Antiferromagnetism in semiconducting SrMn2Sb2 and BaMn2Sb2 single crystals

Sangeetha, N. S.; Smetana, V.; Mudring, A. -V.; Johnston, D. C.

doi:10.1103/PhysRevB.97.014402

Title: Antiferromagnetism in semiconducting ${SrMn}_{2} {Sb}_{2}$ and ${BaMn}_{2} {Sb}_{2}$ single crystals

Abstract

Here, crystals of SrMn₂Sb₂ and BaMn₂Sb₂ were grown using Sn flux and characterized by powder and single-crystal x-ray diffraction, respectively, and by single-crystal electrical resistivity ρ, heat capacity C_p, and magnetic susceptibility χ measurements versus temperature T, and magnetization versus field M(H) isotherm measurements. SrMn₂Sb₂ adopts the trigonal CaAl₂Si₂-type structure, whereas BaMn₂Sb₂ crystallizes in the tetragonal ThCr₂Si₂-type structure. The ρ(T) data indicate semiconducting behaviors for both compounds with activation energies of ≳0.35 eV for SrMn₂Sb₂ and 0.16 eV for BaMn₂Sb₂. The χ(T) and C_p(T) data reveal antiferromagnetic (AFM) ordering at T_N = 110 K for SrMn₂Sb₂ and 450 K for BaMn₂Sb₂. The anisotropic χ(T≤T_N) data also show that the ordered moments in SrMn₂Sb₂ are aligned in the hexagonal ab plane, whereas the ordered moments in BaMn₂Sb₂ are aligned collinearly along the tetragonal c axis. The ab-plane M(H) data for SrMn₂Sb₂ exhibit a continuous metamagnetic transition at low fields 02Sb₂ exhibits no metamagnetic transitions up to 5.5 T. The χ(T) and C_p(T) data for both SrMn₂Sb₂ and BaMn₂Sb₂ indicate strong dynamic short-range AFM correlations above their respective T_N up to at least 900 K within a local-moment picture, corresponding to quasi-two-dimensional magnetic behavior. The present results and a survey of themore »« less

Authors:

Sangeetha, N. S. ^[1]; Smetana, V. ^[2]; Mudring, A. -V. ^[2]; Johnston, D. C. ^[1]

Ames Lab. and Iowa State Univ., Ames, IA (United States)
Stockholm Univ., Stockholm (Sweden)

Publication Date:: Wed Jan 03 00:00:00 EST 2018

Research Org.:: Ames Lab., Ames, IA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1417355

Alternate Identifier(s):: OSTI ID: 1415526

Report Number(s):: IS-J-9555
Journal ID: ISSN 2469-9950; PRBMDO; TRN: US1801041

Grant/Contract Number:: AC02-07CH11358

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 97; Journal Issue: 1; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Sangeetha, N. S., Smetana, V., Mudring, A. -V., and Johnston, D. C. Antiferromagnetism in semiconducting SrMn2Sb2 and BaMn2Sb2 single crystals.  United States: N. p., 2018. 
Web.  doi:10.1103/PhysRevB.97.014402.

Copy to clipboard


                    Sangeetha, N. S., Smetana, V., Mudring, A. -V., & Johnston, D. C. Antiferromagnetism in semiconducting SrMn2Sb2 and BaMn2Sb2 single crystals.  United States.  https://doi.org/10.1103/PhysRevB.97.014402

Copy to clipboard


                    Sangeetha, N. S., Smetana, V., Mudring, A. -V., and Johnston, D. C. Wed .  
"Antiferromagnetism in semiconducting SrMn2Sb2 and BaMn2Sb2 single crystals".  United States.  https://doi.org/10.1103/PhysRevB.97.014402.  https://www.osti.gov/servlets/purl/1417355.

Copy to clipboard


                    
@article{osti_1417355,

  title        = {Antiferromagnetism in semiconducting SrMn2Sb2 and BaMn2Sb2 single crystals},

  author       = {Sangeetha, N. S. and Smetana, V. and Mudring, A. -V. and Johnston, D. C.},

  abstractNote = {Here, crystals of SrMn2Sb2 and BaMn2Sb2 were grown using Sn flux and characterized by powder and single-crystal x-ray diffraction, respectively, and by single-crystal electrical resistivity ρ, heat capacity Cp, and magnetic susceptibility χ measurements versus temperature T, and magnetization versus field M(H) isotherm measurements. SrMn2Sb2 adopts the trigonal CaAl2Si2-type structure, whereas BaMn2Sb2 crystallizes in the tetragonal ThCr2Si2-type structure. The ρ(T) data indicate semiconducting behaviors for both compounds with activation energies of ≳0.35 eV for SrMn2Sb2 and 0.16 eV for BaMn2Sb2. The χ(T) and Cp(T) data reveal antiferromagnetic (AFM) ordering at TN = 110 K for SrMn2Sb2 and 450 K for BaMn2Sb2. The anisotropic χ(T≤TN) data also show that the ordered moments in SrMn2Sb2 are aligned in the hexagonal ab plane, whereas the ordered moments in BaMn2Sb2 are aligned collinearly along the tetragonal c axis. The ab-plane M(H) data for SrMn2Sb2 exhibit a continuous metamagnetic transition at low fields 02Sb2 exhibits no metamagnetic transitions up to 5.5 T. The χ(T) and Cp(T) data for both SrMn2Sb2 and BaMn2Sb2 indicate strong dynamic short-range AFM correlations above their respective TN up to at least 900 K within a local-moment picture, corresponding to quasi-two-dimensional magnetic behavior. The present results and a survey of the literature for Mn pnictides with the CaAl2Si2 and ThCr2Si2 crystal structures show that the TN values for the CaAl2Si2-type compounds are much smaller than those for the ThCr2Si2-type materials.},

  doi          = {10.1103/PhysRevB.97.014402},

  journal      = {Physical Review B},

  number       = 1,

  volume       = 97,

  place        = {United States},

  year         = {Wed Jan 03 00:00:00 EST 2018},

  month        = {Wed Jan 03 00:00:00 EST 2018}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1103/PhysRevB.97.014402

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 20 works

Citation information provided by
Web of Science

Figures / Tables:

TABLE I:: Properties of 1111-type and 122-type Mn pnictides, including results from the present work (PW). Included are the structure type, AFM ordering temperatures T_N, low temperature ordered moment µ, and semiconducting activation energy . The ZrCuSiAs structure is primitive tetragonal with space group P4/nmm, the ThCr₂Si₂ structure is body-centeredmore »

All figures and tables (12 total)

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

The first order phase transition and superconductivity in BaNi ₂ As ₂ single crystals
journal, August 2008

Ronning, F.; Kurita, N.; Bauer, E. D.
Journal of Physics: Condensed Matter, Vol. 20, Issue 34
DOI: 10.1088/0953-8984/20/34/342203

Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo $_{2}$ As $_{2}$
journal, July 2013

Pandey, Abhishek; Quirinale, D. G.; Jayasekara, W.
Physical Review B, Vol. 88, Issue 1
DOI: 10.1103/PhysRevB.88.014526

${EuCo}_{2} P_{2}$ : A model molecular-field helical Heisenberg antiferromagnet
journal, July 2016

Sangeetha, N. S.; Cuervo-Reyes, Eduardo; Pandey, Abhishek
Physical Review B, Vol. 94, Issue 1
DOI: 10.1103/PhysRevB.94.014422

Itinerant and local-moment magnetism in ${EuCr}_{2}$ ${As}_{2}$ single crystals
journal, April 2014

Paramanik, U. B.; Prasad, R.; Geibel, C.
Physical Review B, Vol. 89, Issue 14
DOI: 10.1103/PhysRevB.89.144423

Strong magnetic correlations to 900 K in single crystals of the trigonal antiferromagnetic insulators ${SrMn}_{2} {As}_{2}$ and ${CaMn}_{2} {As}_{2}$
journal, September 2016

Sangeetha, N. S.; Pandey, Abhishek; Benson, Zackery A.
Physical Review B, Vol. 94, Issue 9
DOI: 10.1103/PhysRevB.94.094417

Pressure-induced metallization of BaMn $_{2}$ As $_{2}$
journal, November 2011

Satya, A. T.; Mani, Awadhesh; Arulraj, A.
Physical Review B, Vol. 84, Issue 18
DOI: 10.1103/PhysRevB.84.180515

Structure and magnetic properties of $L n MnSbO$ ( $L n = La$ and Ce)
journal, March 2016

Zhang, Qiang; Kumar, C. M. N.; Tian, Wei
Physical Review B, Vol. 93, Issue 9
DOI: 10.1103/PhysRevB.93.094413

Field-induced spin-flop transitions in single-crystalline CaCo $_{2}$ As $_{2}$
journal, April 2012

Cheng, B.; Hu, B. F.; Yuan, R. H.
Physical Review B, Vol. 85, Issue 14
DOI: 10.1103/PhysRevB.85.144426

Structural and physical properties of SrMn2As2
journal, May 2011

Wang, Z. W.; Yang, H. X.; Tian, H. F.
Journal of Physics and Chemistry of Solids, Vol. 72, Issue 5
DOI: 10.1016/j.jpcs.2010.10.053

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015

Krause, Lennard; Herbst-Irmer, Regine; Sheldrick, George M.
Journal of Applied Crystallography, Vol. 48, Issue 1
DOI: 10.1107/S1600576714022985

Magnetic order in ${BaMn}_{2} {As}_{2}$ from neutron diffraction measurements
journal, September 2009

Singh, Yogesh; Green, M. A.; Huang, Q.
Physical Review B, Vol. 80, Issue 10
DOI: 10.1103/PhysRevB.80.100403

Magnetic Susceptibility of Collinear and Noncollinear Heisenberg Antiferromagnets
journal, August 2012

Johnston, D. C.
Physical Review Letters, Vol. 109, Issue 7
DOI: 10.1103/PhysRevLett.109.077201

Antiferromagnetic structure and electronic properties of ${BaCr}_{2} {As}_{2}$ and ${BaCrFeAs}_{2}$
journal, May 2017

Filsinger, Kai A.; Schnelle, Walter; Adler, Peter
Physical Review B, Vol. 95, Issue 18
DOI: 10.1103/PhysRevB.95.184414

Combined Experimental and Density Functional Theory Studies on the Crystal Structures and Magnetic Properties of Mg(Mg _{1- x} Mn _x ) ₂ Sb ₂ ( x ≈ 0.25) and BaMn ₂ Sb ₂
journal, September 2008

Xia, Sheng-Qing; Myers, Chad; Bobev, Svilen
European Journal of Inorganic Chemistry, Vol. 2008, Issue 27
DOI: 10.1002/ejic.200800572

Neutron diffraction studies of CaMn2Ge2 and BaMn2Ge2 compounds: first examples of antiferromagnetic Mn planes in ThCr2Si2-type structure compounds
journal, August 1994

Malaman, B.; Venturini, G.; Welter, R.
Journal of Alloys and Compounds, Vol. 210, Issue 1-2
DOI: 10.1016/0925-8388(94)90140-6

The magnetic ground state of
journal, September 2009

Ratcliff II, W.; Lima Sharma, A. L.; Gomes, A. M.
Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 17
DOI: 10.1016/j.jmmm.2009.03.054

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Rodríguez-Carvajal, Juan
Physica B: Condensed Matter, Vol. 192, Issue 1-2
DOI: 10.1016/0921-4526(93)90108-I

From antiferromagnetic insulator to ferromagnetic metal: Effects of hydrogen substitution in LaMnAsO
journal, January 2013

Hanna, Taku; Matsuishi, Satoru; Kodama, Katsuaki
Physical Review B, Vol. 87, Issue 2
DOI: 10.1103/PhysRevB.87.020401

Iron-Based Layered Superconductor La[O _1- _x F _x ]FeAs ( x = 0.05−0.12) with T _c = 26 K
journal, March 2008

Kamihara, Yoichi; Watanabe, Takumi; Hirano, Masahiro
Journal of the American Chemical Society, Vol. 130, Issue 11
DOI: 10.1021/ja800073m

Coexistence of Half-Metallic Itinerant Ferromagnetism with Local-Moment Antiferromagnetism in ${Ba}_{0.60} K_{0.40} {Mn}_{2} {As}_{2}$
journal, July 2013

Pandey, Abhishek; Ueland, B. G.; Yeninas, S.
Physical Review Letters, Vol. 111, Issue 4
DOI: 10.1103/PhysRevLett.111.047001

Magnetic and structural phase diagram of CaMn $_{2}$ Sb $_{2}$
journal, November 2012

Simonson, J. W.; Smith, G. J.; Post, K.
Physical Review B, Vol. 86, Issue 18
DOI: 10.1103/PhysRevB.86.184430

Itinerant Ferromagnetism in the As $4 p$ Conduction Band of ${Ba}_{0.6} K_{0.4} {Mn}_{2} {As}_{2}$ Identified by X-Ray Magnetic Circular Dichroism
journal, May 2015

Ueland, B. G.; Pandey, Abhishek; Lee, Y.
Physical Review Letters, Vol. 114, Issue 21
DOI: 10.1103/PhysRevLett.114.217001

Thorium-doping–induced superconductivity up to 56 K in Gd _1−x Th _x FeAsO
journal, September 2008

Wang, Cao; Li, Linjun; Chi, Shun
EPL (Europhysics Letters), Vol. 83, Issue 6
DOI: 10.1209/0295-5075/83/67006

Magnetic structure and spin excitations in ${BaMn}_{2} {Bi}_{2}$
journal, February 2014

Calder, S.; Saparov, B.; Cao, H. B.
Physical Review B, Vol. 89, Issue 6
DOI: 10.1103/PhysRevB.89.064417

Synthesis, crystal structure and superconductivity of LaNiPO
journal, February 2008

Tegel, Marcus; Bichler, Daniel; Johrendt, Dirk
Solid State Sciences, Vol. 10, Issue 2
DOI: 10.1016/j.solidstatesciences.2007.08.016

Short- and long-range magnetic order in LaMnAsO
journal, February 2016

McGuire, Michael A.; Garlea, V. Ovidiu
Physical Review B, Vol. 93, Issue 5
DOI: 10.1103/PhysRevB.93.054404

${CaMn}_{2} {Sb}_{2}$ : Spin waves on a frustrated antiferromagnetic honeycomb lattice
journal, May 2015

McNally, D. E.; Simonson, J. W.; Kistner-Morris, J. J.
Physical Review B, Vol. 91, Issue 18
DOI: 10.1103/PhysRevB.91.180407

Superconductivity in iron compounds
journal, December 2011

Stewart, G. R.
Reviews of Modern Physics, Vol. 83, Issue 4
DOI: 10.1103/RevModPhys.83.1589

Pressure-induced collapsed-tetragonal phase in ${SrCo}_{2} {As}_{2}$
journal, December 2015

Jayasekara, W. T.; Kaluarachchi, U. S.; Ueland, B. G.
Physical Review B, Vol. 92, Issue 22
DOI: 10.1103/PhysRevB.92.224103

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

Sheldrick, George M.
Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
DOI: 10.1107/S2053273314026370

Anomalous magnetization in the layered itinerant ferromagnet LaCoAsO
journal, May 2009

Ohta, Hiroto; Yoshimura, Kazuyoshi
Physical Review B, Vol. 79, Issue 18
DOI: 10.1103/PhysRevB.79.184407

Synthesis and thermoelectric properties of BaMn2Sb2 single crystals
journal, May 2009

Wang, H. F.; Cai, K. F.; Li, H.
Journal of Alloys and Compounds, Vol. 477, Issue 1-2
DOI: 10.1016/j.jallcom.2008.10.080

Magnetic, transport, and thermal properties of single crystals of the layered arsenide ${BaMn}_{2} {As}_{2}$
journal, March 2009

Singh, Yogesh; Ellern, A.; Johnston, D. C.
Physical Review B, Vol. 79, Issue 9
DOI: 10.1103/PhysRevB.79.094519

Crystals, magnetic and electronic properties of a new ThCr2Si2-type BaMn2Bi2 and K-doped compositions
journal, August 2013

Saparov, Bayrammurad; Sefat, Athena S.
Journal of Solid State Chemistry, Vol. 204
DOI: 10.1016/j.jssc.2013.05.010

Weakly ferromagnetic metallic state in heavily doped Ba $_{1 - x}$ K $_{x}$ Mn $_{2}$ As $_{2}$
journal, April 2012

Bao, Jin-Ke; Jiang, Hao; Sun, Yun-Lei
Physical Review B, Vol. 85, Issue 14
DOI: 10.1103/PhysRevB.85.144523

Structural, thermal, magnetic, and electronic transport properties of the LaNi $_{2}$ (Ge $_{1 - x}$ P $_{x}$ ) $_{2}$ system
journal, February 2012

Goetsch, R. J.; Anand, V. K.; Pandey, Abhishek
Physical Review B, Vol. 85, Issue 5
DOI: 10.1103/PhysRevB.85.054517

A tetragonal polymorph of SrMn ₂ P ₂ made under high pressure – theory and experiment in harmony
journal, January 2017

Xie, Weiwei; Winiarski, Michał J.; Klimczuk, Tomasz
Dalton Transactions, Vol. 46, Issue 21
DOI: 10.1039/C7DT00781G

Is ${BaCr}_{2} {As}_{2}$ symmetrical to ${BaFe}_{2} {As}_{2}$ with respect to half $3 d$ shell filling?
journal, May 2017

Richard, P.; van Roekeghem, A.; Lv, B. Q.
Physical Review B, Vol. 95, Issue 18
DOI: 10.1103/PhysRevB.95.184516

Pressure-induced transition to the collapsed tetragonal phase in $BaC r_{2} A s_{2}$
journal, April 2017

Naumov, P. G.; Filsinger, K.; Barkalov, O. I.
Physical Review B, Vol. 95, Issue 14
DOI: 10.1103/PhysRevB.95.144106

Growth of MnSb single crystals by pulling with a seed from nonstoichiometric molten solution
journal, January 1977

Chen, Tu; Charlan, G. B.; Keezer, R. C.
Journal of Crystal Growth, Vol. 37, Issue 1
DOI: 10.1016/0022-0248(77)90140-3

Unusual Mn−Mn Spin Coupling in the Polar Intermetallic Compounds CaMn ₂ Sb ₂ and SrMn ₂ Sb ₂
journal, May 2006

Bobev, Svilen; Merz, Justin; Lima, Ana
Inorganic Chemistry, Vol. 45, Issue 10
DOI: 10.1021/ic060092e

Magnetic and electronic properties of ${CaMn}_{2} {Bi}_{2}$ : A possible hybridization gap semiconductor
journal, February 2015

Gibson, Q. D.; Wu, H.; Liang, T.
Physical Review B, Vol. 91, Issue 8
DOI: 10.1103/PhysRevB.91.085128

Crystal Magnetic Anisotropy and Magnetization of MnSb
journal, July 1968

Okita, Toshimichi; Makino, Yoshimi
Journal of the Physical Society of Japan, Vol. 25, Issue 1
DOI: 10.1143/JPSJ.25.120

Crystal structure refinement with SHELXL
journal, January 2015

Sheldrick, George M.
Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
DOI: 10.1107/S2053229614024218

Magnetic order in CaMn2Sb2 studied via powder neutron diffraction
journal, November 2009

Bridges, C. A.; Krishnamurthy, V. V.; Poulton, S.
Journal of Magnetism and Magnetic Materials, Vol. 321, Issue 22
DOI: 10.1016/j.jmmm.2009.07.015

Unified molecular field theory for collinear and noncollinear Heisenberg antiferromagnets
journal, February 2015

Johnston, David C.
Physical Review B, Vol. 91, Issue 6
DOI: 10.1103/PhysRevB.91.064427

On the coordination of ThCr2Si2 (BaAl4-type compounds within the field of free parameters
journal, January 1996

Just, G.; Paufler, P.
Journal of Alloys and Compounds, Vol. 232, Issue 1-2
DOI: 10.1016/0925-8388(95)01939-1

${Ba}_{0.4} {Rb}_{0.6} {Mn}_{2} {As}_{2}$ : A prototype half-metallic ferromagnet
journal, November 2015

Pandey, Abhishek; Johnston, D. C.
Physical Review B, Vol. 92, Issue 17
DOI: 10.1103/PhysRevB.92.174401

Superconductivity in ${SrNi}_{2} {As}_{2}$ single crystals
journal, November 2008

Bauer, E. D.; Ronning, F.; Scott, B. L.
Physical Review B, Vol. 78, Issue 17
DOI: 10.1103/PhysRevB.78.172504

Crystal and magnetic structure of CaCo $_{1.86}$ As $_{2}$ studied by x-ray and neutron diffraction
journal, November 2013

Quirinale, D. G.; Anand, V. K.; Kim, M. G.
Physical Review B, Vol. 88, Issue 17
DOI: 10.1103/PhysRevB.88.174420

From antiferromagnetic insulator to correlated metal in pressurized and doped LaMnPO
journal, May 2012

Simonson, J. W.; Yin, Z. P.; Pezzoli, M.
Proceedings of the National Academy of Sciences, Vol. 109, Issue 27
DOI: 10.1073/pnas.1117366109

Itinerant G-type antiferromagnetic order in ${SrCr}_{2} {As}_{2}$
journal, July 2017

Das, Pinaki; Sangeetha, N. S.; Lindemann, George R.
Physical Review B, Vol. 96, Issue 1
DOI: 10.1103/PhysRevB.96.014411

Persistence of local-moment antiferromagnetic order in Ba $_{1 - x}$ K $_{x}$ Mn $_{2}$ As $_{2}$
journal, April 2013

Lamsal, J.; Tucker, G. S.; Heitmann, T. W.
Physical Review B, Vol. 87, Issue 14
DOI: 10.1103/PhysRevB.87.144418

Gap states in insulating LaMnPO $_{1 - x}$ F $_{x}$ ( $x = 0$ –0.3)
journal, October 2011

Simonson, J. W.; Post, K.; Marques, C.
Physical Review B, Vol. 84, Issue 16
DOI: 10.1103/PhysRevB.84.165129

Renormalized behavior and proximity of ${BaCo}_{2} {As}_{2}$ to a magnetic quantum critical point
journal, January 2009

Sefat, A. S.; Singh, D. J.; Jin, R.
Physical Review B, Vol. 79, Issue 2
DOI: 10.1103/PhysRevB.79.024512

Collinear antiferromagnetism in trigonal SrMn ₂ As ₂ revealed by single-crystal neutron diffraction
journal, November 2016

Das, Pinaki; Sangeetha, N. S.; Pandey, Abhishek
Journal of Physics: Condensed Matter, Vol. 29, Issue 3
DOI: 10.1088/0953-8984/29/3/035802

Magnetic Structure and Electromagnetic Properties of LnCrAsO with a ZrCuSiAs-type Structure (Ln = La, Ce, Pr, and Nd)
journal, November 2013

Park, Sang-Won; Mizoguchi, Hiroshi; Kodama, Katsuaki
Inorganic Chemistry, Vol. 52, Issue 23
DOI: 10.1021/ic401487q

Antiferromagnetic bipolar semiconductor LaMnPO with ZrCuSiAs-type structure
journal, May 2009

Yanagi, Hiroshi; Watanabe, Takumi; Kodama, Katsuaki
Journal of Applied Physics, Vol. 105, Issue 9
DOI: 10.1063/1.3124582

Stripe Antiferromagnetic Spin Fluctuations in ${SrCo}_{2} {As}_{2}$
journal, October 2013

Jayasekara, W.; Lee, Y.; Pandey, Abhishek
Physical Review Letters, Vol. 111, Issue 15
DOI: 10.1103/PhysRevLett.111.157001

Resistivity and Magnetism of AMn2P2 (A = Sr, Ba): The Effect of Structure Type on Physical Properties
journal, December 1994

Brock, Stephanie L.; Greedan, J. E.; Kauzlarich, Susan M.
Journal of Solid State Chemistry, Vol. 113, Issue 2
DOI: 10.1006/jssc.1994.1375

Physical properties of metallic antiferromagnetic ${CaCo}_{1.86}$ ${As}_{2}$ single crystals
journal, June 2014

Anand, V. K.; Dhaka, R. S.; Lee, Y.
Physical Review B, Vol. 89, Issue 21
DOI: 10.1103/PhysRevB.89.214409

Insulator-to-metal transition and large thermoelectric effect in La _1−x Sr _x MnAsO
journal, April 2012

Sun, Yun-Lei; Bao, Jin-Ke; Luo, Yong-Kang
EPL (Europhysics Letters), Vol. 98, Issue 1
DOI: 10.1209/0295-5075/98/17009

A common thread: The pairing interaction for unconventional superconductors
journal, October 2012

Scalapino, D. J.
Reviews of Modern Physics, Vol. 84, Issue 4
DOI: 10.1103/RevModPhys.84.1383

Magnetic exchange interactions in ${BaMn}_{2} {As}_{2}$ : A case study of the $J_{1}$ - $J_{2}$ - $J_{c}$ Heisenberg model
journal, September 2011

Johnston, D. C.; McQueeney, R. J.; Lake, B.
Physical Review B, Vol. 84, Issue 9
DOI: 10.1103/PhysRevB.84.094445

The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides
journal, October 2010

Johnston, David C.
Advances in Physics, Vol. 59, Issue 6
DOI: 10.1080/00018732.2010.513480

Kramers non-magnetic superconductivity in Ln NiAsO superconductors
journal, September 2014

Li, Yuke; Luo, Yongkang; Li, Lin
Journal of Physics: Condensed Matter, Vol. 26, Issue 42
DOI: 10.1088/0953-8984/26/42/425701

Zur Struktur ternärer Übergangsmetallarsenide/On the Structure of Ternary Arsenides
journal, June 1980

Pfisterer, Martin; Nagorsen, Günter
Zeitschrift für Naturforschung B, Vol. 35, Issue 6
DOI: 10.1515/znb-1980-0611

Bindungsverhältnisse und magnetische Eigenschaften ternärer Arsenide ET2As2 / Bonding and Magnetic Properties in Ternary Arsenides ET2As2
journal, July 1983

Pfisterer, Martin; Nagorsen, Günter
Zeitschrift für Naturforschung B, Vol. 38, Issue 7
DOI: 10.1515/znb-1983-0704

Darstellung und Kristallstruktur von BaMn2Sb2, BaZn2Sb2 und BaCd2Sb2 / Preparation and Crystal Structure of BaMn2Sb2 , BaZn2Sb2 and BaCd2Sb2
journal, July 1979

Brechtel, Erwin; Cordier, Gerhard; Schäfer, Herbert
Zeitschrift für Naturforschung B, Vol. 34, Issue 7
DOI: 10.1515/znb-1979-0708

Neue intermetallische Verbindungen im anti-Ce2O2S-Strukturtyp. / New Intermetallic Compounds in the anti-Ce2O2S-Structure Type
journal, November 1976

Cordier, Gerhard; Schäfer, Herbert
Zeitschrift für Naturforschung B, Vol. 31, Issue 11
DOI: 10.1515/znb-1976-1105

Figures / Tables found in this record:

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

Similar Records in DOE PAGES and OSTI.GOV collections:

Strong magnetic correlations to 900 K in single crystals of the trigonal antiferromagnetic insulators ${SrMn}_{2} {As}_{2}$ and ${CaMn}_{2} {As}_{2}$

Journal Article Sangeetha, N. S. ; Pandey, Abhishek ; Benson, Zackery A. ; ... - Physical Review B

Crystallographic, electronic transport, thermal, and magnetic properties are reported for SrMn₂As₂ and CaMn₂As₂ single crystals grown using Sn flux. Rietveld refinements of powder x-ray diffraction data show that the two compounds are isostructural and crystallize in the trigonal CaAl₂Si₂-type structure (space groupmore »« less
Cited by 26
https://doi.org/10.1103/PhysRevB.94.094417

Full Text Available
Non-Fermi-liquid types of behavior associated with a magnetic quantum critical point in $Sr {({Co}_{1 - x} {Ni}_{x})}_{2} {As}_{2}$ single crystals

Journal Article Sangeetha, N. S. ; Wang, L. -L. ; Smirnov, A. V. ; ... - Physical Review B

The compound SrCo₂As₂ with the body-centered tetragonal ThCr₂Si₂ structure is known to remain paramagnetic down to a temperature T = 0.05 K, but inelastic neutron scattering studies have shown that both ferromagnetic (FM) and antiferromagnetic (AFM) fluctuations occur in single crystals. Thus it is of interest to study how the magnetism evolves on doping SrCo₂As₂. Previous work on polycrystalline samples of Sr (Co_1-x Ni_x)₂ As₂ indicated the development of AFM order for 0 < x ≲ 0.3. Here we studied single crystals of Sr(Co_1-x Ni_x)₂ As₂ for 0 < x ≤ 1 and confirmed the occurrence of AFM order whichmore »« less
Cited by 17
https://doi.org/10.1103/PhysRevB.100.094447

Full Text Available
Metallic behavior induced by potassium doping of the trigonal antiferromagnetic insulator ${EuMn}_{2} {As}_{2}$

Journal Article Anand, V. K. ; Johnston, D. C. - Physical Review B

Here, we report magnetic susceptibility χ, isothermal magnetization M, heat capacity C_p, and electrical resistivity ρ measurements on undoped EuMn₂As₂ and K-doped Eu_0.96K_0.04Mn₂As₂ and Eu_0.93K_0.07Mn₂As₂ single crystals with the trigonal CaAl₂Si₂-type structure as a function of temperature T and magnetic field H. EuMn₂As₂ has an insulating ground state with an activation energy of 52 meV and exhibits antiferromagnetic (AFM) ordering of the Eu⁺² spins S=7/2 at T_N1=15 K from C_p(T) and χ(T) data with a likely spin-reorientation transition at T_N2=5.0 K. The Mn⁺² 3d⁵ spins-5/2 exhibit AFM ordering at T_N=142 K from all three types of measurements. The M(H) isothermmore »« less
Cited by 12
https://doi.org/10.1103/PhysRevB.94.014431

Full Text Available
Enhanced moments of Eu in single crystals of the metallic helical antiferromagnet ${EuCo}_{2 - y} {As}_{2}$

Journal Article Sangeetha, N. S. ; Anand, V. K. ; Cuervo-Reyes, Eduardo ; ... - Physical Review B

>more »
Cited by 17
https://doi.org/10.1103/PhysRevB.97.144403

Full Text Available
Anomalous Composition-Induced Crossover in the Magnetic Properties of the Itinerant-Electron Antiferromagnet ${Ca}_{1 - x} {Sr}_{x} {Co}_{2 - y} {As}_{2}$

Journal Article Sangeetha, N. S. ; Smetana, V. ; Mudring, A. -V. ; ... - Physical Review Letters

We report the inference of Ying et al. [Europhys. Lett. 104, 67005 (2013)] of a composition-induced change from c-axis ordered-moment alignment in a collinear A-type antiferromagnetic (AFM) structure at small x to ab-plane alignment in an unknown AFM structure at larger x in Ca_1-xSr_xCo_2-yAs₂ with the body-centered tetragonal ThCr₂Si₂ structure is confirmed. Our major finding is an anomalous magnetic behavior in the crossover region 0.2 ≲ x ≲ 0.3 between these two phases. Also, in this region the magnetic susceptibility vs temperature χ_ab(T) measured with magnetic fields H applied in the ab plane exhibit typical AFM behaviors with cusps atmore »« less
Cited by 12
https://doi.org/10.1103/PhysRevLett.119.257203

Full Text Available

Similar Records

Title: Antiferromagnetism in semiconducting SrMn 2 Sb 2 and BaMn 2 Sb 2 single crystals

Abstract

Citation Formats

Figures / Tables:

The first order phase transition and superconductivity in BaNi 2 As 2 single crystals journal, August 2008

Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo 2 As 2 journal, July 2013

EuCo 2 P 2 : A model molecular-field helical Heisenberg antiferromagnet journal, July 2016

Itinerant and local-moment magnetism in EuCr 2 As 2 single crystals journal, April 2014

Strong magnetic correlations to 900 K in single crystals of the trigonal antiferromagnetic insulators SrMn 2 As 2 and CaMn 2 As 2 journal, September 2016

Pressure-induced metallization of BaMn 2 As 2 journal, November 2011

Structure and magnetic properties of L n MnSbO ( L n = La and Ce) journal, March 2016

Field-induced spin-flop transitions in single-crystalline CaCo 2 As 2 journal, April 2012

Structural and physical properties of SrMn2As2 journal, May 2011

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination journal, January 2015

Magnetic order in BaMn 2 As 2 from neutron diffraction measurements journal, September 2009

Magnetic Susceptibility of Collinear and Noncollinear Heisenberg Antiferromagnets journal, August 2012

Antiferromagnetic structure and electronic properties of BaCr 2 As 2 and BaCrFeAs 2 journal, May 2017

Combined Experimental and Density Functional Theory Studies on the Crystal Structures and Magnetic Properties of Mg(Mg 1- x Mn x ) 2 Sb 2 ( x ≈ 0.25) and BaMn 2 Sb 2 journal, September 2008

Neutron diffraction studies of CaMn2Ge2 and BaMn2Ge2 compounds: first examples of antiferromagnetic Mn planes in ThCr2Si2-type structure compounds journal, August 1994

The magnetic ground state of journal, September 2009

Recent advances in magnetic structure determination by neutron powder diffraction journal, October 1993

From antiferromagnetic insulator to ferromagnetic metal: Effects of hydrogen substitution in LaMnAsO journal, January 2013

Iron-Based Layered Superconductor La[O 1- x F x ]FeAs ( x = 0.05−0.12) with T c = 26 K journal, March 2008

Coexistence of Half-Metallic Itinerant Ferromagnetism with Local-Moment Antiferromagnetism in Ba 0.60 K 0.40 Mn 2 As 2 journal, July 2013

Magnetic and structural phase diagram of CaMn 2 Sb 2 journal, November 2012

Itinerant Ferromagnetism in the As 4 p Conduction Band of Ba 0.6 K 0.4 Mn 2 As 2 Identified by X-Ray Magnetic Circular Dichroism journal, May 2015

Thorium-doping–induced superconductivity up to 56 K in Gd 1−x Th x FeAsO journal, September 2008

Magnetic structure and spin excitations in BaMn 2 Bi 2 journal, February 2014

Synthesis, crystal structure and superconductivity of LaNiPO journal, February 2008

Short- and long-range magnetic order in LaMnAsO journal, February 2016

CaMn 2 Sb 2 : Spin waves on a frustrated antiferromagnetic honeycomb lattice journal, May 2015

Superconductivity in iron compounds journal, December 2011

Pressure-induced collapsed-tetragonal phase in SrCo 2 As 2 journal, December 2015

SHELXT – Integrated space-group and crystal-structure determination journal, January 2015

Anomalous magnetization in the layered itinerant ferromagnet LaCoAsO journal, May 2009

Synthesis and thermoelectric properties of BaMn2Sb2 single crystals journal, May 2009

Magnetic, transport, and thermal properties of single crystals of the layered arsenide BaMn 2 As 2 journal, March 2009

Crystals, magnetic and electronic properties of a new ThCr2Si2-type BaMn2Bi2 and K-doped compositions journal, August 2013

Weakly ferromagnetic metallic state in heavily doped Ba 1 − x K x Mn 2 As 2 journal, April 2012

Structural, thermal, magnetic, and electronic transport properties of the LaNi 2 (Ge 1 − x P x ) 2 system journal, February 2012

A tetragonal polymorph of SrMn 2 P 2 made under high pressure – theory and experiment in harmony journal, January 2017

Is BaCr 2 As 2 symmetrical to BaFe 2 As 2 with respect to half 3 d shell filling? journal, May 2017

Pressure-induced transition to the collapsed tetragonal phase in BaC r 2 A s 2 journal, April 2017

Growth of MnSb single crystals by pulling with a seed from nonstoichiometric molten solution journal, January 1977

Unusual Mn−Mn Spin Coupling in the Polar Intermetallic Compounds CaMn 2 Sb 2 and SrMn 2 Sb 2 journal, May 2006

Magnetic and electronic properties of CaMn 2 Bi 2 : A possible hybridization gap semiconductor journal, February 2015

Crystal Magnetic Anisotropy and Magnetization of MnSb journal, July 1968

Crystal structure refinement with SHELXL journal, January 2015

Magnetic order in CaMn2Sb2 studied via powder neutron diffraction journal, November 2009

Unified molecular field theory for collinear and noncollinear Heisenberg antiferromagnets journal, February 2015

On the coordination of ThCr2Si2 (BaAl4-type compounds within the field of free parameters journal, January 1996

Ba 0.4 Rb 0.6 Mn 2 As 2 : A prototype half-metallic ferromagnet journal, November 2015

Superconductivity in SrNi 2 As 2 single crystals journal, November 2008

Crystal and magnetic structure of CaCo 1.86 As 2 studied by x-ray and neutron diffraction journal, November 2013

From antiferromagnetic insulator to correlated metal in pressurized and doped LaMnPO journal, May 2012

Itinerant G-type antiferromagnetic order in SrCr 2 As 2 journal, July 2017

Persistence of local-moment antiferromagnetic order in Ba 1 − x K x Mn 2 As 2 journal, April 2013

Gap states in insulating LaMnPO 1 − x F x ( x = 0 –0.3) journal, October 2011

Renormalized behavior and proximity of BaCo 2 As 2 to a magnetic quantum critical point journal, January 2009

Collinear antiferromagnetism in trigonal SrMn 2 As 2 revealed by single-crystal neutron diffraction journal, November 2016

Magnetic Structure and Electromagnetic Properties of LnCrAsO with a ZrCuSiAs-type Structure (Ln = La, Ce, Pr, and Nd) journal, November 2013

Antiferromagnetic bipolar semiconductor LaMnPO with ZrCuSiAs-type structure journal, May 2009

Stripe Antiferromagnetic Spin Fluctuations in SrCo 2 As 2 journal, October 2013

Resistivity and Magnetism of AMn2P2 (A = Sr, Ba): The Effect of Structure Type on Physical Properties journal, December 1994

Physical properties of metallic antiferromagnetic CaCo 1.86 As 2 single crystals journal, June 2014

Insulator-to-metal transition and large thermoelectric effect in La 1−x Sr x MnAsO journal, April 2012

A common thread: The pairing interaction for unconventional superconductors journal, October 2012

Magnetic exchange interactions in BaMn 2 As 2 : A case study of the J 1 - J 2 - J c Heisenberg model journal, September 2011

The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides journal, October 2010

Kramers non-magnetic superconductivity in Ln NiAsO superconductors journal, September 2014

Zur Struktur ternärer Übergangsmetallarsenide/On the Structure of Ternary Arsenides journal, June 1980

Bindungsverhältnisse und magnetische Eigenschaften ternärer Arsenide ET2As2 / Bonding and Magnetic Properties in Ternary Arsenides ET2As2 journal, July 1983

Darstellung und Kristallstruktur von BaMn2Sb2, BaZn2Sb2 und BaCd2Sb2 / Preparation and Crystal Structure of BaMn2Sb2 , BaZn2Sb2 and BaCd2Sb2 journal, July 1979

Neue intermetallische Verbindungen im anti-Ce2O2S-Strukturtyp. / New Intermetallic Compounds in the anti-Ce2O2S-Structure Type journal, November 1976

Title: Antiferromagnetism in semiconducting ${SrMn}_{2} {Sb}_{2}$ and ${BaMn}_{2} {Sb}_{2}$ single crystals

The first order phase transition and superconductivity in BaNi ₂ As ₂ single crystals
journal, August 2008

Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo $_{2}$ As $_{2}$
journal, July 2013

${EuCo}_{2} P_{2}$ : A model molecular-field helical Heisenberg antiferromagnet
journal, July 2016

Itinerant and local-moment magnetism in ${EuCr}_{2}$ ${As}_{2}$ single crystals
journal, April 2014

Strong magnetic correlations to 900 K in single crystals of the trigonal antiferromagnetic insulators ${SrMn}_{2} {As}_{2}$ and ${CaMn}_{2} {As}_{2}$
journal, September 2016

Pressure-induced metallization of BaMn $_{2}$ As $_{2}$
journal, November 2011

Structure and magnetic properties of $L n MnSbO$ ( $L n = La$ and Ce)
journal, March 2016

Field-induced spin-flop transitions in single-crystalline CaCo $_{2}$ As $_{2}$
journal, April 2012

Structural and physical properties of SrMn2As2
journal, May 2011

Comparison of silver and molybdenum microfocus X-ray sources for single-crystal structure determination
journal, January 2015

Magnetic order in ${BaMn}_{2} {As}_{2}$ from neutron diffraction measurements
journal, September 2009

Magnetic Susceptibility of Collinear and Noncollinear Heisenberg Antiferromagnets
journal, August 2012

Antiferromagnetic structure and electronic properties of ${BaCr}_{2} {As}_{2}$ and ${BaCrFeAs}_{2}$
journal, May 2017

Combined Experimental and Density Functional Theory Studies on the Crystal Structures and Magnetic Properties of Mg(Mg _{1- x} Mn _x ) ₂ Sb ₂ ( x ≈ 0.25) and BaMn ₂ Sb ₂
journal, September 2008

Neutron diffraction studies of CaMn2Ge2 and BaMn2Ge2 compounds: first examples of antiferromagnetic Mn planes in ThCr2Si2-type structure compounds
journal, August 1994

The magnetic ground state of
journal, September 2009

Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

From antiferromagnetic insulator to ferromagnetic metal: Effects of hydrogen substitution in LaMnAsO
journal, January 2013

Iron-Based Layered Superconductor La[O _1- _x F _x ]FeAs ( x = 0.05−0.12) with T _c = 26 K
journal, March 2008

Coexistence of Half-Metallic Itinerant Ferromagnetism with Local-Moment Antiferromagnetism in ${Ba}_{0.60} K_{0.40} {Mn}_{2} {As}_{2}$
journal, July 2013

Magnetic and structural phase diagram of CaMn $_{2}$ Sb $_{2}$
journal, November 2012

Itinerant Ferromagnetism in the As $4 p$ Conduction Band of ${Ba}_{0.6} K_{0.4} {Mn}_{2} {As}_{2}$ Identified by X-Ray Magnetic Circular Dichroism
journal, May 2015

Thorium-doping–induced superconductivity up to 56 K in Gd _1−x Th _x FeAsO
journal, September 2008

Magnetic structure and spin excitations in ${BaMn}_{2} {Bi}_{2}$
journal, February 2014

Synthesis, crystal structure and superconductivity of LaNiPO
journal, February 2008

Short- and long-range magnetic order in LaMnAsO
journal, February 2016

${CaMn}_{2} {Sb}_{2}$ : Spin waves on a frustrated antiferromagnetic honeycomb lattice
journal, May 2015

Superconductivity in iron compounds
journal, December 2011

Pressure-induced collapsed-tetragonal phase in ${SrCo}_{2} {As}_{2}$
journal, December 2015

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

Anomalous magnetization in the layered itinerant ferromagnet LaCoAsO
journal, May 2009

Synthesis and thermoelectric properties of BaMn2Sb2 single crystals
journal, May 2009

Magnetic, transport, and thermal properties of single crystals of the layered arsenide ${BaMn}_{2} {As}_{2}$
journal, March 2009

Crystals, magnetic and electronic properties of a new ThCr2Si2-type BaMn2Bi2 and K-doped compositions
journal, August 2013

Weakly ferromagnetic metallic state in heavily doped Ba $_{1 - x}$ K $_{x}$ Mn $_{2}$ As $_{2}$
journal, April 2012

Structural, thermal, magnetic, and electronic transport properties of the LaNi $_{2}$ (Ge $_{1 - x}$ P $_{x}$ ) $_{2}$ system
journal, February 2012

A tetragonal polymorph of SrMn ₂ P ₂ made under high pressure – theory and experiment in harmony
journal, January 2017

Is ${BaCr}_{2} {As}_{2}$ symmetrical to ${BaFe}_{2} {As}_{2}$ with respect to half $3 d$ shell filling?
journal, May 2017

Pressure-induced transition to the collapsed tetragonal phase in $BaC r_{2} A s_{2}$
journal, April 2017

Growth of MnSb single crystals by pulling with a seed from nonstoichiometric molten solution
journal, January 1977

Unusual Mn−Mn Spin Coupling in the Polar Intermetallic Compounds CaMn ₂ Sb ₂ and SrMn ₂ Sb ₂
journal, May 2006

Magnetic and electronic properties of ${CaMn}_{2} {Bi}_{2}$ : A possible hybridization gap semiconductor
journal, February 2015

Crystal Magnetic Anisotropy and Magnetization of MnSb
journal, July 1968

Crystal structure refinement with SHELXL
journal, January 2015

Magnetic order in CaMn2Sb2 studied via powder neutron diffraction
journal, November 2009

Unified molecular field theory for collinear and noncollinear Heisenberg antiferromagnets
journal, February 2015

On the coordination of ThCr2Si2 (BaAl4-type compounds within the field of free parameters
journal, January 1996

${Ba}_{0.4} {Rb}_{0.6} {Mn}_{2} {As}_{2}$ : A prototype half-metallic ferromagnet
journal, November 2015

Superconductivity in ${SrNi}_{2} {As}_{2}$ single crystals
journal, November 2008

Crystal and magnetic structure of CaCo $_{1.86}$ As $_{2}$ studied by x-ray and neutron diffraction
journal, November 2013

From antiferromagnetic insulator to correlated metal in pressurized and doped LaMnPO
journal, May 2012

Itinerant G-type antiferromagnetic order in ${SrCr}_{2} {As}_{2}$
journal, July 2017

Persistence of local-moment antiferromagnetic order in Ba $_{1 - x}$ K $_{x}$ Mn $_{2}$ As $_{2}$
journal, April 2013

Gap states in insulating LaMnPO $_{1 - x}$ F $_{x}$ ( $x = 0$ –0.3)
journal, October 2011

Renormalized behavior and proximity of ${BaCo}_{2} {As}_{2}$ to a magnetic quantum critical point
journal, January 2009

Collinear antiferromagnetism in trigonal SrMn ₂ As ₂ revealed by single-crystal neutron diffraction
journal, November 2016

Magnetic Structure and Electromagnetic Properties of LnCrAsO with a ZrCuSiAs-type Structure (Ln = La, Ce, Pr, and Nd)
journal, November 2013

Antiferromagnetic bipolar semiconductor LaMnPO with ZrCuSiAs-type structure
journal, May 2009

Stripe Antiferromagnetic Spin Fluctuations in ${SrCo}_{2} {As}_{2}$
journal, October 2013

Resistivity and Magnetism of AMn2P2 (A = Sr, Ba): The Effect of Structure Type on Physical Properties
journal, December 1994

Physical properties of metallic antiferromagnetic ${CaCo}_{1.86}$ ${As}_{2}$ single crystals
journal, June 2014

Insulator-to-metal transition and large thermoelectric effect in La _1−x Sr _x MnAsO
journal, April 2012

A common thread: The pairing interaction for unconventional superconductors
journal, October 2012

Magnetic exchange interactions in ${BaMn}_{2} {As}_{2}$ : A case study of the $J_{1}$ - $J_{2}$ - $J_{c}$ Heisenberg model
journal, September 2011

The puzzle of high temperature superconductivity in layered iron pnictides and chalcogenides
journal, October 2010

Kramers non-magnetic superconductivity in Ln NiAsO superconductors
journal, September 2014

Zur Struktur ternärer Übergangsmetallarsenide/On the Structure of Ternary Arsenides
journal, June 1980

Bindungsverhältnisse und magnetische Eigenschaften ternärer Arsenide ET2As2 / Bonding and Magnetic Properties in Ternary Arsenides ET2As2
journal, July 1983

Darstellung und Kristallstruktur von BaMn2Sb2, BaZn2Sb2 und BaCd2Sb2 / Preparation and Crystal Structure of BaMn2Sb2 , BaZn2Sb2 and BaCd2Sb2
journal, July 1979

Neue intermetallische Verbindungen im anti-Ce2O2S-Strukturtyp. / New Intermetallic Compounds in the anti-Ce2O2S-Structure Type
journal, November 1976