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Title: Fabrication of uranium nitride

Patent ·
OSTI ID:1632559

A method of producing uranium nitride (e.g., uranium mononitride) and/or uranium-containing intermediates that can be used to further produce uranium nitride includes reacting a reaction mixture comprising uranium carbide with a gas comprising hydrogen and nitrogen, cooling the reaction mixture to a temperature suitable to produce a phase comprising U2N3, and heating the reaction mixture to a temperature suitable to convert the phase comprising U2N3 to a phase comprising UN. The method produces highly purified UN, is insensitive to excess carbon reactants, and can be readily integrated into existing uranium production facilities as part of a continuous process.

Research Organization:
Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC52-06NA25396
Assignee:
Triad National Security, LLC (Los Alamos, NM)
Patent Number(s):
10,562,771
Application Number:
15/889,608
OSTI ID:
1632559
Resource Relation:
Patent File Date: 02/06/2018
Country of Publication:
United States
Language:
English

References (19)

Kinetics of the carbothermic synthesis of uranium mononitride microspheres journal November 1991
Diffusion of carbon and uranium in uranium carbide journal September 1968
Preparation of Compounds of Uranium and Nonmetals patent December 1950
Fabrication of (U, Pu)N fuel pellets journal December 1989
Investigation of the reaction UO2+x + PuO2 + C + N2 by thermogravimetry journal August 1988
Kinetics of the UO 2 -C-N 2 Reaction at 1700°C journal December 1972
Nuclear Reactor Fuel Material and a Method of Preparing the Same patent November 1966
The crystal structure of UC2 journal November 1966
Particulate Metal Fuels Used in Power Generation, Recycling Systems, and Small Modular Reactors patent-application December 2010
Chemical thermodynamic representation of nonstoichiometry in 〈UO2−xN3x4〉 journal April 1989
Preparing Microspheres of Actinide Nitrides from Carbon Containing Oxide Sols patent September 1975
Multi stage selective catalytic cracking process and a system for producing high yield of middle distillate products from heavy hydrocarbon feedstocks patent April 2006
Investigations on uranium carbonitrides (I) journal June 1975
Fabrication and testing of uranium nitride fuel for space power reactors journal February 1988
Carbothermic synthesis of 820μm uranium nitride kernels: Literature review, thermodynamics, analysis, and related experiments journal May 2014
Preparation of uranium nitride in the form of microspheres journal June 1992
Mechanism and Kinetics for the Formation of Uranium Mononitride by the Reaction of Uranium Dioxide with Carbon and Nitrogen journal January 1978
Thermodynamics of carbothermic synthesis of actinide mononitrides journal August 1997
Uranium nitride as LWR TRISO fuel: Thermodynamic modeling of U–C–N journal August 2012

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