Systematic Engineering of Single Substitution in Zirconium Metal–Organic Frameworks toward High-Performance Catalysis

Huang, Ning; Yuan, Shuai; Drake, Hannah; Yang, Xinyu; Pang, Jiandong; Qin, Junsheng; Li, Jialuo; Zhang, Yingmu; Wang, Qi; Jiang, Donglin; Zhou, Hong-Cai

doi:10.1021/jacs.7b09553

Title: Systematic Engineering of Single Substitution in Zirconium Metal–Organic Frameworks toward High-Performance Catalysis

Journal Article · Fri Nov 24 00:00:00 EST 2017 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.7b09553· OSTI ID:1470071

^[1]; Yuan, Shuai ^[1]; Drake, Hannah ^[1]; Yang, Xinyu ^[1]; Pang, Jiandong ^[1]; Qin, Junsheng ^[1]; Li, Jialuo ^[1]; Zhang, Yingmu ^[1]; Wang, Qi ^[1];

^[2];

^[1]

Texas A & M Univ., College Station, TX (United States). Dept. of Chemistry
Field of Environment and Energy, School of Materials Science, Japan Advanced Inst. of Science and Technology (Japan)

Zirconium-based metal–organic frameworks (Zr-MOFs) exhibit great structural tunability and outstanding chemical stability, rendering them promising candidates for a wide range of practical applications. In this work, we synthesized a series of isostructural PCN-224 analogues functionalized by ethyl, bromo, chloro, and fluoro groups on the porphyrin unit, which allowed us to explicitly study the effects of electron-donating and electron-withdrawing substituents on catalytic performance in MOFs. Owing to the different electronic properties of ethyl, bromo, chloro, and fluoro substitutes, the molecular-level control over the chemical environment surrounding a catalytic center could be readily achieved in our MOFs. To investigate the effects of these substitutes on catalytic activity and selectivity, the oxidation of 3-methylpentane to corresponding alcohols and ketones was utilized as a model reaction. Within these five analogues of PCN-224, an extremely high turnover number of 7680 and turnover frequency of 10 240 h^–1 was achieved by simply altering the substitutes on porphyrin rings. Moreover, a remarkable 99% selectivity of the tertiary alcohol over the five other possible by-products are realized. We demonstrate that this strategy can be used to efficiently screen a suitable peripheral environment around catalytic cores in MOFs for catalysis.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations Relevant to Clean Energy Technologies (CGS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Fossil Energy (FE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Sustainable Transportation Office. Hydrogen Fuel Cell Technologies Office

Grant/Contract Number:: SC0001015

OSTI ID:: 1470071

Journal Information:: Journal of the American Chemical Society, Vol. 139, Issue 51; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 78 works

Citation information provided by
Web of Science

References (72)

Enzymelike Catalysis of the Nazarov Cyclization by Supramolecular Encapsulation Hastings, Courtney J.; Pluth, Michael D.; Bergman, Robert G. Journal of the American Chemical Society, Vol. 132, Issue 20 https://doi.org/10.1021/ja102633e	journal	May 2010
Supramolecular catalysis beyond enzyme mimics Meeuwissen, Jurjen; Reek, Joost N. H. Nature Chemistry, Vol. 2, Issue 8 https://doi.org/10.1038/nchem.744	journal	July 2010
Enzyme-like Catalysis by Molecularly Imprinted Polymers Wulff, Günter Chemical Reviews, Vol. 102, Issue 1 https://doi.org/10.1021/cr980039a	journal	January 2002
Catalytic accordions Giuseppone, Nicolas; Lutz, Jean-François Nature, Vol. 473, Issue 7345 https://doi.org/10.1038/473040a	journal	May 2011
Biomimetic enzyme nanocomplexes and their use as antidotes and preventive measures for alcohol intoxication Liu, Yang; Du, Juanjuan; Yan, Ming Nature Nanotechnology, Vol. 8, Issue 3 https://doi.org/10.1038/nnano.2012.264	journal	February 2013
Biomimetic Chemistry and Artificial Enzymes: Catalysis by Design Breslow, Ronald Accounts of Chemical Research, Vol. 28, Issue 3 https://doi.org/10.1021/ar00051a008	journal	March 1995
Biomimetic approaches to artificial photosynthesis Hammarström, Leif; Wasielewski, Michael R. Energy & Environmental Science, Vol. 4, Issue 7 https://doi.org/10.1039/c1ee90023d	journal	January 2011
Biologically inspired oxidation catalysis Que, Lawrence; Tolman, William B. Nature, Vol. 455, Issue 7211 https://doi.org/10.1038/nature07371	journal	September 2008
Biomimetic Catalysis Marchetti, Louis; Levine, Mindy ACS Catalysis, Vol. 1, Issue 9 https://doi.org/10.1021/cs200171u	journal	July 2011
Design of Biomimetic Catalysts by Molecular Imprinting in Synthetic Polymers: The Role of Transition State Stabilization Wulff, GÜnter; Liu, Junqiu Accounts of Chemical Research, Vol. 45, Issue 2 https://doi.org/10.1021/ar200146m	journal	August 2011
Pore Environment Effects on Catalytic Cyclohexane Oxidation in Expanded Fe ₂ (dobdc) Analogues Xiao, Dianne J.; Oktawiec, Julia; Milner, Phillip J. Journal of the American Chemical Society, Vol. 138, Issue 43 https://doi.org/10.1021/jacs.6b08417	journal	October 2016
Molecular Designs for Controlling the Local Environments around Metal Ions Cook, Sarah A.; Borovik, A. S. Accounts of Chemical Research, Vol. 48, Issue 8 https://doi.org/10.1021/acs.accounts.5b00212	journal	July 2015
The Use of Calixarenes in Metal-Based Catalysis Homden, Damien M.; Redshaw, Carl Chemical Reviews, Vol. 108, Issue 12 https://doi.org/10.1021/cr8002196	journal	December 2008
Biomimetic Reactions Catalyzed by Cyclodextrins and Their Derivatives Breslow, Ronald; Dong, Steven D. Chemical Reviews, Vol. 98, Issue 5 https://doi.org/10.1021/cr970011j	journal	July 1998
Artificial Enzymes Murakami, Yukito; Kikuchi, Jun-ichi; Hisaeda, Yoshio Chemical Reviews, Vol. 96, Issue 2 https://doi.org/10.1021/cr9403704	journal	January 1996
Bioinspired Hydrogen Bond Motifs in Ligand Design: The Role of Noncovalent Interactions in Metal Ion Mediated Activation of Dioxygen Borovik, A. S. Accounts of Chemical Research, Vol. 38, Issue 1 https://doi.org/10.1021/ar030160q	journal	January 2005
Small-Molecule H-Bond Donors in Asymmetric Catalysis Doyle, Abigail G.; Jacobsen, Eric N. Chemical Reviews, Vol. 107, Issue 12 https://doi.org/10.1021/cr068373r	journal	December 2007
Catalysis of the electrochemical reduction of carbon dioxide Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35360A	journal	January 2013
Role of the Secondary Coordination Sphere in Metal-Mediated Dioxygen Activation Shook, Ryan L.; Borovik, A. S. Inorganic Chemistry, Vol. 49, Issue 8 https://doi.org/10.1021/ic901550k	journal	April 2010
The roles of the first and second coordination spheres in the design of molecular catalysts for H ₂ production and oxidation Rakowski DuBois, M.; DuBois, Daniel L. Chem. Soc. Rev., Vol. 38, Issue 1 https://doi.org/10.1039/B801197B	journal	January 2009
Recent Developments in the Synthesis of Supported Catalysts Munnik, Peter; de Jongh, Petra E.; de Jong, Krijn P. Chemical Reviews, Vol. 115, Issue 14 https://doi.org/10.1021/cr500486u	journal	June 2015
Carbon Materials as Catalyst Supports and Catalysts in the Transformation of Biomass to Fuels and Chemicals Lam, Edmond; Luong, John H. T. ACS Catalysis, Vol. 4, Issue 10 https://doi.org/10.1021/cs5008393	journal	September 2014
Covalent organic frameworks: a materials platform for structural and functional designs Huang, Ning; Wang, Ping; Jiang, Donglin Nature Reviews Materials, Vol. 1, Issue 10 https://doi.org/10.1038/natrevmats.2016.68	journal	September 2016
Porous materials in catalysis: challenges for mesoporous materials Perego, Carlo; Millini, Roberto Chem. Soc. Rev., Vol. 42, Issue 9 https://doi.org/10.1039/C2CS35244C	journal	January 2013
Hierarchical porous materials: catalytic applications Parlett, Christopher M. A.; Wilson, Karen; Lee, Adam F. Chem. Soc. Rev., Vol. 42, Issue 9 https://doi.org/10.1039/C2CS35378D	journal	January 2013
Recent advances in zeolite chemistry and catalysis Weckhuysen, Bert M.; Yu, Jihong Chemical Society Reviews, Vol. 44, Issue 20 https://doi.org/10.1039/C5CS90100F	journal	January 2015
Nanosized microporous crystals: emerging applications Mintova, Svetlana; Jaber, Maguy; Valtchev, Valentin Chemical Society Reviews, Vol. 44, Issue 20 https://doi.org/10.1039/C5CS00210A	journal	January 2015
Introduction to Metal–Organic Frameworks Zhou, Hong-Cai; Long, Jeffrey R.; Yaghi, Omar M. Chemical Reviews, Vol. 112, Issue 2, p. 673-674 https://doi.org/10.1021/cr300014x	journal	September 2011
The Chemistry and Applications of Metal-Organic Frameworks Furukawa, H.; Cordova, K. E.; O'Keeffe, M. Science, Vol. 341, Issue 6149, p. 1230444-1230444 https://doi.org/10.1126/science.1230444	journal	August 2013
Zeolite-like metal–organic frameworks (ZMOFs): design, synthesis, and properties Eddaoudi, Mohamed; Sava, Dorina F.; Eubank, Jarrod F. Chemical Society Reviews, Vol. 44, Issue 1 https://doi.org/10.1039/C4CS00230J	journal	January 2015
Methane storage in metal–organic frameworks He, Yabing; Zhou, Wei; Qian, Guodong Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00032C	journal	January 2014
Reticular synthesis and the design of new materials Yaghi, Omar M.; O'Keeffe, Michael; Ockwig, Nathan W. Nature, Vol. 423, Issue 6941, p. 705-714 https://doi.org/10.1038/nature01650	journal	June 2003
Metal–organic and covalent organic frameworks as single-site catalysts Rogge, S. M. J.; Bavykina, A.; Hajek, J. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C7CS00033B	journal	January 2017
Covalent Chemistry beyond Molecules Jiang, Juncong; Zhao, Yingbo; Yaghi, Omar M. Journal of the American Chemical Society, Vol. 138, Issue 10 https://doi.org/10.1021/jacs.5b10666	journal	February 2016
Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene Cui, X.; Chen, K.; Xing, H. Science, Vol. 353, Issue 6295 https://doi.org/10.1126/science.aaf2458	journal	May 2016
UTSA-74: A MOF-74 Isomer with Two Accessible Binding Sites per Metal Center for Highly Selective Gas Separation Luo, Feng; Yan, Changsheng; Dang, Lilong Journal of the American Chemical Society, Vol. 138, Issue 17 https://doi.org/10.1021/jacs.6b02030	journal	April 2016
Bimetallic Metal–Organic Frameworks for Gas Storage and Separation Yang, Xinchun; Xu, Qiang Crystal Growth & Design, Vol. 17, Issue 4 https://doi.org/10.1021/acs.cgd.7b00166	journal	March 2017
Cooperative insertion of CO2 in diamine-appended metal-organic frameworks McDonald, Thomas M.; Mason, Jarad A.; Kong, Xueqian Nature, Vol. 519, Issue 7543 https://doi.org/10.1038/nature14327	journal	March 2015
Partitioning MOF-5 into Confined and Hydrophobic Compartments for Carbon Capture under Humid Conditions Ding, Nan; Li, Haiwei; Feng, Xiao Journal of the American Chemical Society, Vol. 138, Issue 32 https://doi.org/10.1021/jacs.6b06051	journal	August 2016
Luminescent Functional Metal–Organic Frameworks Cui, Yuanjing; Yue, Yanfeng; Qian, Guodong Chemical Reviews, Vol. 112, Issue 2 https://doi.org/10.1021/cr200101d	journal	June 2011
Phenyl Ring Dynamics in a Tetraphenylethylene-Bridged Metal–Organic Framework: Implications for the Mechanism of Aggregation-Induced Emission Shustova, Natalia B.; Ong, Ta-Chung; Cozzolino, Anthony F. Journal of the American Chemical Society, Vol. 134, Issue 36 https://doi.org/10.1021/ja306042w	journal	August 2012
Confinement of pyridinium hemicyanine dye within an anionic metal-organic framework for two-photon-pumped lasing Yu, Jiancan; Cui, Yuanjing; Xu, Hui Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3719	journal	October 2013
Tuning the Luminescence of Metal–Organic Frameworks for Detection of Energetic Heterocyclic Compounds Guo, Yuexin; Feng, Xiao; Han, Tianyu Journal of the American Chemical Society, Vol. 136, Issue 44 https://doi.org/10.1021/ja508962m	journal	October 2014
Luminescent metal–organic frameworks for chemical sensing and explosive detection Hu, Zhichao; Deibert, Benjamin J.; Li, Jing Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C4CS00010B	journal	January 2014
Rigidifying Fluorescent Linkers by Metal–Organic Framework Formation for Fluorescence Blue Shift and Quantum Yield Enhancement Wei, Zhangwen; Gu, Zhi-Yuan; Arvapally, Ravi K. Journal of the American Chemical Society, Vol. 136, Issue 23 https://doi.org/10.1021/ja5006866	journal	May 2014
Metal–Organic Framework Materials as Chemical Sensors Kreno, Lauren E.; Leong, Kirsty; Farha, Omar K. Chemical Reviews, Vol. 112, Issue 2, p. 1105-1125 https://doi.org/10.1021/cr200324t	journal	September 2011
Metal–organic frameworks: functional luminescent and photonic materials for sensing applications Lustig, William P.; Mukherjee, Soumya; Rudd, Nathan D. Chemical Society Reviews, Vol. 46, Issue 11 https://doi.org/10.1039/C6CS00930A	journal	January 2017
Ion Conductivity and Transport by Porous Coordination Polymers and Metal–Organic Frameworks Horike, Satoshi; Umeyama, Daiki; Kitagawa, Susumu Accounts of Chemical Research, Vol. 46, Issue 11 https://doi.org/10.1021/ar300291s	journal	June 2013
Ionic Conductivity in the Metal-Organic Framework UiO-66 by Dehydration and Insertion of Lithium tert -Butoxide Ameloot, Rob; Aubrey, Michael; Wiers, Brian M. Chemistry - A European Journal, Vol. 19, Issue 18 https://doi.org/10.1002/chem.201300326	journal	March 2013
Proton Conduction with Metal-Organic Frameworks Shimizu, G. K. H.; Taylor, J. M.; Kim, S. Science, Vol. 341, Issue 6144 https://doi.org/10.1126/science.1239872	journal	July 2013
Single Crystal Proton Conduction Study of a Metal Organic Framework of Modest Water Stability Joarder, Biplab; Lin, Jian-Bin; Romero, Zaida Journal of the American Chemical Society, Vol. 139, Issue 21 https://doi.org/10.1021/jacs.7b03397	journal	May 2017
Metal–Organic Frameworks for Heterogeneous Basic Catalysis Zhu, Li; Liu, Xiao-Qin; Jiang, Hai-Long Chemical Reviews, Vol. 117, Issue 12 https://doi.org/10.1021/acs.chemrev.7b00091	journal	May 2017
Oxidation of ethane to ethanol by N2O in a metal–organic framework with coordinatively unsaturated iron(II) sites Xiao, Dianne J.; Bloch, Eric D.; Mason, Jarad A. Nature Chemistry, Vol. 6, Issue 7 https://doi.org/10.1038/nchem.1956	journal	May 2014
Pyrazolate-Based Porphyrinic Metal–Organic Framework with Extraordinary Base-Resistance Wang, Kecheng; Lv, Xiu-Liang; Feng, Dawei Journal of the American Chemical Society, Vol. 138, Issue 3 https://doi.org/10.1021/jacs.5b10881	journal	January 2016
Hierarchical Integration of Photosensitizing Metal-Organic Frameworks and Nickel-Containing Polyoxometalates for Efficient Visible-Light-Driven Hydrogen Evolution Kong, Xiang-Jian; Lin, Zekai; Zhang, Zhi-Ming Angewandte Chemie International Edition, Vol. 55, Issue 22 https://doi.org/10.1002/anie.201600431	journal	April 2016
A Base-Resistant Metalloporphyrin Metal–Organic Framework for C–H Bond Halogenation Lv, Xiu-Liang; Wang, Kecheng; Wang, Bin Journal of the American Chemical Society, Vol. 139, Issue 1 https://doi.org/10.1021/jacs.6b09463	journal	December 2016
Inserting CO ₂ into Aryl C−H Bonds of Metal-Organic Frameworks: CO ₂ Utilization for Direct Heterogeneous C−H Activation Gao, Wen-Yang; Wu, Haifan; Leng, Kunyue Angewandte Chemie International Edition, Vol. 55, Issue 18 https://doi.org/10.1002/anie.201511484	journal	April 2016
Metal–Organic Framework Based upon the Synergy of a Brønsted Acid Framework and Lewis Acid Centers as a Highly Efficient Heterogeneous Catalyst for Fixed-Bed Reactions Li, Baiyan; Leng, Kunyue; Zhang, Yiming Journal of the American Chemical Society, Vol. 137, Issue 12 https://doi.org/10.1021/jacs.5b01352	journal	March 2015
Linker Installation: Engineering Pore Environment with Precisely Placed Functionalities in Zirconium MOFs Yuan, Shuai; Chen, Ying-Pin; Qin, Jun-Sheng Journal of the American Chemical Society, Vol. 138, Issue 28 https://doi.org/10.1021/jacs.6b04501	journal	July 2016
Two Principles of Reticular Chemistry Uncovered in a Metal–Organic Framework of Heterotritopic Linkers and Infinite Secondary Building Units Catarineu, Noelle R.; Schoedel, Alexander; Urban, Philipp Journal of the American Chemical Society, Vol. 138, Issue 34 https://doi.org/10.1021/jacs.6b07267	journal	August 2016
Metal–organic framework composites Zhu, Qi-Long; Xu, Qiang Chem. Soc. Rev., Vol. 43, Issue 16 https://doi.org/10.1039/C3CS60472A	journal	January 2014
Zr-based metal–organic frameworks: design, synthesis, structure, and applications Bai, Yan; Dou, Yibo; Xie, Lin-Hua Chemical Society Reviews, Vol. 45, Issue 8 https://doi.org/10.1039/C5CS00837A	journal	January 2016
Zirconium-Metalloporphyrin PCN-222: Mesoporous Metal-Organic Frameworks with Ultrahigh Stability as Biomimetic Catalysts Feng, Dawei; Gu, Zhi-Yuan; Li, Jian-Rong Angewandte Chemie International Edition, Vol. 51, Issue 41 https://doi.org/10.1002/anie.201204475	journal	August 2012
A Highly Stable Porphyrinic Zirconium Metal–Organic Framework with shp-a Topology Feng, Dawei; Gu, Zhi-Yuan; Chen, Ying-Pin Journal of the American Chemical Society, Vol. 136, Issue 51 https://doi.org/10.1021/ja510525s	journal	December 2014
Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination Feng, Dawei; Chung, Wan-Chun; Wei, Zhangwen Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja408084j	journal	October 2013
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability Cavka, Jasmina Hafizovic; Jakobsen, Søren; Olsbye, Unni Journal of the American Chemical Society, Vol. 130, Issue 42, p. 13850-13851 https://doi.org/10.1021/ja8057953	journal	October 2008
A stable and porous iridium( iii )-porphyrin metal–organic framework: synthesis, structure and catalysis Cui, Hao; Wang, Yingxia; Wang, Yanhu CrystEngComm, Vol. 18, Issue 12 https://doi.org/10.1039/C6CE00358C	journal	January 2016
Cooperative electrochemical water oxidation by Zr nodes and Ni–porphyrin linkers of a PCN-224 MOF thin film Usov, P. M.; Ahrenholtz, S. R.; Maza, W. A. Journal of Materials Chemistry A, Vol. 4, Issue 43 https://doi.org/10.1039/C6TA05877A	journal	January 2016
Halogen substituent effects on the catalytic activity of iron porphyrin complexes for selective air-oxidation of alkanes in the liquid phase Ellis, Paul E.; Lyons, James E. Catalysis Letters, Vol. 3, Issue 5-6 https://doi.org/10.1007/BF00771267	journal	September 1989
Mechanism of catalytic oxygenation of alkanes by halogenated iron porphyrins Grinstaff, M.; Hill, M.; Labinger, J. Science, Vol. 264, Issue 5163 https://doi.org/10.1126/science.8191283	journal	May 1994
Probing structure-function relations in heme-containing oxygenases and peroxidases Dawson, J. Science, Vol. 240, Issue 4851 https://doi.org/10.1126/science.3358128	journal	April 1988
High-yield epoxidations with hydrogen peroxide and tert-butyl hydroperoxide catalyzed by iron(III) porphyrins: heterolytic cleavage of hydroperoxides Traylor, Teddy G.; Tsuchiya, Shinji; Byun, Young Seok Journal of the American Chemical Society, Vol. 115, Issue 7 https://doi.org/10.1021/ja00060a027	journal	April 1993

Cited By (16)

A series of dysprosium-based hydrogen-bonded organic frameworks (Dy–HOFs): thermally triggered off → on conversion of a single-ion magnet Wang, Hai-Ling; Ma, Xiong-Feng; Zhu, Zhong-Hong Inorganic Chemistry Frontiers, Vol. 6, Issue 10 https://doi.org/10.1039/c9qi00582j	journal	January 2019
NH ₂ -Ni-MOF electrocatalysts with tunable size/morphology for ultrasensitive C-reactive protein detection via an aptamer binding induced DNA walker–antibody sandwich assay Wang, Zhen; Dong, Pei; Sun, Zhongxiong Journal of Materials Chemistry B, Vol. 6, Issue 16 https://doi.org/10.1039/c8tb00373d	journal	January 2018
Evaluation of the BET Theory for the Characterization of Meso and Microporous MOFs Ambroz, Filip; Macdonald, Thomas J.; Martis, Vladimir Small Methods, Vol. 2, Issue 11 https://doi.org/10.1002/smtd.201800173	journal	August 2018
A Water Stable Cd II -based Metal-Organic Framework as a Multifunctional Sensor for Selective Detection of Cu 2+ and Cr 2 O 7 2- Ions : A Water Stable Cd Hu, Chang-Jiang; Yu, Li; Dong, Wen-Wen Zeitschrift für anorganische und allgemeine Chemie, Vol. 645, Issue 4 https://doi.org/10.1002/zaac.201800442	journal	January 2019
Facile and reversible digestion and regeneration of zirconium-based metal-organic frameworks Chu, Jun; Ke, Fu-Sheng; Wang, Yunxiao Communications Chemistry, Vol. 3, Issue 1 https://doi.org/10.1038/s42004-019-0248-7	journal	January 2020
Two MOFs as dual-responsive photoluminescence sensors for metal and inorganic ion detection Wang, Zhong-Jie; Ge, Fa-Yuan; Sun, Guo-Hao Dalton Transactions, Vol. 47, Issue 25 https://doi.org/10.1039/c8dt01363b	journal	January 2018
A highly sensitive self-enhanced aptasensor based on a stable ultrathin 2D metal–organic layer with outstanding electrochemiluminescence property Yang, Yang; Hu, Gui-Bing; Liang, Wen-Bin Nanoscale, Vol. 11, Issue 20 https://doi.org/10.1039/c9nr00860h	journal	January 2019
Two mixed-ligand Cd( ii )–organic frameworks with unique topologies: selective luminescence sensing of TNP and Cu 2+ ions with recyclable performances Zhang, Jinfang; Jia, Wen; Wu, Junjie New Journal of Chemistry, Vol. 43, Issue 40 https://doi.org/10.1039/c9nj03551f	journal	January 2019
Predictable Catalysis of Electron‐Rich Palladium Catalyst toward Aldehydes Hydrogenation Wang, Tao; Xu, Yida; Yang, Jie ChemCatChem, Vol. 11, Issue 16 https://doi.org/10.1002/cctc.201900514	journal	June 2019
Metal–Helix Frameworks Formed by μ ₃ ‐NO ₃ ⁻ with Different Orientations and Connected to a Heterometallic Cu ^II ₁₀ Dy ^III ₂ Folded Cluster Wang, Hai‐Ling; Zhu, Zhong‐Hong; Ma, Xiong‐Feng Chemistry – A European Journal, Vol. 25, Issue 46 https://doi.org/10.1002/chem.201902096	journal	July 2019
Chiral metal-organic frameworks with tunable catalytic selectivity in asymmetric transfer hydrogenation reactions Chen, Xu; Qiao, Zhiwei; Hou, Bang Nano Research https://doi.org/10.1007/s12274-020-2905-7	journal	June 2020
Metal–Organic Framework (MOF)‐Based Materials as Heterogeneous Catalysts for C−H Bond Activation Liu, Mengjia; Wu, Jie; Hou, Hongwei Chemistry – A European Journal https://doi.org/10.1002/chem.201804149	journal	December 2018
Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework Zee, David Z.; Harris, T. David Chemical Science, Vol. 11, Issue 21 https://doi.org/10.1039/d0sc01796e	journal	January 2020
Flexible and Hierarchical Metal-Organic Framework Composites for High-Performance Catalysis Huang, Ning; Drake, Hannah; Li, Jialuo Angewandte Chemie, Vol. 130, Issue 29 https://doi.org/10.1002/ange.201803096	journal	June 2018
van der Waals Epitaxial Growth of 2D Metal-Porphyrin Framework Derived Thin Films for Dye-Sensitized Solar Cells Wang, Yan-Yue; Chen, Shu-Mei; Haldar, Ritesh Advanced Materials Interfaces, Vol. 5, Issue 21 https://doi.org/10.1002/admi.201800985	journal	September 2018
Flexible and Hierarchical Metal-Organic Framework Composites for High-Performance Catalysis Huang, Ning; Drake, Hannah; Li, Jialuo Angewandte Chemie International Edition, Vol. 57, Issue 29 https://doi.org/10.1002/anie.201803096	journal	June 2018

Similar Records

Photosensitizer‐Anchored 2D MOF Nanosheets as Highly Stable and Accessible Catalysts toward Artemisinin Production

Journal Article · Tue Apr 09 00:00:00 EDT 2019 · Advanced Science · OSTI ID:1470071

Wang, Ying; Feng, Liang; Pang, Jiandong; +12 more

Tandem catalysis by palladium nanoclusters encapsulated in metal–organic frameworks

Journal Article · Mon Aug 25 00:00:00 EDT 2014 · ACS Catalysis · OSTI ID:1470071

Li, Xinle; Guo, Zhiyong; Xiao, Chaoxian; +3 more

Enhancing catalytic alkane hydroxylation by tuning the outer coordination sphere in a heme-containing metal–organic framework

Journal Article · Wed Jun 03 00:00:00 EDT 2020 · Chemical Science · OSTI ID:1470071

Zee, David Z.; Harris, T. David

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)

Title: Systematic Engineering of Single Substitution in Zirconium Metal–Organic Frameworks toward High-Performance Catalysis

Citation Formats

References (72)

Cited By (16)

Similar Records

Related Subjects