Combustion Properties of Amino-Substituted Guanidinium 4,4',5,5'-Tetranitro-2,2'-biimidazolate(N4BIM) Salts

Tappan, Bryce C.; Chavez, David E.

doi:10.1002/prep.201400247

Title: Combustion Properties of Amino-Substituted Guanidinium 4,4',5,5'-Tetranitro-2,2'-biimidazolate(N4BIM) Salts

Abstract

Abstract This paper describes the combustion properties of the amino‐substituted guanidinium 4,4′,5,5′‐tetranitro‐2,2′‐biimidazolate (N4BIM) series, including the bis‐mono, di and triaminoguanidinium salts. These salts are of interest as propellant ingredient additives, and in particular, the bis‐triaminoguanidinium salt of N4BIM displays excellent burn rate and combustion behavior. Our combustion studies have shown that TAGN4‐BIM displays a fast burning rate and has the lowest pressure dependence exponent yet measured for a triaminoguanidinium salt.

Authors:

Tappan, Bryce C. ^[1]; Chavez, David E. ^[1]

Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

Publication Date:: Tue Dec 02 00:00:00 EST 2014

Research Org.:: Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1239252

Alternate Identifier(s):: OSTI ID: 1401115

Report Number(s):: LA-UR-14-27925
Journal ID: ISSN 1521-4087

Grant/Contract Number:: AC52-06NA25396; LA-UR-14-27925

Resource Type:: Accepted Manuscript

Journal Name:: Propellants, Explosives, Pyrotechnics (Online)

Additional Journal Information:: Journal Name: Propellants, Explosives, Pyrotechnics (Online); Journal Volume: 40; Journal Issue: 1; Journal ID: ISSN 1521-4087

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 33 ADVANCED PROPULSION SYSTEMS

Citation Formats


                    Tappan, Bryce C., and Chavez, David E. Combustion Properties of Amino-Substituted Guanidinium 4,4',5,5'-Tetranitro-2,2'-biimidazolate(N4BIM) Salts.  United States: N. p., 2014. 
Web.  doi:10.1002/prep.201400247.

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                    Tappan, Bryce C., & Chavez, David E. Combustion Properties of Amino-Substituted Guanidinium 4,4',5,5'-Tetranitro-2,2'-biimidazolate(N4BIM) Salts.  United States.  https://doi.org/10.1002/prep.201400247

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                    Tappan, Bryce C., and Chavez, David E. Tue .  
"Combustion Properties of Amino-Substituted Guanidinium 4,4',5,5'-Tetranitro-2,2'-biimidazolate(N4BIM) Salts".  United States.  https://doi.org/10.1002/prep.201400247.  https://www.osti.gov/servlets/purl/1239252.

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@article{osti_1239252,

  title        = {Combustion Properties of Amino-Substituted Guanidinium 4,4',5,5'-Tetranitro-2,2'-biimidazolate(N4BIM) Salts},

  author       = {Tappan, Bryce C. and Chavez, David E.},

  abstractNote = {Abstract This paper describes the combustion properties of the amino‐substituted guanidinium 4,4′,5,5′‐tetranitro‐2,2′‐biimidazolate (N4BIM) series, including the bis‐mono, di and triaminoguanidinium salts. These salts are of interest as propellant ingredient additives, and in particular, the bis‐triaminoguanidinium salt of N4BIM displays excellent burn rate and combustion behavior. Our combustion studies have shown that TAGN4‐BIM displays a fast burning rate and has the lowest pressure dependence exponent yet measured for a triaminoguanidinium salt.},

  doi          = {10.1002/prep.201400247},

  journal      = {Propellants, Explosives, Pyrotechnics (Online)},

  number       = 1,

  volume       = 40,

  place        = {United States},

  year         = {Tue Dec 02 00:00:00 EST 2014},

  month        = {Tue Dec 02 00:00:00 EST 2014}

}

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https://doi.org/10.1002/prep.201400247

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Works referenced in this record:

Synthesis and Combustion Characteristics of Novel High-Nitrogen Materials
journal, January 2013

Chavez, David E.; Tappan, Bryce C.
International Journal of Energetic Materials and Chemical Propulsion, Vol. 12, Issue 2
DOI: 10.1615/IntJEnergeticMaterialsChemProp.2013001360

Future Articles: Prop., Explos., Pyrotech. 4/2009
journal, August 2009

Simpson, Randall L.; Eckl, Wilhelm; Gee, Richard
Propellants, Explosives, Pyrotechnics, Vol. 34, Issue 4, p. 366-366
DOI: 10.1002/prep.200990010

Contents: Prop., Explos., Pyrotech. 6/2012
journal, December 2012

Simpson, Randall L.; Eckl, Wilhelm; Gee, Richard
Propellants, Explosives, Pyrotechnics, Vol. 37, Issue 6, p. 631-632
DOI: 10.1002/prep.201290024

Synthesis and Energetic Properties of 4,4′,5,5′-Tetranitro-2,2′-biimidazolate(N4BIM) Salts
journal, August 2012

Chavez, David E.; Parrish, Damon; Preston, Daniel N.
Propellants, Explosives, Pyrotechnics, Vol. 37, Issue 6
DOI: 10.1002/prep.201200040

High Nitrogen Energetic Salts of 4,4',5,5'-Tetranitro-2,2'-Biimidazole
journal, August 2013

Kim, Seung Hee; Kim, Jin Seuk
Bulletin of the Korean Chemical Society, Vol. 34, Issue 8
DOI: 10.5012/bkcs.2013.34.8.2503

Nucleophilic Reactions of The Bis Ammonium Salt of 4,4′,5,5′-Tetranitro-2,2′-biimidazole
journal, January 2013

Breiner, Megan; Chavez, David; Parrish, Damon
Synlett, Vol. 24, Issue 04
DOI: 10.1055/s-0032-1318142

Energetic Derivatives of 4, 4′,5, 5′-Tetranitro-2, 2′-bisimidazole (TNBI)
journal, July 2012

Klapötke, Thomas M.; Preimesser, Andreas; Stierstorfer, Jörg
Zeitschrift für anorganische und allgemeine Chemie, Vol. 638, Issue 9
DOI: 10.1002/zaac.201200188

New High-Nitrogen Materials Based on Nitroguanyl-Tetrazines: Explosive Properties, Thermal Decomposition and Combustion Studies
journal, December 2005

Chavez, David E.; Tappan, Bryce C.; Hiskey, Michael A.
Propellants, Explosives, Pyrotechnics, Vol. 30, Issue 6
DOI: 10.1002/prep.200500033

Synthesis and Energetic Properties of Bis-(Triaminoguanidinium) 3,3′-Dinitro-5,5′-Azo-1,2,4-Triazolate (TAGDNAT): A New High-Nitrogen Material
journal, November 2009

Chavez, David E.; Tappan, Bryce C.; Mason, Benjamin Aaron
Propellants, Explosives, Pyrotechnics, Vol. 34, Issue 6
DOI: 10.1002/prep.200800081

Works referencing / citing this record:

Synthesis and Properties of 4,4',5,5'-Tetranitro-1H,1'H-2,2'-Biimidazole Salts: Semicarbazidium, 3-Amino-1,2,4-Triazolium, and 5-Aminotetrazolium Derivatives
journal, June 2017

Lewczuk, Rafał; Szala, Mateusz; Rećko, Judyta
Chemistry of Heterocyclic Compounds, Vol. 53, Issue 6-7
DOI: 10.1007/s10593-017-2111-z

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Title: Combustion Properties of Amino-Substituted Guanidinium 4,4',5,5'-Tetranitro-2,2'-biimidazolate(N4BIM) Salts

Abstract

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