CO Chemical Capture on Lithium Cuprate, Through a Consecutive CO Oxidation and Chemisorption Bifunctional Process

Lara-Garcia, Hugo; Alcántar-Vázquez, Brenda; Duan, Yuhua; Pfeiffer, Heriberto

doi:10.1021/acs.jpcc.5b11147

Title: CO Chemical Capture on Lithium Cuprate, Through a Consecutive CO Oxidation and Chemisorption Bifunctional Process

Journal Article · Thu Feb 25 00:00:00 EST 2016 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.5b11147· OSTI ID:1239130

Lara-Garcia, Hugo ^[1]; Alcántar-Vázquez, Brenda ^[1]; Duan, Yuhua ^[2]; Pfeiffer, Heriberto ^[1]

Universidad nacional Autonoma de Mexico, Coyoacan (Mexico). Instituto de Investigaciones en Materiales
National Energy Technology Lab. (NETL), Pittsburgh, PA, (United States)

Lithium cuprate was studied as a possible catalytic and captor material for CO oxidation and the subsequent CO₂ chemisorption process, a bifunctional material. The CO oxidation reaction was analyzed in a high temperature reactor coupled to an FTIR spectrometer and a gas chromatograph. The CO₂ production and consequent chemisorption processes were analyzed by thermogravimetric analysis. All of these experiments were performed in both the presence and absence of oxygen. Experimental results were then compared with theoretical thermodynamic data. The results clearly showed that Li2CuO₂ can be used as a bifunctional material; it is able to catalyze the CO oxidation, producing CO₂, and, subsequently, it can chemically capture the CO₂. Both processes occur in the presence or absence of oxygen and follow the Mars–van Krevelen reaction mechanism.

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Research Organization:: National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV (United States)

Sponsoring Organization:: USDOE Office of Fossil Energy (FE)

OSTI ID:: 1239130

Report Number(s):: NETL-PUB-20216

Journal Information:: Journal of Physical Chemistry. C, Vol. 120, Issue 7; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

References (52)

A review on development of industrial processes and emerging techniques for production of hydrogen from renewable and sustainable sources Chaubey, Rashmi; Sahu, Satanand; James, Olusola O. Renewable and Sustainable Energy Reviews, Vol. 23 https://doi.org/10.1016/j.rser.2013.02.019	journal	July 2013
Syngas production in a novel methane dry reformer by utilizing of tri-reforming process for energy supplying: Modeling and simulation Farniaei, Mehdi; Abbasi, Mohsen; Rahnama, Hamid Journal of Natural Gas Science and Engineering, Vol. 20 https://doi.org/10.1016/j.jngse.2014.06.010	journal	September 2014
Combination of dry reforming and partial oxidation of methane over Ni catalysts supported on nanocrystalline MgAl2O4 Hadian, Narges; Rezaei, Mehran Fuel, Vol. 113 https://doi.org/10.1016/j.fuel.2013.06.013	journal	November 2013
Dry reforming of methane: Influence of process parameters—A review Usman, Muhammad; Wan Daud, W. M. A.; Abbas, Hazzim F. Renewable and Sustainable Energy Reviews, Vol. 45 https://doi.org/10.1016/j.rser.2015.02.026	journal	May 2015
Reactor modeling of sorption-enhanced autothermal reforming of methane. Part II: Effect of operational parameters Halabi, M. H.; de Croon, M. H. J. M.; van der Schaaf, J. Chemical Engineering Journal, Vol. 168, Issue 2 https://doi.org/10.1016/j.cej.2011.02.016	journal	April 2011
Effects of Steam Addition on the Properties of High Temperature Ceramic CO2 Acceptors Ochoa-Fernández, Esther; Zhao, Tiejun; Rønning, Magnus Journal of Environmental Engineering, Vol. 135, Issue 6 https://doi.org/10.1061/(ASCE)EE.1943-7870.0000006	journal	June 2009
High temperature CO2 sorbents and their application for hydrogen production by sorption enhanced steam reforming process Shokrollahi Yancheshmeh, Marziehossadat; Radfarnia, Hamid R.; Iliuta, Maria C. Chemical Engineering Journal, Vol. 283 https://doi.org/10.1016/j.cej.2015.06.060	journal	January 2016
Sorption-enhanced reaction process for hydrogen production Hufton, J. R.; Mayorga, S.; Sircar, S. AIChE Journal, Vol. 45, Issue 2 https://doi.org/10.1002/aic.690450205	journal	February 1999
Sorbent-Enhanced Methane Reforming over a Ni–Ca-Based, Bifunctional Catalyst Sorbent Broda, Marcin; Kierzkowska, Agnieszka M.; Baudouin, David ACS Catalysis, Vol. 2, Issue 8 https://doi.org/10.1021/cs300247g	journal	July 2012
Enhanced ethanol steam reforming by CO 2 absorption using CaO, CaO*MgO or Na 2 ZrO 3 Aceves Olivas, D. Y.; Baray Guerrero, M. R.; Escobedo Bretado, M. A. International Journal of Hydrogen Energy, Vol. 39, Issue 29 https://doi.org/10.1016/j.ijhydene.2014.04.156	journal	October 2014
Sorption-enhanced steam methane reforming by in situ CO 2 capture on a CaO–Ca 9 Al 6 O 18 sorbent Xie, Miaomiao; Zhou, Zhiming; Qi, Yang Chemical Engineering Journal, Vol. 207-208 https://doi.org/10.1016/j.cej.2012.06.032	journal	October 2012
Sorption enhanced hydrogen production by steam methane reforming using Li2ZrO3 as sorbent: Sorption kinetics and reactor simulation Ochoa-Fernández, Esther; Rusten, Hans Kristian; Jakobsen, Hugo Atle Catalysis Today, Vol. 106, Issue 1-4 https://doi.org/10.1016/j.cattod.2005.07.146	journal	October 2005
Hydrogen Production by Sorption-Enhanced Steam Methane Reforming Using Lithium Oxides as CO ₂ -Acceptor Rusten, Hans Kristian; Ochoa-Fernández, Esther; Lindborg, Håvard Industrial & Engineering Chemistry Research, Vol. 46, Issue 25 https://doi.org/10.1021/ie070770k	journal	December 2007
A Novel Method of CO[sub 2] Capture from High Temperature Gases Nakagawa, K. Journal of The Electrochemical Society, Vol. 145, Issue 4 https://doi.org/10.1149/1.1838462	journal	January 1998
CO2 capture with a novel solid fluidizable sorbent: Thermodynamics and Temperature Programmed Carbonation–Decarbonation Chowdhury, Muhammad B. I.; Quddus, Mohammad R.; deLasa, Hugo I. Chemical Engineering Journal, Vol. 232 https://doi.org/10.1016/j.cej.2013.07.044	journal	October 2013
Three-Step Calcination Synthesis of High-Purity Li ₈ ZrO ₆ with CO ₂ Absorption Properties Yin, Xian-Sheng; Zhang, Qin-Hui; Yu, Jian-Guo Inorganic Chemistry, Vol. 50, Issue 7 https://doi.org/10.1021/ic102035y	journal	April 2011
High temperature sequestration of CO2 using lithium zirconates Iwan, Alina; Stephenson, Hazel; Ketchie, William C. Chemical Engineering Journal, Vol. 146, Issue 2 https://doi.org/10.1016/j.cej.2008.06.006	journal	February 2009
Citrate route to prepare K-doped Li2ZrO3 sorbents with excellent CO2 capture properties Xiao, Qiang; Tang, Xiaodan; Liu, Yefeng Chemical Engineering Journal, Vol. 174, Issue 1 https://doi.org/10.1016/j.cej.2011.09.005	journal	October 2011
Use of small-amplitude oscillatory shear rheometry to study the flow properties of pure and potassium-doped Li2ZrO3 sorbents during the sorption of CO2 at high temperatures Olivares-Marín, Mara; Castro-Díaz, Miguel; Drage, Trevor C. Separation and Purification Technology, Vol. 73, Issue 3 https://doi.org/10.1016/j.seppur.2010.04.033	journal	July 2010
A citrate sol–gel method to synthesize Li2ZrO3 nanocrystals with improved CO2 capture properties Xiao, Qiang; Liu, Yefeng; Zhong, Yijun Journal of Materials Chemistry, Vol. 21, Issue 11 https://doi.org/10.1039/c0jm03243c	journal	January 2011
Syntheses and structures of lithium zirconates for high-temperature CO2 absorption Wang, Shutao; An, Changhua; Zhang, Qin-Hui Journal of Materials Chemistry A, Vol. 1, Issue 11 https://doi.org/10.1039/c2ta00700b	journal	January 2013
Thermal Behavior and CO ₂ Absorption of Li _2- _x Na _x ZrO ₃ Solid Solutions Pfeiffer, Heriberto; Vázquez, Carmen; Lara, Víctor H. Chemistry of Materials, Vol. 19, Issue 4 https://doi.org/10.1021/cm0623965	journal	February 2007
Microstructural Thermal Evolution of the Na ₂ CO ₃ Phase Produced during a Na ₂ ZrO ₃ –CO ₂ Chemisorption Process Martínez-dlCruz, Lorena; Pfeiffer, Heriberto The Journal of Physical Chemistry C, Vol. 116, Issue 17 https://doi.org/10.1021/jp301917a	journal	April 2012
Preparation and High-Temperature CO ₂ Capture Properties of Nanocrystalline Na ₂ ZrO ₃ Zhao, Tiejun; Ochoa-Fernández, Esther; Rønning, Magnus Chemistry of Materials, Vol. 19, Issue 13 https://doi.org/10.1021/cm062732h	journal	May 2007
Compositional Effects of Nanocrystalline Lithium Zirconate on Its CO ₂ Capture Properties Ochoa-Fernández, Esther; Rønning, Magnus; Yu, Xiaofeng Industrial & Engineering Chemistry Research, Vol. 47, Issue 2 https://doi.org/10.1021/ie0705150	journal	January 2008
Application of surfactant-template technique for preparation of sodium zirconate as high temperature CO2 sorbent Radfarnia, Hamid R.; Iliuta, Maria C. Separation and Purification Technology, Vol. 93 https://doi.org/10.1016/j.seppur.2012.03.036	journal	June 2012
Preparation of nanocrystalline Na2ZrO3 for high-temperature CO2 acceptors: chemistry and mechanism Zhao, Tiejun; Rønning, Magnus; Chen, De Journal of Energy Chemistry, Vol. 22, Issue 3 https://doi.org/10.1016/S2095-4956(13)60050-9	journal	May 2013
Facile synthesis of macroporous Li4SiO4 with remarkably enhanced CO2 adsorption kinetics Kim, Hyeonbin; Jang, Hee Dong; Choi, Minkee Chemical Engineering Journal, Vol. 280 https://doi.org/10.1016/j.cej.2015.05.127	journal	November 2015
High-Temperature Capture of CO ₂ on Lithium-Based Sorbents Prepared by a Water-Based Sol-Gel Technique Wang, Ke; Wang, Xinyong; Zhao, Pengfei Chemical Engineering & Technology, Vol. 37, Issue 9 https://doi.org/10.1002/ceat.201300584	journal	August 2014
A High Temperature Lithium Orthosilicate-Based Solid Absorbent for Post Combustion CO ₂ Capture Quinn, Robert; Kitzhoffer, Ronald J.; Hufton, Jeffrey R. Industrial & Engineering Chemistry Research, Vol. 51, Issue 27 https://doi.org/10.1021/ie300157m	journal	June 2012
Surfactant-assisted hydrothermal crystallization of nanostructured lithium metasilicate (Li2SiO3) hollow spheres: II—Textural analysis and CO2–H2O sorption evaluation Ortiz-Landeros, José; Gómez-Yáñez, Carlos; Pfeiffer, Heriberto Journal of Solid State Chemistry, Vol. 184, Issue 8 https://doi.org/10.1016/j.jssc.2011.06.027	journal	August 2011
Microstructural and CO2 chemisorption analyses of Li4SiO4: Effect of surface modification by the ball milling process Romero-Ibarra, Issis C.; Ortiz-Landeros, José; Pfeiffer, Heriberto Thermochimica Acta, Vol. 567 https://doi.org/10.1016/j.tca.2012.11.018	journal	September 2013
High temperature capture of CO ₂ on Li ₄ SiO ₄ -based sorbents from biomass ashes Wang, Ke; Zhao, Pengfei; Guo, Xin Environmental Progress & Sustainable Energy, Vol. 34, Issue 2 https://doi.org/10.1002/ep.11986	journal	April 2014
Analysis of the CO2 chemisorption reaction mechanism in lithium oxosilicate (Li8SiO6): a new option for high-temperature CO2 capture Durán-Muñoz, Fernando; Romero-Ibarra, Issis C.; Pfeiffer, Heriberto Journal of Materials Chemistry A, Vol. 1, Issue 12 https://doi.org/10.1039/c3ta00421j	journal	January 2013
Effect of the Particle Size of Quartz Powder on the Synthesis and CO ₂ Absorption Properties of Li ₄ SiO ₄ at High Temperature Xu, Hongliang; Cheng, Weigao; Jin, Xiaozeng Industrial & Engineering Chemistry Research, Vol. 52, Issue 5 https://doi.org/10.1021/ie301178p	journal	January 2013
High CO ₂ Capture in Sodium Metasilicate (Na ₂ SiO ₃ ) at Low Temperatures (30–60 °C) through the CO ₂ –H ₂ O Chemisorption Process Rodríguez-Mosqueda, Rafael; Pfeiffer, Heriberto The Journal of Physical Chemistry C, Vol. 117, Issue 26 https://doi.org/10.1021/jp402850j	journal	June 2013
Thermochemical Capture of Carbon Dioxide on Lithium Aluminates (LiAlO ₂ and Li ₅ AlO ₄ ): A New Option for the CO ₂ Absorption Ávalos-Rendón, Tatiana; Casa-Madrid, Julio; Pfeiffer, Heriberto The Journal of Physical Chemistry A, Vol. 113, Issue 25 https://doi.org/10.1021/jp902501v	journal	June 2009
CO ₂ Chemisorption and Cyclability Analyses of Lithium Aluminate Polymorphs (α- and β-Li ₅ AlO ₄ ) Ávalos-Rendón, Tatiana; Lara, Víctor H.; Pfeiffer, Heriberto Industrial & Engineering Chemistry Research, Vol. 51, Issue 6 https://doi.org/10.1021/ie201616h	journal	February 2012
High CO ₂ Chemisorption in α-Li ₅ AlO ₄ at Low Temperatures (30–80 °C): Effect of the Water Vapor Addition Ávalos-Rendón, Tatiana L.; Pfeiffer, Heriberto Energy & Fuels, Vol. 26, Issue 5 https://doi.org/10.1021/ef3004416	journal	December 2011
Lithium Cuprate (Li ₂ CuO ₂ ): A New Possible Ceramic Material for CO ₂ Chemisorption Palacios-Romero, Luis M.; Pfeiffer, Heriberto Chemistry Letters, Vol. 37, Issue 8 https://doi.org/10.1246/cl.2008.862	journal	August 2008
Structural Analysis and CO ₂ Chemisorption Study on Nonstoichiometric Lithium Cuprates (Li _{2+ x} CuO _{2+ x /2} ) Palacios-Romero, Luis M.; Lima, Enrique; Pfeiffer, Heriberto The Journal of Physical Chemistry A, Vol. 113, Issue 1 https://doi.org/10.1021/jp808521f	journal	December 2008
Water steam effect during high CO ₂ chemisorption in lithium cuprate (Li ₂ CuO ₂ ) at moderate temperatures: experimental and theoretical evidence Lara-García, Hugo A.; Alcántar-Vázquez, Brenda; Duan, Yuhua RSC Advances, Vol. 5, Issue 43 https://doi.org/10.1039/C5RA03580E	journal	January 2015
Synthesis and CO ₂ Absorption Properties of Single-phase Li ₂ CuO ₂ as a CO ₂ Absorbent Matsukura, Yusuke; Okumura, Takeshi; Kobayashi, Ryota Chemistry Letters, Vol. 39, Issue 9 https://doi.org/10.1246/cl.2010.966	journal	September 2010
Fundamental research on gas–solid reaction between CO2 and Li2CuO2 linking application for solid CO2 absorbent Oh-ishi, Katsuyoshi; Matsukura, Yusuke; Okumura, Takeshi Journal of Solid State Chemistry, Vol. 211 https://doi.org/10.1016/j.jssc.2013.12.018	journal	March 2014
CO2 chemisorption and evidence of the CO oxidation–chemisorption mechanisms on sodium cobaltate Vera, Elizabeth; Alcántar-Vázquez, Brenda; Pfeiffer, Heriberto Chemical Engineering Journal, Vol. 271 https://doi.org/10.1016/j.cej.2015.02.075	journal	July 2015
Evidence of CO Oxidation–Chemisorption Process on Sodium Zirconate (Na ₂ ZrO ₃ ) Alcántar-Vázquez, Brenda; Vera, Elizabeth; Buitron-Cabrera, Frida Chemistry Letters, Vol. 44, Issue 4 https://doi.org/10.1246/cl.141134	journal	April 2015
Catalytic Oxidation of Carbon Monoxide over Transition Metal Oxides Royer, Sébastien; Duprez, Daniel ChemCatChem, Vol. 3, Issue 1 https://doi.org/10.1002/cctc.201000378	journal	December 2010
CO2 capture properties of lithium silicates with different ratios of Li2O/SiO2: an ab initio thermodynamic and experimental approach Duan, Yuhua; Pfeiffer, Heriberto; Li, Bingyun Physical Chemistry Chemical Physics, Vol. 15, Issue 32 https://doi.org/10.1039/c3cp51659h	journal	January 2013
Density functional theory studies of the structural, electronic, and phonon properties of ${Li}_{2} O$ and ${Li}_{2} {CO}_{3}$ : Application to ${CO}_{2}$ capture reaction Duan, Yuhua; Sorescu, Dan C. Physical Review B, Vol. 79, Issue 1 https://doi.org/10.1103/PhysRevB.79.014301	journal	January 2009
CO2 capture properties of alkaline earth metal oxides and hydroxides: A combined density functional theory and lattice phonon dynamics study Duan, Yuhua; Sorescu, Dan C. The Journal of Chemical Physics, Vol. 133, Issue 7 https://doi.org/10.1063/1.3473043	journal	August 2010
Efficient Theoretical Screening of Solid Sorbents for CO<sub>2</sub> Capture Applications Duan, Yuhua; Luebke, David; Henry Pennline, Henry International Journal of Clean Coal and Energy, Vol. 01, Issue 01 https://doi.org/10.4236/ijcce.2012.11001	journal	January 2012
Density functional theory study of CO ₂ capture with transition metal oxides and hydroxides Zhang, Bo; Duan, Yuhua; Johnson, Karl The Journal of Chemical Physics, Vol. 136, Issue 6 https://doi.org/10.1063/1.3684901	journal	February 2012

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