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Title: An evaluation of foaming potential in the IDMS melter

Technical Report ·
DOI:https://doi.org/10.2172/10123952· OSTI ID:10123952

The present DWPF flowsheet calls for the chemical treatment of waste sludge with 90 wt% formic acid prior to the addition of the Precipitate Hydrolysis Aqueous (PHA) product. An alternative processing methodology, denoted the ``Nitric Acid Flowsheet``, has been proposed. In the application of this flowsheet, nitric acid would be used to neutralize sludge base components (hydroxides and carbonates) prior to the addition of late wash PHA. The late wash PHA will contain sufficient quantities of formic acid to adequately complete necessary reduction-oxidation (REDOX) reactions. The use of this flowsheet may result in a change in the nominal concentrations of two of the major REDOX reaction participants: formate (HCOO{sup minus}) and nitrate (NO{sub 3}{sup minus}).

Research Organization:
Savannah River Site (SRS), Aiken, SC (United States)
Sponsoring Organization:
USDOE, Washington, DC (United States)
DOE Contract Number:
AC09-89SR18035
OSTI ID:
10123952
Report Number(s):
WSRC-TR-92-491; ON: DE93006246
Resource Relation:
Other Information: PBD: 22 Oct 1992
Country of Publication:
United States
Language:
English