Comparing highly ordered monolayers of nanoparticles fabricated using electrophoretic deposition: Cobalt ferrite nanoparticles versus iron oxide nanoparticles
Abstract
Ordered assemblies of nanoparticles remain challenging to fabricate, yet could open the door to many potential applications of nanomaterials. Here, we demonstrate that locally ordered arrays of nanoparticles, using electrophoretic deposition, can be extended to produce long-range order among the constituents. Voronoi tessellations along with multiple statistical analyses show dramatic increases in order compared with previously reported assemblies formed through electric field-assisted assembly. As a result, based on subsequent physical measurements of the nanoparticles and the deposition system, the underlying mechanisms that generate increased order are inferred.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States); Brown Univ., Providence, RI (United States)
- SUNY Korea, Incheon (South Korea); Stony Brook Univ., Stony Brook, NY (United States)
- Brown Univ., Providence, RI (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1235850
- Report Number(s):
- BNL-108608-2015-JA
Journal ID: ISSN 0013-4651; KC0403020
- Grant/Contract Number:
- SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 162; Journal Issue: 11; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 77 NANOSCIENCE AND NANOTECHNOLOGY; electrophoretic deposition; iron oxide; cobalt ferrite; nanoparticles; Center for Functional Nanomaterials; directed assembly; Voronoi tessellation
Citation Formats
Dickerson, James H., Krejci, Alex J., Garcia, Adriana -Mendoza, Sun, Shouheng, and Pham, Viet Hung. Comparing highly ordered monolayers of nanoparticles fabricated using electrophoretic deposition: Cobalt ferrite nanoparticles versus iron oxide nanoparticles. United States: N. p., 2015.
Web. doi:10.1149/2.0171511jes.
Dickerson, James H., Krejci, Alex J., Garcia, Adriana -Mendoza, Sun, Shouheng, & Pham, Viet Hung. Comparing highly ordered monolayers of nanoparticles fabricated using electrophoretic deposition: Cobalt ferrite nanoparticles versus iron oxide nanoparticles. United States. https://doi.org/10.1149/2.0171511jes
Dickerson, James H., Krejci, Alex J., Garcia, Adriana -Mendoza, Sun, Shouheng, and Pham, Viet Hung. Sat .
"Comparing highly ordered monolayers of nanoparticles fabricated using electrophoretic deposition: Cobalt ferrite nanoparticles versus iron oxide nanoparticles". United States. https://doi.org/10.1149/2.0171511jes. https://www.osti.gov/servlets/purl/1235850.
@article{osti_1235850,
title = {Comparing highly ordered monolayers of nanoparticles fabricated using electrophoretic deposition: Cobalt ferrite nanoparticles versus iron oxide nanoparticles},
author = {Dickerson, James H. and Krejci, Alex J. and Garcia, Adriana -Mendoza and Sun, Shouheng and Pham, Viet Hung},
abstractNote = {Ordered assemblies of nanoparticles remain challenging to fabricate, yet could open the door to many potential applications of nanomaterials. Here, we demonstrate that locally ordered arrays of nanoparticles, using electrophoretic deposition, can be extended to produce long-range order among the constituents. Voronoi tessellations along with multiple statistical analyses show dramatic increases in order compared with previously reported assemblies formed through electric field-assisted assembly. As a result, based on subsequent physical measurements of the nanoparticles and the deposition system, the underlying mechanisms that generate increased order are inferred.},
doi = {10.1149/2.0171511jes},
journal = {Journal of the Electrochemical Society},
number = 11,
volume = 162,
place = {United States},
year = {Sat Aug 01 00:00:00 EDT 2015},
month = {Sat Aug 01 00:00:00 EDT 2015}
}
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