Polymers incorporating covalently attached organoimido polyoxometalates
New polyoxometalate compounds and polymers comprising recurring monomers of those compounds are provided. The compounds are formed by replacing at least one oxide of the starting polyoxometalate with an organoimido (NR) group bonded to the polyoxometalate via a triple bond to the nitrogen atom. The R of the (NR) group comprises a reactive functional group which renders the compound readily polymerizable, alone or with other monomers (e.g., divinylbenzene), to form the inventive polymers. Additionally, a countercation (e.g., bis(tetra-n-butylammonium)) can be mixed with the polyoxometalate compounds in order to neutralize the negative charge thereof as well as to make those compounds more soluble in organic solvents.
- Research Organization:
- Kansas State University Research Foundation, Manhattan, KS (United States)
- Sponsoring Organization:
- USDOE
- DOE Contract Number:
- FG02-92ER14246
- Assignee:
- Kansas State University Research Foundation (Manhattan, KS)
- Patent Number(s):
- 6,706,833
- Application Number:
- 09/609,863
- OSTI ID:
- 1174770
- Country of Publication:
- United States
- Language:
- English
Derivatives of heteropolyanions. 2. Metal-metal-bonded derivatives
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journal | April 1979 |
Synthesis and properties of polyoxometalates based inorganic-organic polymers
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journal | January 1992 |
Silicone-Polyoxometalate (SiPOM) Hybrid Compounds
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journal | January 1996 |
A Survey of Applications of Polyoxometalates
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journal | February 1998 |
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