The corrosivity and passivity of sputtered Mg-Ti alloys
Abstract
Our study explored the possibility of forming a “stainless” Mg–Ti alloy. The electrochemical behavior of magnetron-sputtered Mg–Ti alloys was measured in a NaCl solution, and the surface films on the alloys were examined by XPS, SEM and TEM. Increased corrosion resistance was observed with increased Ti content in the sputtered Mg–Ti alloys, but passive-like behavior was not reached until the Ti level (atomic %) was higher than the Mg level. Moreover, the surface film that formed on sputtered Mg–Ti based alloys in NaCl solution was thick, discontinuous and non-protective, whereas a thin, continuous and protective Mg and Ti oxide film was formed on a sputtered Ti–Mg based alloy.
- Authors:
-
- Xiamen Univ., Xiamen (China)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Montana State Univ., Bozeman, MT (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO)
- OSTI Identifier:
- 1237147
- Alternate Identifier(s):
- OSTI ID: 1254777
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Corrosion Science
- Additional Journal Information:
- Journal Volume: 104; Journal Issue: 3; Journal ID: ISSN 0010-938X
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; A. Mg alloy; B. SEM; B. TEM; B. XPS; C. Passivity
Citation Formats
Song, Guang -Ling, Unocic, Kinga A., Meyer, III, Harry M., Cakmak, Ercan, Brady, Michael P., Gannon, Paul E., Himmer, Phil, and Andrews, Quinn. The corrosivity and passivity of sputtered Mg-Ti alloys. United States: N. p., 2015.
Web. doi:10.1016/j.corsci.2015.11.028.
Song, Guang -Ling, Unocic, Kinga A., Meyer, III, Harry M., Cakmak, Ercan, Brady, Michael P., Gannon, Paul E., Himmer, Phil, & Andrews, Quinn. The corrosivity and passivity of sputtered Mg-Ti alloys. United States. https://doi.org/10.1016/j.corsci.2015.11.028
Song, Guang -Ling, Unocic, Kinga A., Meyer, III, Harry M., Cakmak, Ercan, Brady, Michael P., Gannon, Paul E., Himmer, Phil, and Andrews, Quinn. Mon .
"The corrosivity and passivity of sputtered Mg-Ti alloys". United States. https://doi.org/10.1016/j.corsci.2015.11.028. https://www.osti.gov/servlets/purl/1237147.
@article{osti_1237147,
title = {The corrosivity and passivity of sputtered Mg-Ti alloys},
author = {Song, Guang -Ling and Unocic, Kinga A. and Meyer, III, Harry M. and Cakmak, Ercan and Brady, Michael P. and Gannon, Paul E. and Himmer, Phil and Andrews, Quinn},
abstractNote = {Our study explored the possibility of forming a “stainless” Mg–Ti alloy. The electrochemical behavior of magnetron-sputtered Mg–Ti alloys was measured in a NaCl solution, and the surface films on the alloys were examined by XPS, SEM and TEM. Increased corrosion resistance was observed with increased Ti content in the sputtered Mg–Ti alloys, but passive-like behavior was not reached until the Ti level (atomic %) was higher than the Mg level. Moreover, the surface film that formed on sputtered Mg–Ti based alloys in NaCl solution was thick, discontinuous and non-protective, whereas a thin, continuous and protective Mg and Ti oxide film was formed on a sputtered Ti–Mg based alloy.},
doi = {10.1016/j.corsci.2015.11.028},
journal = {Corrosion Science},
number = 3,
volume = 104,
place = {United States},
year = {Mon Nov 30 00:00:00 EST 2015},
month = {Mon Nov 30 00:00:00 EST 2015}
}
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Works referencing / citing this record:
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