Halloysite Clay Nanotubes for Loading and Sustained Release of Functional Compounds

Lvov, Yuri; Wang, Wencai; Zhang, Liqun; Fakhrullin, Rawil

doi:10.1002/adma.201502341

Title: Halloysite Clay Nanotubes for Loading and Sustained Release of Functional Compounds

Journal Article · Tue Oct 06 00:00:00 EDT 2015 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201502341· OSTI ID:1673766

Lvov, Yuri ^[1]; Wang, Wencai ^[2]; Zhang, Liqun ^[2]; Fakhrullin, Rawil ^[3]

Louisiana Tech Univ., Ruston, LA (United States); Kazan Federal Univ. (Russia)
Beijing Univ. of Chemical Technology (China)
Kazan Federal Univ. (Russia)

Halloysite is an alumosilicate tubular clay with a diameter of 50 nm, an inner lumen of 15 nm and a length of 600-900 nm. It is a natural biocompatible nanomaterial available in thousands of tons at low price, which makes it a good candidate for nanoarchitectural composites. The inner lumen of halloysite may be adjusted by etching to 20-30% of the tube volume and loading with functional agents (antioxidants, anticorrosion agents, flame-retardant agents, drugs, or proteins) allowing for formulations with sustained release tuned by the tube end-stoppers for hours and days. Clogging the tube ends in polymeric composites allows further extension of the release time. Thus, antioxidant-loaded halloysite doped into rubber enhances anti-aging properties for at least 12 months. The addition of 3-5 wt% of halloysite increases the strength of polymeric materials, and the possibility of the tube's orientation promises a gradient of properties. Halloysite nanotubes are a promising mesoporous media for catalytic nanoparticles that may be seeded on the tube surface or synthesized exclusively in the lumens, providing enhanced catalytic properties, especially at high temperatures. Finally, in vitro and in vivo studies on biological cells and worms indicate the safety of halloysite, and tests for efficient adsorption of mycotoxins in animals' stomachs are also carried out.

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Research Organization:: Louisiana State Univ., Baton Rouge, LA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Louisiana Board of Regents; Alexander von Humboldt Foundation; National Natural Science Foundation of China (NSFC); Russian Science Foundation (RSF)

Grant/Contract Number:: SC0012432; 51320105012; 81330043; 14–14–00924

OSTI ID:: 1673766

Journal Information:: Advanced Materials, Vol. 28, Issue 6; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Thermal stability and flame retardant effects of halloysite nanotubes on poly(propylene) Du, Mingliang; Guo, Baochun; Jia, Demin European Polymer Journal, Vol. 42, Issue 6 https://doi.org/10.1016/j.eurpolymj.2005.12.006	journal	June 2006
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Modified Halloysite Nanotubes: Nanoarchitectures for Enhancing the Capture of Oils from Vapor and Liquid Phases Cavallaro, Giuseppe; Lazzara, Giuseppe; Milioto, Stefana ACS Applied Materials & Interfaces, Vol. 6, Issue 1 https://doi.org/10.1021/am404693r	journal	December 2013
Halloysite Clay Nanotubes for Controlled Release of Protective Agents Lvov, Yuri M.; Shchukin, Dmitry G.; Möhwald, Helmuth ACS Nano, Vol. 2, Issue 5 https://doi.org/10.1021/nn800259q	journal	May 2008
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Direct Assembly of Silica Nanospheres on Halloysite Nanotubes for “Green” Ultrahydrophobic Cotton Fabrics Patil, Namrata V.; Netravali, Anil N. Advanced Sustainable Systems, Vol. 3, Issue 8 https://doi.org/10.1002/adsu.201900009	journal	June 2019
Core/shell structured halloysite/polyaniline nanotubes with enhanced electrochromic properties Hu, Fei; Xu, Jianlong; Zhang, Sihang Journal of Materials Chemistry C, Vol. 6, Issue 21 https://doi.org/10.1039/c8tc01163j	journal	January 2018
Halloysite Nanotubes: Controlled Access and Release by Smart Gates Cavallaro, Giuseppe; Danilushkina, Anna; Evtugyn, Vladimir Nanomaterials, Vol. 7, Issue 8 https://doi.org/10.3390/nano7080199	journal	July 2017
Environmentally Benign Halloysite Nanotube Multilayer Assembly Significantly Reduces Polyurethane Flammability Smith, Ryan J.; Holder, Kevin M.; Ruiz, Sofia Advanced Functional Materials, Vol. 28, Issue 27 https://doi.org/10.1002/adfm.201703289	journal	August 2017
Preparation of palladated porous nitrogen-doped carbon using halloysite as porogen: disclosing its utility as a hydrogenation catalyst Sadjadi, Samahe; Malmir, Masoumeh; Lazzara, Giuseppe Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-59003-5	journal	February 2020
Preparation of hollow iron/halloysite nanocomposites with enhanced electromagnetic performances Chen, Xue-Gang; Li, Ru-Chang; Zhang, Ao-Bo Royal Society Open Science, Vol. 5, Issue 1 https://doi.org/10.1098/rsos.171657	journal	January 2018
The Effect of Halloysite Addition on the Material Properties of Chitosan–Halloysite Hydrogel Composites Gels, Vol. 5, Issue 3 https://doi.org/10.3390/gels5030040	journal	August 2019
Antimicrobial Membranes of Bio-Based PA 11 and HNTs Filled with Lysozyme Obtained by an Electrospinning Process Bugatti, Valeria; Vertuccio, Luigi; Viscusi, Gianluca Nanomaterials, Vol. 8, Issue 3 https://doi.org/10.3390/nano8030139	journal	March 2018
Palladated Nanocomposite of Halloysite-Nitrogen-Doped Porous Carbon Prepared from a Novel Cyano-/Nitrile-Free Task Specific Ionic Liquid: An Efficient Catalyst for Hydrogenation Heravi, Majid Mommahed; Sadjadi, Samahe; Akbari, Maryam figshare https://doi.org/10.6084/m9.figshare.13081841.v1	text	January 2020

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