Topotactic Synthesis of Phosphabenzene-Functionalized Porous Organic Polymers: Efficient Ligands in CO2 Conversion
Abstract
Progress toward the preparation of porous organic polymers (POPs) with task-specific functionalities has been exceedingly slow—especially where polymers containing low-oxidation phosphorus in the structure are concerned. In this work, a two-step topotactic pathway for the preparation of phosphabenzene-based POPs (Phos-POPs) under metal-free conditions is reported, without the use of unstable phosphorus-based monomers. The synthetic route allows additional functionalities to be introduced into the porous polymer framework with ease. As an example, partially fluorinated Phos-POPs (F-Phos-POPs) were obtained with a surface area of up to 591 m2 g–1. After coordination with Ru species, a Ru/F-Phos-POPs catalyst exhibited high catalytic efficiency in the formylation of amines (turnover frequency up to 204 h–1) using a CO2/H2 mixture, in comparison with the non-fluorinated analogue (43 h–1) and a Au/TiO2 heterogeneous catalysts reported previously (<44 h–1). This work describes a practical method for synthesis of porous organic phosphorus-based polymers with applications in transition-metal-based heterogeneous catalysis.
- Authors:
-
- Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Univ. of Tennessee, Knoxville, TN (United States)
- Univ. of California, Riverside, CA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division
- OSTI Identifier:
- 1808416
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition); Journal Volume: 58; Journal Issue: 39; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yang, Zhenzhen, Chen, Hao, Li, Bo, Guo, Wei, Jie, Kecheng, Sun, Yifan, Jiang, De-en, Popovs, Ilja, and Dai, Sheng. Topotactic Synthesis of Phosphabenzene-Functionalized Porous Organic Polymers: Efficient Ligands in CO2 Conversion. United States: N. p., 2019.
Web. doi:10.1002/anie.201907015.
Yang, Zhenzhen, Chen, Hao, Li, Bo, Guo, Wei, Jie, Kecheng, Sun, Yifan, Jiang, De-en, Popovs, Ilja, & Dai, Sheng. Topotactic Synthesis of Phosphabenzene-Functionalized Porous Organic Polymers: Efficient Ligands in CO2 Conversion. United States. https://doi.org/10.1002/anie.201907015
Yang, Zhenzhen, Chen, Hao, Li, Bo, Guo, Wei, Jie, Kecheng, Sun, Yifan, Jiang, De-en, Popovs, Ilja, and Dai, Sheng. Tue .
"Topotactic Synthesis of Phosphabenzene-Functionalized Porous Organic Polymers: Efficient Ligands in CO2 Conversion". United States. https://doi.org/10.1002/anie.201907015. https://www.osti.gov/servlets/purl/1808416.
@article{osti_1808416,
title = {Topotactic Synthesis of Phosphabenzene-Functionalized Porous Organic Polymers: Efficient Ligands in CO2 Conversion},
author = {Yang, Zhenzhen and Chen, Hao and Li, Bo and Guo, Wei and Jie, Kecheng and Sun, Yifan and Jiang, De-en and Popovs, Ilja and Dai, Sheng},
abstractNote = {Progress toward the preparation of porous organic polymers (POPs) with task-specific functionalities has been exceedingly slow—especially where polymers containing low-oxidation phosphorus in the structure are concerned. In this work, a two-step topotactic pathway for the preparation of phosphabenzene-based POPs (Phos-POPs) under metal-free conditions is reported, without the use of unstable phosphorus-based monomers. The synthetic route allows additional functionalities to be introduced into the porous polymer framework with ease. As an example, partially fluorinated Phos-POPs (F-Phos-POPs) were obtained with a surface area of up to 591 m2 g–1. After coordination with Ru species, a Ru/F-Phos-POPs catalyst exhibited high catalytic efficiency in the formylation of amines (turnover frequency up to 204 h–1) using a CO2/H2 mixture, in comparison with the non-fluorinated analogue (43 h–1) and a Au/TiO2 heterogeneous catalysts reported previously (<44 h–1). This work describes a practical method for synthesis of porous organic phosphorus-based polymers with applications in transition-metal-based heterogeneous catalysis.},
doi = {10.1002/anie.201907015},
journal = {Angewandte Chemie (International Edition)},
number = 39,
volume = 58,
place = {United States},
year = {Tue Jul 16 00:00:00 EDT 2019},
month = {Tue Jul 16 00:00:00 EDT 2019}
}
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