In situ δ13C and δ18O microanalysis by SIMS: A method for characterizing the carbonate components of natural and engineered CO2-reservoirs

Śliwiński, Maciej G.; Kitajima, Kouki; Kozdon, Reinhard; Spicuzza, Michael J.; Denny, Adam; Valley, John W.

doi:10.1016/j.ijggc.2016.12.013

Title: In situ δ¹³C and δ¹⁸O microanalysis by SIMS: A method for characterizing the carbonate components of natural and engineered CO₂-reservoirs

Journal Article · Tue Jan 10 00:00:00 EST 2017 · International Journal of Greenhouse Gas Control

DOI:https://doi.org/10.1016/j.ijggc.2016.12.013· OSTI ID:1661870

Śliwiński, Maciej G. ^[1]; Kitajima, Kouki ^[1]; Kozdon, Reinhard ^[2]; Spicuzza, Michael J. ^[1]; Denny, Adam ^[1]; Valley, John W. ^[1]

Univ. of Wisconsin, Madison, WI (United States)
Univ. of Wisconsin, Madison, WI (United States); Columbia Univ., Palisades, NY (United States)

This work addresses the potential utility of in situ carbon and oxygen isotope microanalysis (δ¹³C and δ¹⁸O) by secondary ion mass spectrometry (SIMS) in carbon sequestration research. A desirable long-term consequence of CO₂-injection into underground rock formations at prospective sequestration sites (such as deep saline sandstone aquifers capped by impermeable strata) is the precipitation of carbonate mineral cements, the isotopic fingerprinting of which is a central theme here. More specifically, we focus on the unique advantage of the SIMS technique, which lies in the capability of analyzing very small sample volumes that are otherwise inaccessible to sampling techniques in conventional isotope ratio mass spectrometry (IRMS). For example, single carbonate crystallites as small as 3–10 μm across can be readily analyzed by SIMS with sub per-mil (‰) accuracy and precision. Importantly, the ability to perform micrometer-scale measurements in situ from either thin sections or 1-in. (25 mm) diameter polished core plugs preserves the petrographic context of measured carbonate δ¹⁸O and δ¹³C values. Here, we provide a preliminary characterization of the pre-injection mineralogy and isotopic fingerprints of carbonate cements in the Mount Simon Sandstone reservoir and the overlying silty-shaly caprock (the Eau Claire Formation) at the Illinois Basin Decatur Project, a demonstration and research site for exploring the feasibility of long-term CO₂ storage in a deep saline aquifer. By drawing upon published data on ambient reservoir conditions and the isotopic composition of the injected CO₂, we make simple predictions regarding possible δ¹³C values of calcite, dolomite-ankerite, and siderite cements that may form in response to long-term CO₂ storage.

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Research Organization:: Univ. of Wisconsin, Madison, WI (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-93ER14389

OSTI ID:: 1661870

Alternate ID(s):: OSTI ID: 1416798

Journal Information:: International Journal of Greenhouse Gas Control, Vol. 57; ISSN 1750-5836

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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58 GEOSCIENCES
Carbon sequestration
Natural analogues
Carbonate cements
Carbon isotopes
SIMS microanalysis
Illinois Basin
Illinois Basin Decatur Project

Title: In situ δ13C and δ18O microanalysis by SIMS: A method for characterizing the carbonate components of natural and engineered CO2-reservoirs

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Title: In situ δ¹³C and δ¹⁸O microanalysis by SIMS: A method for characterizing the carbonate components of natural and engineered CO₂-reservoirs