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Title: Solvent annealing of perovskite-induced crystal growth for photovoltaic-device efficiency enhancement

Abstract

Solvent-annealing is found to be an effective method to increase the grain size and carrier diffusion lengths of trihalide perovskite materials. Thus, the carrier diffusion length of MAPbI3 is increased to over 1 μm. The efficiency remains above 14.5% when the MAPbI3 thickness changes from 250 nm to 1 μm, with the highest efficiency reaching 15.6%.

Authors:
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Univ. of Nebraska, Lincoln, NE (United States)
Publication Date:
Research Org.:
Univ. of Nebraska, Lincoln, NE (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1237997
Grant/Contract Number:  
EE0006709
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Materials
Additional Journal Information:
Journal Volume: 26; Journal Issue: 37; Journal ID: ISSN 0935-9648
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Xiao, Zhengguo, Dong, Qingfeng, Bi, Cheng, Shao, Yuchuan, Yuan, Yongbo, and Huang, Jinsong. Solvent annealing of perovskite-induced crystal growth for photovoltaic-device efficiency enhancement. United States: N. p., 2014. Web. doi:10.1002/adma.201401685.
Xiao, Zhengguo, Dong, Qingfeng, Bi, Cheng, Shao, Yuchuan, Yuan, Yongbo, & Huang, Jinsong. Solvent annealing of perovskite-induced crystal growth for photovoltaic-device efficiency enhancement. United States. https://doi.org/10.1002/adma.201401685
Xiao, Zhengguo, Dong, Qingfeng, Bi, Cheng, Shao, Yuchuan, Yuan, Yongbo, and Huang, Jinsong. Tue . "Solvent annealing of perovskite-induced crystal growth for photovoltaic-device efficiency enhancement". United States. https://doi.org/10.1002/adma.201401685. https://www.osti.gov/servlets/purl/1237997.
@article{osti_1237997,
title = {Solvent annealing of perovskite-induced crystal growth for photovoltaic-device efficiency enhancement},
author = {Xiao, Zhengguo and Dong, Qingfeng and Bi, Cheng and Shao, Yuchuan and Yuan, Yongbo and Huang, Jinsong},
abstractNote = {Solvent-annealing is found to be an effective method to increase the grain size and carrier diffusion lengths of trihalide perovskite materials. Thus, the carrier diffusion length of MAPbI3 is increased to over 1 μm. The efficiency remains above 14.5% when the MAPbI3 thickness changes from 250 nm to 1 μm, with the highest efficiency reaching 15.6%.},
doi = {10.1002/adma.201401685},
journal = {Advanced Materials},
number = 37,
volume = 26,
place = {United States},
year = {Tue Aug 26 00:00:00 EDT 2014},
month = {Tue Aug 26 00:00:00 EDT 2014}
}

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Aerosol-Jet-Assisted Thin-Film Growth of CH 3 NH 3 PbI 3 Perovskites-A Means to Achieve High Quality, Defect-Free Films for Efficient Solar Cells
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Role of Ionic Functional Groups on Ion Transport at Perovskite Interfaces
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Vertically Oriented 2D Layered Perovskite Solar Cells with Enhanced Efficiency and Good Stability
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A solvent- and vacuum-free route to large-area perovskite films for efficient solar modules
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Morphological control of organic–inorganic perovskite layers by hot isostatic pressing for efficient planar solar cells
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Enhancing the grain size of organic halide perovskites by sulfonate-carbon nanotube incorporation in high performance perovskite solar cells
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Enhanced photovoltaic performance and stability of carbon counter electrode based perovskite solar cells encapsulated by PDMS
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Improving the efficiency and stability of inverted perovskite solar cells with dopamine-copolymerized PEDOT:PSS as a hole extraction layer
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Covering effect of conductive glass: a facile route to tailor the grain growth of hybrid perovskites for highly efficient solar cells
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Efficiency improvement of planar perovskite solar cells using a phenol additive
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Third generation photovoltaic cells based on photonic crystals
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Performance enhancement of perovskite solar cells via material quality improvement assisted by MAI/IPA solution post-treatment
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A thiourea additive-based quadruple cation lead halide perovskite with an ultra-large grain size for efficient perovskite solar cells
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In-plane stimulated emission of polycrystalline CH 3 NH 3 PbBr 3 perovskite thin films
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Modifying perovskite solar cells with l (+)-cysteine at the interface between mesoporous TiO 2 and perovskite
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Ion induced passivation of grain boundaries in perovskite solar cells
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The roles of acetylacetone additives in enhancing perovskite solar cell performance
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Overcoming the electroluminescence efficiency limitations of perovskite light-emitting diodes
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MAPbI3 Incorporated with Carboxyl Group Chelated Titania for Planar Perovskite Solar Cells in Low-Temperature Process
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Unraveling the Reasons for Efficiency Loss in Perovskite Solar Cells
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Unveiling a Key Intermediate in Solvent Vapor Postannealing to Enlarge Crystalline Domains of Organometal Halide Perovskite Films
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High-Quality Mixed-Organic-Cation Perovskites from a Phase-Pure Non-stoichiometric Intermediate (FAI) 1− x -PbI 2 for Solar Cells
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“Liquid Knife” to Fabricate Patterning Single-Crystalline Perovskite Microplates toward High-Performance Laser Arrays
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Highly Efficient and Stable Inverted Perovskite Solar Cell Obtained via Treatment by Semiconducting Chemical Additive
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Application of Perovskite‐Structured Materials in Field‐Effect Transistors
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Formation of Thin Films of Organic-Inorganic Perovskites for High-Efficiency Solar Cells
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Low Temperature Solution-Processed Sb:SnO 2 Nanocrystals for Efficient Planar Perovskite Solar Cells
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High Electrical Conductivity 2D MXene Serves as Additive of Perovskite for Efficient Solar Cells
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A Universal Strategy to Utilize Polymeric Semiconductors for Perovskite Solar Cells with Enhanced Efficiency and Longevity
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Precisely Controlling the Grain Sizes with an Ammonium Hypophosphite Additive for High-Performance Perovskite Solar Cells
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Materials toward the Upscaling of Perovskite Solar Cells: Progress, Challenges, and Strategies
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Control of Crystal Growth toward Scalable Fabrication of Perovskite Solar Cells
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Engineering Perovskite Nanocrystal Surface Termination for Light-Emitting Diodes with External Quantum Efficiency Exceeding 15%
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27%‐Efficiency Four‐Terminal Perovskite/Silicon Tandem Solar Cells by Sandwiched Gold Nanomesh
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Efficient CH 3 NH 3 PbI 3 Perovskite Solar Cells Employing Nanostructured p-Type NiO Electrode Formed by a Pulsed Laser Deposition
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Single-Layer Light-Emitting Diodes Using Organometal Halide Perovskite/Poly(ethylene oxide) Composite Thin Films
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Oriented Grains with Preferred Low-Angle Grain Boundaries in Halide Perovskite Films by Pressure-Induced Crystallization
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High-Performance Thickness Insensitive Perovskite Solar Cells with Enhanced Moisture Stability
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Morphology Controlling of All-Inorganic Perovskite at Low Temperature for Efficient Rigid and Flexible Solar Cells
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Reverse‐Graded 2D Ruddlesden–Popper Perovskites for Efficient Air‐Stable Solar Cells
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Solution‐Processed Ternary Oxides as Carrier Transport/Injection Layers in Optoelectronics
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Probing the Microstructure of Methylammonium Lead Iodide Perovskite Solar Cells
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Interfacial Post‐Treatment for Enhancing the Performance of Printable Carbon‐Based Perovskite Solar Cells
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The synergistic effect of cooperating solvent vapor annealing for high-efficiency planar inverted perovskite solar cells
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Elucidating the mechanisms underlying PCBM enhancement of CH 3 NH 3 PbI 3 perovskite solar cells using GIXRD and XAFS
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Efficient and carbon-based hole transport layer-free CsPbI 2 Br planar perovskite solar cells using PMMA modification
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Pb‐Site Doping of Lead Halide Perovskites for Efficient Solar Cells
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Lead‐Free Solar Cells based on Tin Halide Perovskite Films with High Coverage and Improved Aggregation
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Efficient Charge Collection Promoted by Interface Passivation Using Amino Acid Toward High Performance Perovskite Solar Cells
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Cesium-Doped Vanadium Oxide as the Hole Extraction Layer for Efficient Perovskite Solar Cells
journal, January 2018


Solution-Processed BiI3 Films with 1.1 eV Quasi-Fermi Level Splitting: The Role of Water, Temperature, and Solvent during Processing
journal, October 2018

  • Williamson, B. Wesley; Eickemeyer, Felix T.; Hillhouse, Hugh W.
  • ACS Omega, Vol. 3, Issue 10
  • DOI: 10.1021/acsomega.8b00813

Facile fabrication of large-grain CH3NH3PbI3−xBrx films for high-efficiency solar cells via CH3NH3Br-selective Ostwald ripening
journal, August 2016

  • Yang, Mengjin; Zhang, Taiyang; Schulz, Philip
  • Nature Communications, Vol. 7, Issue 1
  • DOI: 10.1038/ncomms12305

The dynamics of methylammonium ions in hybrid organic–inorganic perovskite solar cells
journal, May 2015

  • Leguy, Aurelien M. A.; Frost, Jarvist Moore; McMahon, Andrew P.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8124

The optoelectronic role of chlorine in CH3NH3PbI3(Cl)-based perovskite solar cells
journal, June 2015

  • Chen, Qi; Zhou, Huanping; Fang, Yihao
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8269

Non-wetting surface-driven high-aspect-ratio crystalline grain growth for efficient hybrid perovskite solar cells
journal, July 2015

  • Bi, Cheng; Wang, Qi; Shao, Yuchuan
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms8747

Hybrid perovskite solar cells fabricated from guanidine hydroiodide and tin iodide
journal, July 2017


Single Source Thermal Evaporation of Two-dimensional Perovskite Thin Films for Photovoltaic Applications
journal, November 2019


Elucidating the Reaction Pathways in the Synthesis of Organolead Trihalide Perovskite for High-Performance Solar Cells
journal, May 2015

  • Wang, Baohua; Young Wong, King; Xiao, Xudong
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep10557

Direct Conversion of CH3NH3PbI3 from Electrodeposited PbO for Highly Efficient Planar Perovskite Solar Cells
journal, October 2015

  • Huang, Jin-hua; Jiang, Ke-jian; Cui, Xue-ping
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep15889

Self-regulation of charged defect compensation and formation energy pinning in semiconductors
journal, November 2015

  • Yang, Ji-Hui; Yin, Wan-Jian; Park, Ji-Sang
  • Scientific Reports, Vol. 5, Issue 1
  • DOI: 10.1038/srep16977

Differentially pumped spray deposition as a rapid screening tool for organic and perovskite solar cells
journal, February 2016

  • Jung, Yen-Sook; Hwang, Kyeongil; Scholes, Fiona H.
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep20357

Ti/Au Cathode for Electronic transport material-free organic-inorganic hybrid perovskite solar cells
journal, December 2016

  • Shi, Tongfei; Chen, Jian; Zheng, Jianqiang
  • Scientific Reports, Vol. 6, Issue 1
  • DOI: 10.1038/srep39132

Annealing Induced Re-crystallization in CH3NH3PbI3−xClx for High Performance Perovskite Solar Cells
journal, April 2017

  • Yang, Yingguo; Feng, Shanglei; Li, Meng
  • Scientific Reports, Vol. 7, Issue 1
  • DOI: 10.1038/srep46724

The effect of oxygen on the efficiency of planar p–i–n metal halide perovskite solar cells with a PEDOT:PSS hole transport layer
journal, January 2018

  • Bruijnaers, Bardo J.; Schiepers, Eric; Weijtens, Christ H. L.
  • Journal of Materials Chemistry A, Vol. 6, Issue 16
  • DOI: 10.1039/c7ta11128b

Charge separation and carrier dynamics in donor-acceptor heterojunction photovoltaic systems
journal, November 2017

  • Teuscher, Joël; Brauer, Jan C.; Stepanov, Andrey
  • Structural Dynamics, Vol. 4, Issue 6
  • DOI: 10.1063/1.4996409

Enhancing the efficiency of planar heterojunction perovskite solar cells via interfacial engineering with 3-aminopropyl trimethoxy silane hydrolysate
journal, December 2017

  • Wang, Ya-Qiong; Xu, Shou-Bin; Deng, Jian-Guo
  • Royal Society Open Science, Vol. 4, Issue 12
  • DOI: 10.1098/rsos.170980

Efficiency Enhancement of Perovskite Solar Cells by Pumping Away the Solvent of Precursor Film Before Annealing
journal, May 2016


The expanding world of hybrid perovskites: materials properties and emerging applications
journal, March 2015

  • Brittman, Sarah; Adhyaksa, Gede Widia Pratama; Garnett, Erik Christian
  • MRS Communications, Vol. 5, Issue 1
  • DOI: 10.1557/mrc.2015.6

Improved Performance of Perovskite Light-Emitting Diodes by Quantum Confinement Effect in Perovskite Nanocrystals
journal, June 2018

  • Chen, Lung-Chien; Tseng, Zong-Liang; Lin, Dai-Wei
  • Nanomaterials, Vol. 8, Issue 7
  • DOI: 10.3390/nano8070459

MAPbI3 Incorporated with Carboxyl Group Chelated Titania for Planar Perovskite Solar Cells in Low-Temperature Process
journal, June 2019

  • Li, Pei-Shan; Balamurugan, Rathinam; Liu, Bo-Tau
  • Nanomaterials, Vol. 9, Issue 6
  • DOI: 10.3390/nano9060908

Low Temperature Combustion Synthesis of a Spinel NiCo2O4 Hole Transport Layer for Perovskite Photovoltaics
text, January 2018