Compact TDLAS based optical sensor for ppb-level ethane detection by use of a 3.34 μm room-temperature CW interband cascade laser
Abstract
A mid-infrared ethane (C2H6) sensor based on a wavelength modulation spectroscopy (WMS) technique was developed using a thermoelectrically cooled (TEC), continuous-wave (CW) interband cascade laser (ICL) emitting at 3.34 μm and a dense multi-pass gas cell (MPGC, 17 × 6.5 × 5.5 cm3) with a 54.6 m optical path length. A compact optical sensor system with a physical size of 35.5 × 18 × 12.5 cm3 was designed and constructed. An ICL was employed for targeting a strong C2H6 line at 2996.88 cm-1 at <100 Torr gas pressure in the fundamental absorption band of C2H6. The sensor performance, including the minimum detection limit (MDL) and the stability were improved by reducing the effect of laser power drift by means of the 2f/1f-WMS technique. A MDL of ~1.2 parts per billion (ppbv) for 2f-WMS and ~1.0 ppbv for 2f/1f-WMS were achieved, respectively, with a measurement time of 4 s. The MDL was further improved from 299 pptv (@108 s for 2f-WMS) to 239 pptv (@208 s for 2f/1f-WMS), based on an Allan deviation analysis.The rise time (@0 → 100 ppbv) and fall time (@100 → 0 ppbv) were determined to be ~64 s and ~48 s,respectively, at a gas pressure ofmore »
- Authors:
-
- Rice Univ., Houston, TX (United States). Dept. of Electrical and Computer Engineering; Jilin Univ., Changchun (China). State Key Lab. on Integrated Optoelectronics and College of Electronic Science and Engineering
- Rice Univ., Houston, TX (United States). Dept. of Electrical and Computer Engineering; Shanxi Univ., Taiyuan (China). State Key Lab. of Quantum Optics and Quantum Optics Devices and Inst. of Laser Spectroscopy
- Rice Univ., Houston, TX (United States). Dept. of Electrical and Computer Engineering
- Publication Date:
- Research Org.:
- Rice Univ., Houston, TX (United States)
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E); China Scholarship Council; National Science Foundation (NSF); Welch Foundation, Houston, TX (United States); National Natural Science Foundation of China (NSFC); Changchun Municipal Science and Technology Bureau
- OSTI Identifier:
- 1435936
- Report Number(s):
- DOE-MAXION-00538-16
Journal ID: ISSN 0925-4005; PII: S092540051630435X
- Grant/Contract Number:
- AR0000538; 201406170107; C-0586; IIP-1230427; AR0000547; AR0000545; 201506175025; 61307124; 14KG022; 61575113; 61275213
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Sensors and Actuators. B, Chemical
- Additional Journal Information:
- Journal Volume: 232; Journal Issue: C; Journal ID: ISSN 0925-4005
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 03 NATURAL GAS; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; 47 OTHER INSTRUMENTATION; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; C2H6 sensor; Infrared spectroscopy; Interband cascade laser
Citation Formats
Li, Chunguang, Dong, Lei, Zheng, Chuantao, and Tittel, Frank K. Compact TDLAS based optical sensor for ppb-level ethane detection by use of a 3.34 μm room-temperature CW interband cascade laser. United States: N. p., 2016.
Web. doi:10.1016/j.snb.2016.03.141.
Li, Chunguang, Dong, Lei, Zheng, Chuantao, & Tittel, Frank K. Compact TDLAS based optical sensor for ppb-level ethane detection by use of a 3.34 μm room-temperature CW interband cascade laser. United States. https://doi.org/10.1016/j.snb.2016.03.141
Li, Chunguang, Dong, Lei, Zheng, Chuantao, and Tittel, Frank K. Sat .
"Compact TDLAS based optical sensor for ppb-level ethane detection by use of a 3.34 μm room-temperature CW interband cascade laser". United States. https://doi.org/10.1016/j.snb.2016.03.141. https://www.osti.gov/servlets/purl/1435936.
@article{osti_1435936,
title = {Compact TDLAS based optical sensor for ppb-level ethane detection by use of a 3.34 μm room-temperature CW interband cascade laser},
author = {Li, Chunguang and Dong, Lei and Zheng, Chuantao and Tittel, Frank K.},
abstractNote = {A mid-infrared ethane (C2H6) sensor based on a wavelength modulation spectroscopy (WMS) technique was developed using a thermoelectrically cooled (TEC), continuous-wave (CW) interband cascade laser (ICL) emitting at 3.34 μm and a dense multi-pass gas cell (MPGC, 17 × 6.5 × 5.5 cm3) with a 54.6 m optical path length. A compact optical sensor system with a physical size of 35.5 × 18 × 12.5 cm3 was designed and constructed. An ICL was employed for targeting a strong C2H6 line at 2996.88 cm-1 at <100 Torr gas pressure in the fundamental absorption band of C2H6. The sensor performance, including the minimum detection limit (MDL) and the stability were improved by reducing the effect of laser power drift by means of the 2f/1f-WMS technique. A MDL of ~1.2 parts per billion (ppbv) for 2f-WMS and ~1.0 ppbv for 2f/1f-WMS were achieved, respectively, with a measurement time of 4 s. The MDL was further improved from 299 pptv (@108 s for 2f-WMS) to 239 pptv (@208 s for 2f/1f-WMS), based on an Allan deviation analysis.The rise time (@0 → 100 ppbv) and fall time (@100 → 0 ppbv) were determined to be ~64 s and ~48 s,respectively, at a gas pressure of <100 Torr for the C2H6 sensor operation.},
doi = {10.1016/j.snb.2016.03.141},
journal = {Sensors and Actuators. B, Chemical},
number = C,
volume = 232,
place = {United States},
year = {Sat Mar 26 00:00:00 EDT 2016},
month = {Sat Mar 26 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Influence of biomass burning during recent fluctuations in the slow growth of global tropospheric methane
journal, January 2006
- Simpson, Isobel J.; Rowland, F. Sherwood; Meinardi, Simone
- Geophysical Research Letters, Vol. 33, Issue 22
Global budget of ethane and regional constraints on U.S. sources
journal, January 2008
- Xiao, Yaping; Logan, Jennifer A.; Jacob, Daniel J.
- Journal of Geophysical Research, Vol. 113, Issue D21
An improved algorithm for locating a gas source using inverse methods
journal, February 2007
- Thomson, Laura C.; Hirst, Bill; Gibson, Graham
- Atmospheric Environment, Vol. 41, Issue 6
Earth's Degassing: A Missing Ethane and Propane Source
journal, January 2009
- Etiope, G.; Ciccioli, P.
- Science, Vol. 323, Issue 5913
Elevation of Exhaled Ethane Concentration in Asthma
journal, October 2000
- Paredi, Paolo; Kharitonov, Sergei A.; Barnes, Peter J.
- American Journal of Respiratory and Critical Care Medicine, Vol. 162, Issue 4
Increased levels of ethane, a non-invasive, quantitative, direct marker of n-3 lipid peroxidation, in the breath of patients with schizophrenia
journal, April 2008
- Puri, Basant K.; Ross, Brian M.; Treasaden, Ian H.
- Progress in Neuro-Psychopharmacology and Biological Psychiatry, Vol. 32, Issue 3
Application of laser spectroscopy for measurement of exhaled ethane in patients with lung cancer
journal, February 2006
- Skeldon, K. D.; McMillan, L. C.; Wyse, C. A.
- Respiratory Medicine, Vol. 100, Issue 2
Frequency-modulation spectroscopy for trace species detection: theory and comparison among experimental methods
journal, January 1992
- Silver, Joel A.
- Applied Optics, Vol. 31, Issue 6, p. 707-717
A review of recent advances in semiconductor laser based gas monitors
journal, February 1998
- Werle, Peter
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 54, Issue 2
Wavelength Modulation Spectroscopy: Combined Frequency and Intensity Laser Modulation
journal, January 2003
- Schilt, Stéphane; Thévenaz, Luc; Robert, Philippe
- Applied Optics, Vol. 42, Issue 33
Dual interband cascade laser based trace-gas sensor for environmental monitoring
journal, January 2007
- Wysocki, Gerard; Bakhirkin, Yury; So, Stephen
- Applied Optics, Vol. 46, Issue 33
Laser Spectroscopy for Atmospheric and Environmental Sensing
journal, December 2009
- Fiddler, Marc; Begashaw, Israel; Mickens, Matthew
- Sensors, Vol. 9, Issue 12
Quantum cascade lasers in chemical physics
journal, February 2010
- Curl, Robert F.; Capasso, Federico; Gmachl, Claire
- Chemical Physics Letters, Vol. 487, Issue 1-3
Recent advances of laser-spectroscopy-based techniques for applications in breath analysis
journal, July 2007
- McCurdy, Matthew R.; Bakhirkin, Yury; Wysocki, Gerard
- Journal of Breath Research, Vol. 1, Issue 1
Current status of midinfrared quantum and interband cascade lasers for clinical breath analysis
journal, November 2010
- Tittel, Frank K.
- Optical Engineering, Vol. 49, Issue 11
Multicomponent Breath Analysis With Infrared Absorption Using Room-Temperature Quantum Cascade Lasers
journal, January 2010
- Shorter, Joanne H.; Nelson, David D.; McManus, J. Barry
- IEEE Sensors Journal, Vol. 10, Issue 1
Clinical study of multiple breath biomarkers of asthma and COPD (NO, CO 2 , CO and N 2 O) by infrared laser spectroscopy
journal, July 2011
- Shorter, Joanne H.; Nelson, David D.; McManus, J. Barry
- Journal of Breath Research, Vol. 5, Issue 3
Exhaled nitric oxide parameters and functional capacity in chronic obstructive pulmonary disease
journal, January 2011
- McCurdy, Matthew R.; Sharafkhaneh, Amir; Abdel-Monem, Hanan
- Journal of Breath Research, Vol. 5, Issue 1
Off-axis integrated cavity output spectroscopy with a mid-infrared interband cascade laser for real-time breath ethane measurements
journal, December 2008
- Parameswaran, Krishnan R.; Rosen, David I.; Allen, Mark G.
- Applied Optics, Vol. 48, Issue 4
Online monitoring of ethane traces in exhaled breath with a difference frequency generation spectrometer
journal, June 2006
- Halmer, D.; Thelen, S.; Hering, P.
- Applied Physics B, Vol. 85, Issue 2-3
Spectroscopic trace-gas sensor with rapidly scanned wavelengths of a pulsed quantum cascade laser for in situ NO monitoring of industrial exhaust systems
journal, March 2005
- Wysocki, G.; Kosterev, A. A.; Tittel, F. K.
- Applied Physics B, Vol. 80, Issue 4-5
Food monitoring based on diode laser gas spectroscopy
journal, September 2008
- Lewander, M.; Guan, Z. G.; Persson, L.
- Applied Physics B, Vol. 93, Issue 2-3
Atmospheric Formaldehyde Monitoring in the Greater Houston Area in 2002
journal, February 2004
- Chen, Jinhai; So, Stephen; Lee, Hoason
- Applied Spectroscopy, Vol. 58, Issue 2
Photoacoustic spectroscopy of formaldehyde with tunable laser radiation at the parts per billion level
journal, June 2006
- Angelmahr, M.; Miklós, A.; Hess, P.
- Applied Physics B, Vol. 85, Issue 2-3
A formaldehyde trace gas sensor based on a thermoelectrically cooled CW-DFB quantum cascade laser
journal, January 2014
- Li, Jingsong; Parchatka, Uwe; Fischer, Horst
- Anal. Methods, Vol. 6, Issue 15
Detection of formaldehyde using off-axis integrated cavity output spectroscopy with an interband cascade laser
journal, June 2006
- Miller, J. H.; Bakhirkin, Y. A.; Ajtai, T.
- Applied Physics B, Vol. 85, Issue 2-3
CW DFB RT diode laser-based sensor for trace-gas detection of ethane using a novel compact multipass gas absorption cell
journal, June 2013
- Krzempek, Karol; Jahjah, Mohammad; Lewicki, Rafał
- Applied Physics B, Vol. 112, Issue 4
Continuous wave, distributed feedback diode laser based sensor for trace-gas detection of ethane
journal, January 2012
- Krzempek, K.; Lewicki, R.; Nähle, L.
- Applied Physics B, Vol. 106, Issue 2
Calibration-free wavelength-modulation spectroscopy for measurements of gas temperature and concentration in harsh environments
journal, January 2009
- Rieker, Gregory B.; Jeffries, Jay B.; Hanson, Ronald K.
- Applied Optics, Vol. 48, Issue 29, p. 5546-5560
Calibration-free wavelength modulation for gas sensing in tunable diode laser absorption spectroscopy
journal, October 2014
- Lan, L. J.; Ding, Y. J.; Peng, Z. M.
- Applied Physics B, Vol. 117, Issue 4
The HITRAN2012 molecular spectroscopic database
journal, November 2013
- Rothman, L. S.; Gordon, I. E.; Babikov, Y.
- Journal of Quantitative Spectroscopy and Radiative Transfer, Vol. 130, p. 4-50
Works referencing / citing this record:
Near-Infrared C2H2 Detection System Based on Single Optical Path Time Division Multiplexing Differential Modulation Technique and Multi-Reflection Chamber
journal, June 2019
- Wang, Biao; Lu, Hongfei; Chen, Chen
- Applied Sciences, Vol. 9, Issue 13
Measurement of ethylene in combustion exhaust using a 3.3-μm distributed feedback interband cascade laser with wavelength modulation spectroscopy
journal, July 2017
- Tanaka, Kotaro; Akishima, Kazushi; Sekita, Masahiro
- Applied Physics B, Vol. 123, Issue 8
A near-infrared carbon dioxide sensor system using a compact folded optical structure for deep-sea natural gas hydrate exploration
journal, January 2018
- Liu, Zhiwei; Zheng, Chuantao; Chen, Chen
- Analytical Methods, Vol. 10, Issue 39
High-speed multi-pass tunable diode laser absorption spectrometer based on frequency-modulation spectroscopy
journal, January 2018
- Li, Chuanliang; Shao, Ligang; Meng, Huiyan
- Optics Express, Vol. 26, Issue 22
Calculation model of dense spot pattern multi-pass cells based on a spherical mirror aberration
journal, January 2019
- Cui, Ruyue; Dong, Lei; Wu, Hongpeng
- Optics Letters, Vol. 44, Issue 5
Study on Mnospectral Peak Identification of Hard Target Based on Brewster Angle
journal, January 2020
- Liu, Jia Xiang; Liu, Jia Ju; Zhu, Zhi Zheng
- IOP Conference Series: Materials Science and Engineering, Vol. 711
A Trace C2H2 Sensor Based on an Absorption Spectrum Technique Using a Mid-Infrared Interband Cascade Laser
journal, October 2018
- Mu, Ye; Hu, Tianli; Gong, He
- Micromachines, Vol. 9, Issue 10
Highly sensitive and selective CO sensor using a 233 μm diode laser and wavelength modulation spectroscopy
journal, January 2018
- Cui, Ruyue; Dong, Lei; Wu, Hongpeng
- Optics Express, Vol. 26, Issue 19
Mid-Infrared Tunable Laser-Based Broadband Fingerprint Absorption Spectroscopy for Trace Gas Sensing: A Review
journal, January 2019
- Du, Zhenhui; Zhang, Shuai; Li, Jinyi
- Applied Sciences, Vol. 9, Issue 2
CH 4 Concentration Distribution in a Semiconductor Process Chamber Measured by the CT-TDLAS
journal, January 2018
- Hayashi, Daisuke; Nakai, Junya; Minami, Masakazu
- ECS Journal of Solid State Science and Technology, Vol. 7, Issue 11