Dual Exchange in PCN-333: A Facile Strategy to Chemically Robust Mesoporous Chromium Metal–Organic Framework with Functional Groups

Park, Jihye; Feng, Dawei; Zhou, Hong-Cai

doi:10.1021/jacs.5b07373

Title: Dual Exchange in PCN-333: A Facile Strategy to Chemically Robust Mesoporous Chromium Metal–Organic Framework with Functional Groups

Journal Article · Fri Aug 28 00:00:00 EDT 2015 · Journal of the American Chemical Society

DOI:https://doi.org/10.1021/jacs.5b07373· OSTI ID:1387387

Park, Jihye ^[1]; Feng, Dawei ^[1]; Zhou, Hong-Cai ^[1]

Texas A & M Univ., College Station, TX (United States)

A facile preparation of a mesoporous Cr-MOF, PCN-333(Cr) with functional group, has been demonstrated herein through a dual exchange strategy, involving a sequential ligand exchange and metal metathesis process. After optimization of the exchange system, the functionalized PCN-333(Cr), N3–PCN-333(Cr) shows well maintained crystallinity, porosity, as well as much improved chemical stability. Because of the exceptionally large pores (~5.5 nm) in PCN-333(Cr), a secondary functional moiety, Zn-TEPP with a size of 18 Å × 18 Å, has been successfully clicked into the framework. In this article, we have also analyzed kinetics and thermodynamics during dual exchange process, showing our attempts to interpret the exchange event in the PCN-333. Our findings not only provide a highly stable mesoporous Cr-MOF platform for expanding MOF-based applications, but also suggest a route to functionalized Cr-MOF which may have not been achievable through conventional approaches.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations (CGS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); The Welch Foundation

Grant/Contract Number:: SC0001015; A-1725

OSTI ID:: 1387387

Journal Information:: Journal of the American Chemical Society, Vol. 137, Issue 36; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; ISSN 0002-7863

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 80 works

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)
functionalization
ligand exchange
metals
metal organic frameworks
metathesis