, Jorge; Kohler, Bern Journal of the American Chemical Society, Vol. 122, Issue 38 https://doi.org/10.1021/ja0021520	journal	September 2000
Excited state non-adiabatic dynamics of the smallest polyene, trans 1,3-butadiene. I. Time-resolved photoelectron-photoion coincidence spectroscopy Boguslavskiy, Andrey E.; Schalk, Oliver; Gador, Niklas The Journal of Chemical Physics, Vol. 148, Issue 16 https://doi.org/10.1063/1.5016452	journal	April 2018
Two-Photon Excited State Dynamics of Dark Valence, Rydberg, and Superexcited States in 1,3-Butadiene Schalk, Oliver; Boguslavskiy, Andrey E.; Stolow, Albert The Journal of Physical Chemistry Letters, Vol. 5, Issue 3 https://doi.org/10.1021/jz402725u	journal	January 2014

Similar Records

Excited state dynamics of CH₂I₂ and CH₂BrI studied with UV pump VUV probe photoelectron spectroscopy

Journal Article · Tue May 07 00:00:00 EDT 2019 · Journal of Chemical Physics · OSTI ID:1800558

Horton, Spencer L.; Liu, Yusong; Forbes, Ruaridh; +7 more

Excited state dynamics of cis,cis-1,3-cyclooctadiene: Non-adiabatic trajectory surface hopping

Journal Article · Mon May 04 00:00:00 EDT 2020 · Journal of Chemical Physics · OSTI ID:1800558

Chakraborty, Pratip; Liu, Yusong; Weinacht, Thomas; +1 more

Vibrationally assisted below-threshold ionization

Journal Article · Thu Jun 15 00:00:00 EDT 2017 · Physical Review A · OSTI ID:1800558

Horton, Spencer L.; Liu, Yusong; Chakraborty, Pratip; +2 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Chemistry
Physics
Photoelectron spectroscopy
Absorption spectroscopy
Signal processing
Optical materials
HOMO and LUMO
Time-resolved photoemission spectroscopy
Potential energy surfaces
Isomerization
Photochemistry
Surface hopping

Title: Excited state dynamics of cis, cis -1,3-cyclooctadiene: UV pump VUV probe time-resolved photoelectron spectroscopy

Citation Formats

References (80)

Similar Records

Related Subjects