Shape transformation of bimetallic Au–Pd core–shell nanocubes to multilayered Au–Pd–Au core–shell hexagonal platelets

Bhattarai, Nabraj; Prozorov, Tanya

doi:10.1007/s13632-015-0246-9

Title: Shape transformation of bimetallic Au–Pd core–shell nanocubes to multilayered Au–Pd–Au core–shell hexagonal platelets

Journal Article · Thu Nov 05 00:00:00 EST 2015 · Metallography, Microstructure and Analysis

DOI:https://doi.org/10.1007/s13632-015-0246-9· OSTI ID:1227433

Bhattarai, Nabraj ^[1]; Prozorov, Tanya ^[1]

Ames Lab. (AMES), Ames, IA (United States)

Transformation of metallic or bimetallic (BM) nanoparticles (NPs) from one shape to another desired shape is of importance to nanoscience and nanotechnology, where new morphologies of NPs lead to enhancement of their exploitable properties. In this report, we present the shape transformation of Au octahedral NPs to Au–Pd core–shell nanocubes, followed by their transformation to nanostars and finally to multilayered Au–Pd–Au core–shell hexagonal platelets in the presence of T30 DNA. The weaker binding affinity of T30 DNA directs the growth to favor the formation of lower energy {111} facets, changing the morphology from nanocubes to nanostar. The nanostars, exhibiting unusual intermediate morphologies, are comprised two sets of shell layers and have Au core, Pd intermediate shell, and Au outer shell. Similarly, the hexagonal platelets, which also have Au core and inner Pd shell, are encased in an external gold shell. As a result, the formation of multilayered Au–Pd–Au core–shell hexagonal platelets from Au–Pd core–shell nanocubes via the multilayered nanostars is monitored using scanning/transmission electron microscopy analysis.

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Research Organization:: Ames Laboratory (AMES), Ames, IA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-07CH11358

OSTI ID:: 1227433

Report Number(s):: IS-J-8646; PII: 246

Journal Information:: Metallography, Microstructure and Analysis, Vol. 4, Issue 6; ISSN 2192-9262

Publisher:: SpringerCopyright Statement

Country of Publication:: United States

Language:: English

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Surface faceting and compositional evolution of Pd@Au core–shell nanocrystals during in situ annealing Wu, Zhemin; Tang, Min; Li, Xiaoyan Physical Chemistry Chemical Physics, Vol. 21, Issue 6 https://doi.org/10.1039/c8cp07576j	journal	January 2019
Direct Observation of Early Stages of Growth of Multilayered DNA-Templated Au-Pd-Au Core-Shell Nanoparticles in Liquid Phase Bhattarai, Nabraj; Prozorov, Tanya Frontiers in Bioengineering and Biotechnology, Vol. 7 https://doi.org/10.3389/fbioe.2019.00019	journal	February 2019

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