Characterization of vanadium ion uptake in sulfonated diels alder poly(phenylene) membranes

Lawton, Jamie; Jones, Amanda; Tang, Zhijiang; Lindsey, Melanie; Zawodzinski, Thomas A

doi:10.1149/2.0291601jes

Title: Characterization of vanadium ion uptake in sulfonated diels alder poly(phenylene) membranes

Journal Article · Sat Nov 28 00:00:00 EST 2015 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0291601jes· OSTI ID:1234345

Lawton, Jamie ^[1]; Jones, Amanda ^[1]; Tang, Zhijiang ^[2]; Lindsey, Melanie ^[1]; Zawodzinski, Thomas A ^[2]

Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sulfonated diels alder poly(phenylene) (SDAPP), alternative aromatic hydrocarbon membranes for vanadium redox flow batteries (VRFBs) are characterized using electron paramagnetic resonance (EPR). Membranes soaked in sulfuric acid and vanadyl sulfate are analyzed to determine the membrane environment in which the vanadyl ion (VO²⁺) diffuses in the membranes. These results are compared to Nafion 117 membranes. In contrast to Nafion, the VO²⁺ in SDAPP membranes exists in two different environments. The results of analysis of rotational diffusion determined from fits the EPR spectral lineshapes in comparison with previously reported permeation studies and measurements of partitioning functions reported here suggest that the diffusion pathways in SDAPP are very different than in Nafion.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1234345

Journal Information:: Journal of the Electrochemical Society, Vol. 163, Issue 1; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 13 works

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Monitoring the State of Charge of the Positive Electrolyte in a Vanadium Redox-Flow Battery with a Novel Amperometric Sensor Kroner, Isabelle; Becker, Maik; Turek, Thomas Batteries, Vol. 5, Issue 1 https://doi.org/10.3390/batteries5010005	journal	January 2019

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