Evolution of microstructure, strain and physical properties in oxide nanocomposite films
Abstract
Using LSMO:ZnO nanocomposite films as a model system, we have researched the effect of film thickness on the physical properties of nanocomposites. It shows that strain, microstructure, as well as magnetoresistance strongly rely on film thickness. The magnetotransport properties have been fitted by a modified parallel connection channel model, which is in agreement with the microstructure evolution as a function of film thickness in nanocomposite films on sapphire substrates. The strain analysis indicates that the variation of physical properties in nanocomposite films on LAO is dominated by strain effect. These results confirm the critical role of film thickness on microstructures, strain states, and functionalities. Furthermore, it shows that one can use film thickness as a key parameter to design nanocomposites with optimum functionalities.
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Center for Integrated Nanotechnologies (CINT)
- Texas A & M Univ., College Station, TX (United States). Department of Electrical and Computer Engineering
- Univ. of Cambridge (United Kingdom). Department of Materials Science and Metallurgy
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE National Nuclear Security Administration (NNSA)
- OSTI Identifier:
- 1321739
- Report Number(s):
- LA-UR-14-22033
Journal ID: ISSN 2045-2322
- Grant/Contract Number:
- AC52-06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Scientific Reports
- Additional Journal Information:
- Journal Volume: 4; Journal ID: ISSN 2045-2322
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY
Citation Formats
Chen, Aiping, Weigand, Marcus, Bi, Zhenxing, Zhang, Wenrui, Lü, Xuejie, Dowden, Paul, MacManus-Driscoll, Judith L., Wang, Haiyan, and Jia, Quanxi. Evolution of microstructure, strain and physical properties in oxide nanocomposite films. United States: N. p., 2014.
Web. doi:10.1038/srep05426.
Chen, Aiping, Weigand, Marcus, Bi, Zhenxing, Zhang, Wenrui, Lü, Xuejie, Dowden, Paul, MacManus-Driscoll, Judith L., Wang, Haiyan, & Jia, Quanxi. Evolution of microstructure, strain and physical properties in oxide nanocomposite films. United States. https://doi.org/10.1038/srep05426
Chen, Aiping, Weigand, Marcus, Bi, Zhenxing, Zhang, Wenrui, Lü, Xuejie, Dowden, Paul, MacManus-Driscoll, Judith L., Wang, Haiyan, and Jia, Quanxi. Tue .
"Evolution of microstructure, strain and physical properties in oxide nanocomposite films". United States. https://doi.org/10.1038/srep05426. https://www.osti.gov/servlets/purl/1321739.
@article{osti_1321739,
title = {Evolution of microstructure, strain and physical properties in oxide nanocomposite films},
author = {Chen, Aiping and Weigand, Marcus and Bi, Zhenxing and Zhang, Wenrui and Lü, Xuejie and Dowden, Paul and MacManus-Driscoll, Judith L. and Wang, Haiyan and Jia, Quanxi},
abstractNote = {Using LSMO:ZnO nanocomposite films as a model system, we have researched the effect of film thickness on the physical properties of nanocomposites. It shows that strain, microstructure, as well as magnetoresistance strongly rely on film thickness. The magnetotransport properties have been fitted by a modified parallel connection channel model, which is in agreement with the microstructure evolution as a function of film thickness in nanocomposite films on sapphire substrates. The strain analysis indicates that the variation of physical properties in nanocomposite films on LAO is dominated by strain effect. These results confirm the critical role of film thickness on microstructures, strain states, and functionalities. Furthermore, it shows that one can use film thickness as a key parameter to design nanocomposites with optimum functionalities.},
doi = {10.1038/srep05426},
journal = {Scientific Reports},
number = ,
volume = 4,
place = {United States},
year = {Tue Jun 24 00:00:00 EDT 2014},
month = {Tue Jun 24 00:00:00 EDT 2014}
}
Web of Science
Works referenced in this record:
Superconductivity in SrCuO2-BaCuO2 Superlattices: Formation of Artificially Layered Superconducting Materials
journal, September 1994
- Norton, D. P.; Chakoumakos, B. C.; Budai, J. D.
- Science, Vol. 265, Issue 5181
The single-phase multiferroic oxides: from bulk to thin film
journal, July 2005
- Prellier, W.; Singh, M. P.; Murugavel, P.
- Journal of Physics: Condensed Matter, Vol. 17, Issue 30
Advanced synthesis techniques and routes to new single-phase multiferroics
journal, October 2012
- Martin, Lane W.; Schlom, Darrell G.
- Current Opinion in Solid State and Materials Science, Vol. 16, Issue 5
A New Class of Room-Temperature Multiferroic Thin Films with Bismuth-Based Supercell Structure
journal, November 2012
- Chen, Aiping; Zhou, Honghui; Bi, Zhenxing
- Advanced Materials, Vol. 25, Issue 7
Thermal Conductivity of Manganite Perovskites: Colossal Magnetoresistance as a Lattice-Dynamics Transition
journal, May 1997
- Visser, D. W.; Ramirez, A. P.; Subramanian, M. A.
- Physical Review Letters, Vol. 78, Issue 20
Colossal Magnetoresistance Without Mn3+/Mn4+ Double Exchange in the Stoichiometric Pyrochlore Tl2Mn2O7
journal, July 1996
- Subramanian, M. A.; Toby, B. H.; Ramirez, A. P.
- Science, Vol. 273, Issue 5271
Reversible electrical switching of spin polarization in multiferroic tunnel junctions
journal, February 2012
- Pantel, D.; Goetze, S.; Hesse, D.
- Nature Materials, Vol. 11, Issue 4
Tunable multiferroic properties in nanocomposite PbTiO3–CoFe2O4 epitaxial thin films
journal, September 2005
- Murakami, M.; Chang, K. -S.; Aronova, M. A.
- Applied Physics Letters, Vol. 87, Issue 11
Design of Self-Assembled Multiferroic Nanostructures in Epitaxial Films
journal, August 2006
- Levin, I.; Li, J.; Slutsker, J.
- Advanced Materials, Vol. 18, Issue 15
Self-assembled perovskite-spinel heterostructure on a highly distorted substrate
journal, March 2013
- Zhu, Y. M.; Ke, D.; Yu, R.
- Applied Physics Letters, Vol. 102, Issue 11
Epitaxial Photostriction–Magnetostriction Coupled Self-Assembled Nanostructures
journal, July 2012
- Liu, Heng-Jui; Chen, Long-Yi; He, Qing
- ACS Nano, Vol. 6, Issue 8
Self-Assembly of Nanostructured, Complex, Multication Films via Spontaneous Phase Separation and Strain-Driven Ordering
journal, November 2012
- Wee, Sung Hun; Gao, Yanfei; Zuev, Yuri L.
- Advanced Functional Materials, Vol. 23, Issue 15
Large Magnetoresistance in Magnetically Coupled SrRuO 3 -CoFe 2 O 4 Self-Assembled Nanostructures
journal, July 2013
- Liu, Heng-Jui; Tra, Vu-Thanh; Chen, Ying-Jiun
- Advanced Materials, Vol. 25, Issue 34
Ferroelectric Properties of Vertically Aligned Nanostructured BaTiO 3 –CeO 2 Thin Films and Their Integration on Silicon
journal, November 2013
- Khatkhatay, Fauzia; Chen, Aiping; Lee, Joon Hwan
- ACS Applied Materials & Interfaces, Vol. 5, Issue 23
Exchange Bias Effect and Magnetic Properties in ${\hbox{La}}_{0.7}{\hbox{Sr}}_{0.3}{\hbox{MnO}}_{3}\hbox{-}{\hbox{NiO}}$ Nanocomposite Films
journal, January 2014
- Ning, Xingkun; Wang, Zhan Jie; Zhao, Xinguo
- IEEE Transactions on Magnetics, Vol. 50, Issue 1
Role of modulus mismatch in vertically aligned nanocomposite formation during spinodal decomposition in constrained films
journal, September 2013
- Liao, X. B.; Ni, Y.; Yang, H.
- Applied Physics Letters, Vol. 103, Issue 14
Extremely High Tunability and Low Loss in Nanoscaffold Ferroelectric Films
journal, July 2012
- Lee, OonJew; Harrington, Sophie A.; Kursumovic, Ahmed
- Nano Letters, Vol. 12, Issue 8
Deposition of epitaxial BiFeO 3 /CoFe 2 O 4 nanocomposites on (001) SrTiO 3 by combinatorial pulsed laser deposition
journal, February 2012
- Aimon, Nicolas M.; Hun Kim, Dong; Kyoon Choi, Hong
- Applied Physics Letters, Vol. 100, Issue 9
Strain control and spontaneous phase ordering in vertical nanocomposite heteroepitaxial thin films
journal, March 2008
- MacManus-Driscoll, Judith L.; Zerrer, Patrick; Wang, Haiyan
- Nature Materials, Vol. 7, Issue 4
Microstructure, vertical strain control and tunable functionalities in self-assembled, vertically aligned nanocomposite thin films
journal, May 2013
- Chen, Aiping; Bi, Zhenxing; Jia, Quanxi
- Acta Materialia, Vol. 61, Issue 8
Multiferroic BaTiO3-CoFe2O4 Nanostructures
journal, January 2004
- Zheng, H.
- Science, Vol. 303, Issue 5658
Magnetoelectric effects of nanoparticulate Pb(Zr0.52Ti0.48)O3–NiFe2O4 composite films
journal, September 2006
- Ryu, Hyejin; Murugavel, P.; Lee, J. H.
- Applied Physics Letters, Vol. 89, Issue 10
Epitaxial self-assembly of multiferroic nanostructures
journal, March 2009
- Tan, Zhuopeng; Slutsker, Julia; Roytburd, Alexander L.
- Journal of Applied Physics, Vol. 105, Issue 6
Quantitative determination of anisotropic magnetoelectric coupling in BiFeO3–CoFe2O4 nanostructures
journal, August 2010
- Oh, Yoon Seok; Crane, S.; Zheng, H.
- Applied Physics Letters, Vol. 97, Issue 5
Direct measurement of magnetoelectric exchange in self-assembled epitaxial BiFeO3–CoFe2O4 nanocomposite thin films
journal, May 2009
- Yan, Li; Xing, Zengping; Wang, Zhiguang
- Applied Physics Letters, Vol. 94, Issue 19
Local Conduction at the BiFeO3-CoFe2O4 Tubular Oxide Interface
journal, July 2012
- Hsieh, Ying-Hui; Liou, Jia-Ming; Huang, Bo-Chao
- Advanced Materials, Vol. 24, Issue 33, p. 4564-4568
Vertically aligned nanocomposite electrolytes with superior out-of-plane ionic conductivity for solid oxide fuel cells
journal, November 2013
- Su, Qing; Yoon, Daeil; Chen, Aiping
- Journal of Power Sources, Vol. 242
Selectable Spontaneous Polarization Direction and Magnetic Anisotropy in BiFeO 3 −CoFe 2 O 4 Epitaxial Nanostructures
journal, July 2010
- Dix, Nico; Muralidharan, Rajaram; Rebled, Jose-Manuel
- ACS Nano, Vol. 4, Issue 8
Stress-mediated magnetic anisotropy and magnetoelastic coupling in epitaxial multiferroic PbTiO 3 -CoFe 2 O 4 nanostructures
journal, April 2013
- Tsai, C. Y.; Chen, H. R.; Chang, F. C.
- Applied Physics Letters, Vol. 102, Issue 13
Strain relaxation and enhanced perpendicular magnetic anisotropy in BiFeO 3 :CoFe 2 O 4 vertically aligned nanocomposite thin films
journal, February 2014
- Zhang, Wenrui; Jian, Jie; Chen, Aiping
- Applied Physics Letters, Vol. 104, Issue 6
Electric-Field Control of Ferromagnetism in a Nanocomposite via a ZnO Phase
journal, November 2013
- Fix, Thomas; Choi, Eun-Mi; Robinson, Jason W. A.
- Nano Letters, Vol. 13, Issue 12
Electric in-plane polarization in multiferroic CoFe2O4/BaTiO3 nanocomposite tuned by magnetic fields
journal, June 2013
- Schmitz-Antoniak, Carolin; Schmitz, Detlef; Borisov, Pavel
- Nature Communications, Vol. 4, Issue 1
Grain size effect on the semiconductor-metal phase transition characteristics of magnetron-sputtered VO2 thin films
journal, August 2005
- Brassard, D.; Fourmaux, S.; Jean-Jacques, M.
- Applied Physics Letters, Vol. 87, Issue 5
Influence of thickness on microstructural and magnetic properties in Fe3O4 thin films produced by PLD
journal, January 2005
- Bollero, A.; Ziese, M.; Höhne, R.
- Journal of Magnetism and Magnetic Materials, Vol. 285, Issue 1-2
Effect of thickness on structural, electrical, and optical properties of ZnO: Al films deposited by pulsed laser deposition
journal, February 2007
- Dong, Bin-Zhong; Fang, Guo-Jia; Wang, Jian-Feng
- Journal of Applied Physics, Vol. 101, Issue 3
Effect of the variation of film thickness on the structural and optical properties of ZnO thin films deposited on sapphire substrate using PLD
journal, January 2002
- Shim, Eun Sub; Kang, Hong Seong; Kang, Jeong Seok
- Applied Surface Science, Vol. 186, Issue 1-4
Film thickness and temperature dependence of the magnetic properties of pulsed-laser-deposited films on different substrates
journal, November 2001
- Kale, Sangeeta; Bhagat, S. M.; Lofland, S. E.
- Physical Review B, Vol. 64, Issue 20
Magnetotransport properties of quasi-one-dimensionally channeled vertically aligned heteroepitaxial nanomazes
journal, March 2013
- Chen, Aiping; Zhang, Wenrui; Khatkhatay, Fauzia
- Applied Physics Letters, Vol. 102, Issue 9
Self-Assembled Growth of BiFeO3–CoFe2O4 Nanostructures
journal, October 2006
- Zheng, H.; Straub, F.; Zhan, Q.
- Advanced Materials, Vol. 18, Issue 20
Microstructural and magnetic properties of (La 0.7 Sr 0.3 MnO 3 ) 0.7 :(Mn 3 O 4 ) 0.3 nanocomposite thin films
journal, March 2011
- Bi, Zhenxing; Weal, Emily; Luo, Hongmei
- Journal of Applied Physics, Vol. 109, Issue 5
Microstructure, magnetic, and low-field magnetotransport properties of self-assembled (La 0.7 Sr 0.3 MnO 3 ) 0.5 :(CeO 2 ) 0.5 vertically aligned nanocomposite thin films
journal, July 2011
- Chen, Aiping; Bi, Zhenxing; Hazariwala, Harshad
- Nanotechnology, Vol. 22, Issue 31
Size and shape evolution of embedded single-crystal α-Fe nanowires
journal, November 2005
- Mohaddes-Ardabili, L.; Zheng, H.; Zhan, Q.
- Applied Physics Letters, Vol. 87, Issue 20
Integration of Self-Assembled Vertically Aligned Nanocomposite (La 0.7 Sr 0.3 MnO 3 ) 1– x :(ZnO) x Thin Films on Silicon Substrates
journal, May 2013
- Zhang, Wenrui; Chen, Aiping; Khatkhatay, Fauzia
- ACS Applied Materials & Interfaces, Vol. 5, Issue 10
Critical Limitations in the Fabrication of Biferroic BiFeO 3 −CoFe 2 O 4 Columnar Nanocomposites Due to Bismuth Loss
journal, April 2009
- Dix, N.; Muralidharan, R.; Warot-Fonrose, B.
- Chemistry of Materials, Vol. 21, Issue 7
Tunable Low-Field Magnetoresistance in (La0.7Sr0.3MnO3)0.5:(ZnO)0.5 Self-Assembled Vertically Aligned Nanocomposite Thin Films
journal, April 2011
- Chen, Aiping; Bi, Zhenxing; Tsai, Chen-Fong
- Advanced Functional Materials, Vol. 21, Issue 13
Conduction channels and magnetoresistance in polycrystalline manganites
journal, September 1999
- de Andrés, A.; García-Hernández, M.; Martínez, J. L.
- Physical Review B, Vol. 60, Issue 10
Low Temperature Magnetoresistance and the Magnetic Phase Diagram of
journal, October 1995
- Schiffer, P.; Ramirez, A. P.; Bao, W.
- Physical Review Letters, Vol. 75, Issue 18
Optimized fabrication of high-quality La 0.67 Sr 0.33 MnO 3 thin films considering all essential characteristics
journal, April 2011
- Boschker, H.; Huijben, M.; Vailionis, A.
- Journal of Physics D: Applied Physics, Vol. 44, Issue 20
Low-field magnetoresistance anisotropy in ultrathin Pr0.67Sr0.33MnO3 films grown on different substrates
journal, April 1999
- Wang, H. S.; Li, Qi; Liu, Kai
- Applied Physics Letters, Vol. 74, Issue 15
Local Conduction at the BiFeO3-CoFe2O4 Tubular Oxide Interface
journal, July 2012
- Hsieh, Ying-Hui; Liou, Jia-Ming; Huang, Bo-Chao
- Advanced Materials, Vol. 24, Issue 33, p. 4564-4568
A New Class of Room-Temperature Multiferroic Thin Films with Bismuth-Based Supercell Structure
journal, November 2012
- Chen, Aiping; Zhou, Honghui; Bi, Zhenxing
- Advanced Materials, Vol. 25, Issue 7
Advanced synthesis techniques and routes to new single-phase multiferroics
journal, October 2012
- Martin, Lane W.; Schlom, Darrell G.
- Current Opinion in Solid State and Materials Science, Vol. 16, Issue 5
Influence of thickness on microstructural and magnetic properties in Fe3O4 thin films produced by PLD
journal, January 2005
- Bollero, A.; Ziese, M.; Höhne, R.
- Journal of Magnetism and Magnetic Materials, Vol. 285, Issue 1-2
Ferroelectric Properties of Vertically Aligned Nanostructured BaTiO 3 –CeO 2 Thin Films and Their Integration on Silicon
journal, November 2013
- Khatkhatay, Fauzia; Chen, Aiping; Lee, Joon Hwan
- ACS Applied Materials & Interfaces, Vol. 5, Issue 23
Extremely High Tunability and Low Loss in Nanoscaffold Ferroelectric Films
journal, July 2012
- Lee, OonJew; Harrington, Sophie A.; Kursumovic, Ahmed
- Nano Letters, Vol. 12, Issue 8
Electric-Field Control of Ferromagnetism in a Nanocomposite via a ZnO Phase
journal, November 2013
- Fix, Thomas; Choi, Eun-Mi; Robinson, Jason W. A.
- Nano Letters, Vol. 13, Issue 12
Selectable Spontaneous Polarization Direction and Magnetic Anisotropy in BiFeO 3 −CoFe 2 O 4 Epitaxial Nanostructures
journal, July 2010
- Dix, Nico; Muralidharan, Rajaram; Rebled, Jose-Manuel
- ACS Nano, Vol. 4, Issue 8
Epitaxial Photostriction–Magnetostriction Coupled Self-Assembled Nanostructures
journal, July 2012
- Liu, Heng-Jui; Chen, Long-Yi; He, Qing
- ACS Nano, Vol. 6, Issue 8
Strain control and spontaneous phase ordering in vertical nanocomposite heteroepitaxial thin films
journal, March 2008
- MacManus-Driscoll, Judith L.; Zerrer, Patrick; Wang, Haiyan
- Nature Materials, Vol. 7, Issue 4
Reversible electrical switching of spin polarization in multiferroic tunnel junctions
journal, February 2012
- Pantel, D.; Goetze, S.; Hesse, D.
- Nature Materials, Vol. 11, Issue 4
Epitaxial self-assembly of multiferroic nanostructures
journal, March 2009
- Tan, Zhuopeng; Slutsker, Julia; Roytburd, Alexander L.
- Journal of Applied Physics, Vol. 105, Issue 6
Microstructure, magnetic, and low-field magnetotransport properties of self-assembled (La 0.7 Sr 0.3 MnO 3 ) 0.5 :(CeO 2 ) 0.5 vertically aligned nanocomposite thin films
journal, July 2011
- Chen, Aiping; Bi, Zhenxing; Hazariwala, Harshad
- Nanotechnology, Vol. 22, Issue 31
Multiferroic BaTiO3-CoFe2O4 Nanostructures
journal, January 2004
- Zheng, H.
- Science, Vol. 303, Issue 5658
Superconductivity in SrCuO2-BaCuO2 Superlattices: Formation of Artificially Layered Superconducting Materials
journal, September 1994
- Norton, D. P.; Chakoumakos, B. C.; Budai, J. D.
- Science, Vol. 265, Issue 5181
Works referencing / citing this record:
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journal, May 2019
- Tian, Guo; Ojha, Shuchi; Ning, Shuai
- Advanced Electronic Materials, Vol. 5, Issue 7
Magnetic, electronic, and optical properties of double perovskite Bi 2 FeMnO 6
journal, March 2017
- Ahmed, Towfiq; Chen, Aiping; Yarotski, Dmitry A.
- APL Materials, Vol. 5, Issue 3
The role of oxide interfaces in highly confined electronic and ionic conductors
journal, January 2019
- Christensen, Dennis V.; Chen, Yunzhong; Esposito, Vincenzo
- APL Materials, Vol. 7, Issue 1
Strain and property tuning of the 3D framed epitaxial nanocomposite thin films via interlayer thickness variation
journal, February 2019
- Sun, X.; Li, Q.; Huang, J.
- Journal of Applied Physics, Vol. 125, Issue 8
Role of scaffold network in controlling strain and functionalities of nanocomposite films
journal, June 2016
- Chen, Aiping; Hu, Jia-Mian; Lu, Ping
- Science Advances, Vol. 2, Issue 6