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Title: Memo, "Incorporation of HLW Glass Shell V2.0 into the Flowsheets," to ED Lee, CCN: 184905, October 20, 2009

Technical Report ·
DOI:https://doi.org/10.2172/1110829· OSTI ID:1110829

Efforts are being made to increase the efficiency and decrease the cost of vitrifying radioactive waste stored in tanks at the U.S. Department of Energy Hanford Site. The compositions of acceptable and processable high-level waste (HL W) glasses need to be optimized to minimize the waste-form volume and, hence, to reduce cost. A database of glass properties of waste glass and associated simulated waste glasses was collected and documented in PNNL 18501, Glass Property Data and Models for Estimating High-Level Waste Glass Volume and glass property models were curve-fitted to the glass compositions. A routine was developed that estimates HL W glass volumes using the following glass property models: II Nepheline, II One-Percent Crystal Temperature (T1%), II Viscosity (11) II Product Consistency Tests (PCT) for boron, sodium, and lithium, and II Liquidus Temperature (TL). The routine, commonly called the HL W Glass Shell, is presented in this document. In addition to the use of the glass property models, glass composition constraints and rules, as recommend in PNNL 18501 and in other documents (as referenced in this report) were incorporated. This new version of the HL W Glass Shell should generally estimate higher waste loading in the HL W glass than previous versions.

Research Organization:
Hanford Site (HNF), Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Environmental Management (EM)
Contributing Organization:
Bechtel Nationa, Inc.; Department of Energy - Office of River Protection
DOE Contract Number:
DE-AC27-08RV14800
OSTI ID:
1110829
Report Number(s):
ORP-56505; CCN 153245; 24590-WTP-MCR-PET-09-0032; 24590-WTP-MRQ-PET-09-0021
Country of Publication:
United States
Language:
English