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Title: Two stage, low temperature, catalyzed fluidized bed incineration with in situ neutralization for radioactive mixed wastes

Technical Report ·
DOI:https://doi.org/10.2172/171999· OSTI ID:171999

A two stage, low temperature, catalyzed fluidized bed incineration process is proving successful at incinerating hazardous wastes containing nuclear material. The process operates at 550{degrees}C and 650{degrees}C in its two stages. Acid gas neutralization takes place in situ using sodium carbonate as a sorbent in the first stage bed. The feed material to the incinerator is hazardous waste-as defined by the Resource Conservation and Recovery Act-mixed with radioactive materials. The radioactive materials are plutonium, uranium, and americium that are byproducts of nuclear weapons production. Despite its low temperature operation, this system successfully destroyed poly-chlorinated biphenyls at a 99.99992% destruction and removal efficiency. Radionuclides and volatile heavy metals leave the fluidized beds and enter the air pollution control system in minimal amounts. Recently collected modeling and experimental data show the process minimizes dioxin and furan production. The report also discusses air pollution, ash solidification, and other data collected from pilot- and demonstration-scale testing. The testing took place at Rocky Flats Environmental Technology Site, a US Department of Energy facility, in the 1970s, 1980s, and 1990s.

Research Organization:
Rocky Flats Environmental Technology Site, Golden, CO (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC34-90DP62349
OSTI ID:
171999
Report Number(s):
RFP-4966; ON: DE96003807; TRN: 96:003371
Resource Relation:
Other Information: PBD: 17 May 1995
Country of Publication:
United States
Language:
English

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