The transformation of organic amines by transition metal cluster compounds. Progress report, 1992--1993
The paper reports results on the following five studies: (1) The activation of tertiary amines by osmium cluster complexes; (2) Nucleophilic ring opening of thietane ligand in metal carbonyl cluster complexes; (3) Ring opening of a nitrogen containing strained ring heterocycle by an osmium cluster complex; (4) Insertion of an alkynes into a metal-metal bond -- evidence for an intramolecular insertion with a trans-stereochemistry; and (5) Cyclobutyne -- the ligand. Plans for future research are also briefly discussed. Two studies are planned: (1) studies of the synthesis and reactivity of strained ring ligands in metal cluster compounds; and (2) studies of the reactivity of dimetallic complexes with alkynes.
- Research Organization:
- South Carolina Univ., Columbia, SC (United States). Dept. of Chemistry
- Sponsoring Organization:
- USDOE, Washington, DC (United States)
- DOE Contract Number:
- FG09-84ER13296
- OSTI ID:
- 10150203
- Report Number(s):
- DOE/ER/13296-9; ON: DE94011527; BR: KC0302010; TRN: AHC29411%%9
- Resource Relation:
- Other Information: PBD: Jan 1993
- Country of Publication:
- United States
- Language:
- English
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