Aqueous sulfate separation by crystallization of sulfate–water clusters

Custelcean, Radu; Williams, Neil J.; Seipp, Charles A.

doi:10.1002/anie.201506314

Title: Aqueous sulfate separation by crystallization of sulfate–water clusters

Journal Article · Fri Aug 07 00:00:00 EDT 2015 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201506314· OSTI ID:1213344

Custelcean, Radu ^[1]; Williams, Neil J. ^[2]; Seipp, Charles A. ^[3]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Texas at Austin, Austin, TX (United States)

An effective approach to separating sulfates from aqueous solutions is based on the crystallization of extended [SO₄(H₂O) ₅^2-]_n sulfate–water clusters with a bis(guanidinium) ligand. The ligand was generated in situ by hydrazone condensation in water, thus avoiding elaborate syntheses, tedious purifications, and organic solvents. Crystallization of sulfate–water clusters represents an alternative to the now established sulfate separation strategies that involve encapsulating the “naked” anion.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1213344

Journal Information:: Angewandte Chemie (International Edition), Vol. 54, Issue 36; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 40 works

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Aqueous Sulfate Separation by Sequestration of [(SO ₄ ) ₂ (H ₂ O) ₄ ] ⁴⁻ Clusters within Highly Insoluble Imine-Linked Bis-Guanidinium Crystals Custelcean, Radu; Williams, Neil J.; Seipp, Charles A. Chemistry - A European Journal, Vol. 22, Issue 6 https://doi.org/10.1002/chem.201504651	journal	December 2015
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Efficient and selective separation of aqueous sulfate through recognition and precipitation Ke, Ya-Ting; Chou, Wei-Tzu; Chiang, Yi-Fen New Journal of Chemistry, Vol. 41, Issue 6 https://doi.org/10.1039/c6nj03710k	journal	January 2017
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CCDC 1404313: Experimental Crystal Structure Determination: LUVYEI : (ethane-1,2-diylidenedihydrazin-1-yl-2-ylidene)bis(aminomethaniminium) sulfate pentahydrate Custelcean, Radu; Williams, Neil J.; Seipp, Charles A. https://doi.org/10.5517/cc1j49fd The current record is supplemented by this dataset	dataset	June 2015
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CCDC 1404315: Experimental Crystal Structure Determination: LUVYOS : (ethane-1,2-diylidenedihydrazin-1-yl-2-ylidene)bis(aminomethaniminium) diperchlorate Custelcean, Radu; Williams, Neil J.; Seipp, Charles A. https://doi.org/10.5517/cc1j49hg The current record is supplemented by this dataset	dataset	June 2015