Nuclear and magnetic supercells in the multiferroic candidate: Pb3TeMn3P2O14

Silverstein, Harlyn J.; Huq, Ashfia; Lee, Minseong; Choi, Eun Sang; Zhou, Haidong; Wiebe, Christopher R.

doi:10.1016/j.jssc.2014.10.007

Title: Nuclear and magnetic supercells in the multiferroic candidate: Pb₃TeMn₃P₂O₁₄

Journal Article · Sat Oct 18 00:00:00 EDT 2014 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2014.10.007· OSTI ID:1261405

Silverstein, Harlyn J. ^[1]; Huq, Ashfia ^[2]; Lee, Minseong ^[3]; Choi, Eun Sang ^[3]; Zhou, Haidong ^[4]; Wiebe, Christopher R. ^[5]

Univ. of Manitoba, Winnipeg, MB (Canada)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)
Univ. of Tennessee, Knoxville, TN (United States)
Univ. of Manitoba, Winnipeg, MB (Canada); Univ. of Winnipeg, Winnipeg, MB (United States); McMaster Univ., Hamilton, ON (Canada)

Here we report that the dugganites, Te⁶⁺-containing members of the langasite series, have attracted recent interest due to their complex low-temperature magnetic unit cells, magnetodielectric, and potentially multiferroic properties. For Pb²⁺-containing dugganites, a large monoclinic supercell was reported and was found to have a profound effect on the low temperature magnetism and spin excitation spectra. Pb₃TeMn₃P₂O₁₄ is another dugganite previously shown to distort away from the canonical P321 langasite unit cell, although this supercell was never fully solved. We report the full crystal and magnetic structure solution of Pb₃TeMn₃P₂O₁₄ using synchrotron x-ray and neutron diffraction data: a large trigonal supercell is observed in this material, which is believed to be the first supercell of its kind in the langasite family. Here, the magnetic structure, high-magnetic field behavior, and dielectric properties of Pb₃TeMn₃P₂O₁₄ are presented. In addition to showing weak magnetoelectric behavior similar to other langasites, it was found that a phase transition occurs at 3 T near the antiferromagnetic transition temperature.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725; 51374-UR10; DMR-1350002; AC02-06CH11357; DMR-1157490

OSTI ID:: 1261405

Alternate ID(s):: OSTI ID: 1246688

Journal Information:: Journal of Solid State Chemistry, Vol. 221, Issue C; ISSN 0022-4596

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Langasite
Dugganite
Multiferroic
Antiferromagnetic
Pb3TeMn3P2O14
Supercell

Title: Nuclear and magnetic supercells in the multiferroic candidate: Pb3TeMn3P2O14

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Title: Nuclear and magnetic supercells in the multiferroic candidate: Pb₃TeMn₃P₂O₁₄