Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid
Abstract
Triflic acid (HOTf)-bound nonheme Mn(IV)-oxo complexes, [(L)MnIV(O)]2+–(HOTf)2 (L = N4Py and Bn-TPEN; N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine and Bn-TPEN = N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine), were synthesized by adding HOTf to the solutions of the [(L)MnIV(O)]2+ complexes and were characterized by various spectroscopies. The one-electron reduction potentials of the MnIV(O) complexes exhibited a significant positive shift upon binding of HOTf. The driving force dependences of electron transfer (ET) from electron donors to the MnIV(O) and MnIV(O)–(HOTf)2 complexes were examined and evaluated in light of the Marcus theory of ET to determine the reorganization energies of ET. The smaller reorganization energies and much more positive reduction potentials of the [(L)MnIV(O)]2+–(HOTf)2 complexes resulted in greatly enhanced oxidation capacity towards one-electron reductants and para-X-substituted-thioanisoles. The reactivities of the Mn(IV)-oxo complexes were markedly enhanced by binding of HOTf, such as a 6.4 × 105-fold increase in the oxygen atom transfer (OAT) reaction (i.e., sulfoxidation). Such a remarkable acceleration in the OAT reaction results from the enhancement of ET from para-X-substituted-thioanisoles to the MnIV(O) complexes as revealed by the unified ET driving force dependence of the rate constants of OAT and ET reactions of [(L)MnIV(O)]2+–(HOTf)2. In contrast, deceleration was observed in the rate of H-atom transfer (HAT) reaction of [(L)MnIV(O)]2+–(HOTf)2 complexesmore »
- Authors:
-
- Ewha Womans Univ., Seoul (Korea)
- Osaka Univ., Suita (Japan). Graduate School of Engineering.
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Ewha Womans Univ., Seoul (Korea); Osaka Univ., Suita (Japan). Graduate School of Engineering.
- Publication Date:
- Research Org.:
- SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1215397
- Grant/Contract Number:
- AC03-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 6; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Chen, Junying, Yoon, Heejung, Lee, Yong -Min, Seo, Mi Sook, Sarangi, Ritimukta, Fukuzumi, Shunichi, and Nam, Wonwoo. Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid. United States: N. p., 2015.
Web. doi:10.1039/C5SC00535C.
Chen, Junying, Yoon, Heejung, Lee, Yong -Min, Seo, Mi Sook, Sarangi, Ritimukta, Fukuzumi, Shunichi, & Nam, Wonwoo. Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid. United States. https://doi.org/10.1039/C5SC00535C
Chen, Junying, Yoon, Heejung, Lee, Yong -Min, Seo, Mi Sook, Sarangi, Ritimukta, Fukuzumi, Shunichi, and Nam, Wonwoo. Tue .
"Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid". United States. https://doi.org/10.1039/C5SC00535C. https://www.osti.gov/servlets/purl/1215397.
@article{osti_1215397,
title = {Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid},
author = {Chen, Junying and Yoon, Heejung and Lee, Yong -Min and Seo, Mi Sook and Sarangi, Ritimukta and Fukuzumi, Shunichi and Nam, Wonwoo},
abstractNote = {Triflic acid (HOTf)-bound nonheme Mn(IV)-oxo complexes, [(L)MnIV(O)]2+–(HOTf)2 (L = N4Py and Bn-TPEN; N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine and Bn-TPEN = N-benzyl-N,N',N'-tris(2-pyridylmethyl)ethane-1,2-diamine), were synthesized by adding HOTf to the solutions of the [(L)MnIV(O)]2+ complexes and were characterized by various spectroscopies. The one-electron reduction potentials of the MnIV(O) complexes exhibited a significant positive shift upon binding of HOTf. The driving force dependences of electron transfer (ET) from electron donors to the MnIV(O) and MnIV(O)–(HOTf)2 complexes were examined and evaluated in light of the Marcus theory of ET to determine the reorganization energies of ET. The smaller reorganization energies and much more positive reduction potentials of the [(L)MnIV(O)]2+–(HOTf)2 complexes resulted in greatly enhanced oxidation capacity towards one-electron reductants and para-X-substituted-thioanisoles. The reactivities of the Mn(IV)-oxo complexes were markedly enhanced by binding of HOTf, such as a 6.4 × 105-fold increase in the oxygen atom transfer (OAT) reaction (i.e., sulfoxidation). Such a remarkable acceleration in the OAT reaction results from the enhancement of ET from para-X-substituted-thioanisoles to the MnIV(O) complexes as revealed by the unified ET driving force dependence of the rate constants of OAT and ET reactions of [(L)MnIV(O)]2+–(HOTf)2. In contrast, deceleration was observed in the rate of H-atom transfer (HAT) reaction of [(L)MnIV(O)]2+–(HOTf)2 complexes with 1,4-cyclohexadiene as compared with those of the [(L)MnIV(O)]2+ complexes. Thus, the binding of two HOTf molecules to the MnIV(O) moiety resulted in remarkable acceleration of the ET rate when the ET is thermodynamically feasible. When the ET reaction is highly endergonic, the rate of the HAT reaction is decelerated due to the steric effect of the counter anion of HOTf.},
doi = {10.1039/C5SC00535C},
journal = {Chemical Science},
number = 6,
volume = 6,
place = {United States},
year = {Tue Apr 14 00:00:00 EDT 2015},
month = {Tue Apr 14 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Mechanism of Oxidation Reactions Catalyzed by Cytochrome P450 Enzymes
journal, September 2004
- Meunier, Bernard; de Visser, Samuël P.; Shaik, Sason
- Chemical Reviews, Vol. 104, Issue 9
Reaction Mechanisms of Mononuclear Non-Heme Iron Oxygenases
journal, June 2005
- Abu-Omar, Mahdi M.; Loaiza, Aristobulo; Hontzeas, Nikos
- Chemical Reviews, Vol. 105, Issue 6
Structure and Chemistry of Cytochrome P450
journal, June 2005
- Denisov, Ilia G.; Makris, Thomas M.; Sligar, Stephen G.
- Chemical Reviews, Vol. 105, Issue 6
High-valent iron in chemical and biological oxidations
journal, April 2006
- Groves, John T.
- Journal of Inorganic Biochemistry, Vol. 100, Issue 4
Hydrocarbon Hydroxylation by Cytochrome P450 Enzymes
journal, February 2010
- Ortiz de Montellano, Paul R.
- Chemical Reviews, Vol. 110, Issue 2
P450 Enzymes: Their Structure, Reactivity, and Selectivity—Modeled by QM/MM Calculations
journal, February 2010
- Shaik, Sason; Cohen, Shimrit; Wang, Yong
- Chemical Reviews, Vol. 110, Issue 2
A Theory for Bioinorganic Chemical Reactivity of Oxometal Complexes and Analogous Oxidants: The Exchange and Orbital-Selection Rules
journal, December 2012
- Usharani, Dandamudi; Janardanan, Deepa; Li, Chunsen
- Accounts of Chemical Research, Vol. 46, Issue 2
Non-Heme Fe(IV)–Oxo Intermediates
journal, July 2007
- Krebs, Carsten; Galonić Fujimori, Danica; Walsh, Christopher T.
- Accounts of Chemical Research, Vol. 40, Issue 7
The Road to Non-Heme Oxoferryls and Beyond †
journal, July 2007
- Que, Lawrence
- Accounts of Chemical Research, Vol. 40, Issue 7
High-Valent Iron(IV)–Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions
journal, July 2007
- Nam, Wonwoo
- Accounts of Chemical Research, Vol. 40, Issue 7
Bioinspired Hydrogen Bond Motifs in Ligand Design: The Role of Noncovalent Interactions in Metal Ion Mediated Activation of Dioxygen
journal, January 2005
- Borovik, A. S.
- Accounts of Chemical Research, Vol. 38, Issue 1
Role of metal–oxo complexes in the cleavage of C–H bonds
journal, January 2011
- Borovik, A. S.
- Chemical Society Reviews, Vol. 40, Issue 4
The biology and chemistry of high-valent iron–oxo and iron–nitrido complexes
journal, January 2012
- Hohenberger, Johannes; Ray, Kallol; Meyer, Karsten
- Nature Communications, Vol. 3, Issue 1
Bispidine Coordination Chemistry
book, June 2007
- Comba, Peter; Kerscher, Marion; Schiek, Wolfgang
- Progress in Inorganic Chemistry, Volume 55
Kinetic and mechanistic studies of the reactions of transition metal-activated oxygen with inorganic substrates
journal, August 2006
- Bakac, Andreja
- Coordination Chemistry Reviews, Vol. 250, Issue 15-16
Related rhenium(V) catalysts adopt different mechanisms for oxygen atom transfer
journal, February 2005
- Espenson, James H.
- Coordination Chemistry Reviews, Vol. 249, Issue 3-4
Electronic structure and reactivity of high-valent oxo iron porphyrins
journal, March 2002
- Fujii, Hiroshi
- Coordination Chemistry Reviews, Vol. 226, Issue 1-2
Geometric and Electronic Structure/Function Correlations in Non-Heme Iron Enzymes
journal, January 2000
- Solomon, Edward I.; Brunold, Thomas C.; Davis, Mindy I.
- Chemical Reviews, Vol. 100, Issue 1
Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates
journal, February 2004
- Costas, Miquel; Mehn, Mark P.; Jensen, Michael P.
- Chemical Reviews, Vol. 104, Issue 2
Synthetic Models for Non-Heme Carboxylate-Bridged Diiron Metalloproteins: Strategies and Tactics
journal, February 2004
- Tshuva, Edit Y.; Lippard, Stephen J.
- Chemical Reviews, Vol. 104, Issue 2
Dioxygen activation by copper, heme and non-heme iron enzymes: comparison of electronic structures and reactivities
journal, April 2005
- Decker, Andrea; Solomon, Edward I.
- Current Opinion in Chemical Biology, Vol. 9, Issue 2
Peroxo and oxo intermediates in mononuclear nonheme iron enzymes and related active sites
journal, February 2009
- Solomon, Edward I.; Wong, Shaun D.; Liu, Lei V.
- Current Opinion in Chemical Biology, Vol. 13, Issue 1
Biological water oxidation: Lessons from Nature
journal, August 2012
- Najafpour, Mohammad Mahdi; Moghaddam, Atefeh Nemati; Allakhverdiev, Suleyman I.
- Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1817, Issue 8
Towards complete cofactor arrangement in the 3.0 Å resolution structure of photosystem II
journal, December 2005
- Loll, Bernhard; Kern, Jan; Saenger, Wolfram
- Nature, Vol. 438, Issue 7070
The Drosophila of single-molecule magnetism: [Mn12O12(O2CR)16(H2O)4]
journal, January 2009
- Bagai, Rashmi; Christou, George
- Chemical Society Reviews, Vol. 38, Issue 4
Reflections on small molecule manganese models that seek to mimic photosynthetic water oxidation chemistry
journal, February 2008
- Mullins, C.; Pecoraro, V.
- Coordination Chemistry Reviews, Vol. 252, Issue 3-4
Structure of photosystem II and molecular architecture of the oxygen-evolving centre
journal, August 2004
- Iwata, So; Barber, James
- Current Opinion in Structural Biology, Vol. 14, Issue 4
Photosynthetic generation of oxygen
journal, May 2008
- Barber, James
- Philosophical Transactions of the Royal Society B: Biological Sciences, Vol. 363, Issue 1504
Native structure of photosystem II at 1.95 Å resolution viewed by femtosecond X-ray pulses
journal, November 2014
- Suga, Michihiro; Akita, Fusamichi; Hirata, Kunio
- Nature, Vol. 517, Issue 7532
Crystal structure of oxygen-evolving photosystem II at a resolution of 1.9 Å
journal, April 2011
- Umena, Yasufumi; Kawakami, Keisuke; Shen, Jian-Ren
- Nature, Vol. 473, Issue 7345
Structure of the catalytic, inorganic core of oxygen-evolving photosystem II at 1.9Å resolution
journal, July 2011
- Kawakami, Keisuke; Umena, Yasufumi; Kamiya, Nobuo
- Journal of Photochemistry and Photobiology B: Biology, Vol. 104, Issue 1-2
Tuning Reactivity and Mechanism in Oxidation Reactions by Mononuclear Nonheme Iron(IV)-Oxo Complexes
journal, February 2014
- Nam, Wonwoo; Lee, Yong-Min; Fukuzumi, Shunichi
- Accounts of Chemical Research, Vol. 47, Issue 4
Nonheme Fe IV O Complexes That Can Oxidize the C−H Bonds of Cyclohexane at Room Temperature
journal, January 2004
- Kaizer, József; Klinker, Eric J.; Oh, Na Young
- Journal of the American Chemical Society, Vol. 126, Issue 2
A mononuclear nonheme iron(iv)-oxo complex which is more reactive than cytochrome P450 model compound I
journal, January 2011
- Seo, Mi Sook; Kim, Nam Hee; Cho, Kyung-Bin
- Chemical Science, Vol. 2, Issue 6
Ligand Topology Effect on the Reactivity of a Mononuclear Nonheme Iron(IV)-Oxo Complex in Oxygenation Reactions
journal, August 2011
- Hong, Seungwoo; Lee, Yong-Min; Cho, Kyung-Bin
- Journal of the American Chemical Society, Vol. 133, Issue 31
Metal Ion-Coupled Electron Transfer of a Nonheme Oxoiron(IV) Complex: Remarkable Enhancement of Electron-Transfer Rates by Sc 3+
journal, January 2011
- Morimoto, Yuma; Kotani, Hiroaki; Park, Jiyun
- Journal of the American Chemical Society, Vol. 133, Issue 3
Metal Ion Effect on the Switch of Mechanism from Direct Oxygen Transfer to Metal Ion-Coupled Electron Transfer in the Sulfoxidation of Thioanisoles by a Non-Heme Iron(IV)−Oxo Complex
journal, April 2011
- Park, Jiyun; Morimoto, Yuma; Lee, Yong-Min
- Journal of the American Chemical Society, Vol. 133, Issue 14
Scandium Ion-Enhanced Oxidative Dimerization and N -Demethylation of N , N -Dimethylanilines by a Non-Heme Iron(IV)-Oxo Complex
journal, November 2011
- Park, Jiyun; Morimoto, Yuma; Lee, Yong-Min
- Inorganic Chemistry, Vol. 50, Issue 22
Mechanistic Borderline of One-Step Hydrogen Atom Transfer versus Stepwise Sc 3+ -Coupled Electron Transfer from Benzyl Alcohol Derivatives to a Non-Heme Iron(IV)-Oxo Complex
journal, September 2012
- Morimoto, Yuma; Park, Jiyun; Suenobu, Tomoyoshi
- Inorganic Chemistry, Vol. 51, Issue 18
Valence Tautomerism in a High-Valent Manganese–Oxo Porphyrinoid Complex Induced by a Lewis Acid
journal, June 2012
- Leeladee, Pannee; Baglia, Regina A.; Prokop, Katharine A.
- Journal of the American Chemical Society, Vol. 134, Issue 25
Redox-inactive metals modulate the reduction potential in heterometallic manganese–oxido clusters
journal, March 2013
- Tsui, Emily Y.; Tran, Rosalie; Yano, Junko
- Nature Chemistry, Vol. 5, Issue 4
Oxygen Atom Transfer and Oxidative Water Incorporation in Cuboidal Mn 3 MO n Complexes Based on Synthetic, Isotopic Labeling, and Computational Studies
journal, January 2013
- Kanady, Jacob S.; Mendoza-Cortes, Jose L.; Tsui, Emily Y.
- Journal of the American Chemical Society, Vol. 135, Issue 3
A Synthetic Model of the Mn3Ca Subsite of the Oxygen-Evolving Complex in Photosystem II
journal, August 2011
- Kanady, J. S.; Tsui, E. Y.; Day, M. W.
- Science, Vol. 333, Issue 6043
Crystal structure of a metal ion-bound oxoiron(IV) complex and implications for biological electron transfer
journal, July 2010
- Fukuzumi, Shunichi; Morimoto, Yuma; Kotani, Hiroaki
- Nature Chemistry, Vol. 2, Issue 9
Catalysis on Electron Transfer and the Mechanistic Insight into Redox Reactions
journal, January 1997
- Fukuzumi, Shunichi
- Bulletin of the Chemical Society of Japan, Vol. 70, Issue 1
Metal ion-coupled and decoupled electron transfer
journal, February 2010
- Fukuzumi, Shunichi; Ohkubo, Kei
- Coordination Chemistry Reviews, Vol. 254, Issue 3-4
Metal Ion-coupled Electron-transfer Reduction of Dioxygen
journal, August 2008
- Fukuzumi, Shunichi
- Chemistry Letters, Vol. 37, Issue 8
Formation of superoxide–metal ion complexes and the electron transfer catalysis
journal, March 2002
- Fukuzumi, Shunichi; Ohtsu, Hideki; Ohkubo, Kei
- Coordination Chemistry Reviews, Vol. 226, Issue 1-2
Catalytic Control of Redox Reactivities of Coenzyme Analogs by Metal Ions
journal, October 2001
- Fukuzumi, Shunichi; Itoh, Shinobu
- Antioxidants & Redox Signaling, Vol. 3, Issue 5
Catalytic control of electron-transfer processes
journal, January 2003
- Fukuzumi, Shunichi
- Pure and Applied Chemistry, Vol. 75, Issue 5
Mechanisms of metal ion-coupled electron transfer
journal, January 2012
- Fukuzumi, Shunichi; Ohkubo, Kei; Morimoto, Yuma
- Physical Chemistry Chemical Physics, Vol. 14, Issue 24
Proton-Promoted Oxygen Atom Transfer vs Proton-Coupled Electron Transfer of a Non-Heme Iron(IV)-Oxo Complex
journal, February 2012
- Park, Jiyun; Morimoto, Yuma; Lee, Yong-Min
- Journal of the American Chemical Society, Vol. 134, Issue 8
Brønsted Acid-Promoted C–H Bond Cleavage via Electron Transfer from Toluene Derivatives to a Protonated Nonheme Iron(IV)-Oxo Complex with No Kinetic Isotope Effect
journal, March 2013
- Park, Jiyun; Lee, Yong-Min; Nam, Wonwoo
- Journal of the American Chemical Society, Vol. 135, Issue 13
Asymmetric Catalysis by Chiral Hydrogen-Bond Donors
journal, February 2006
- Taylor, Mark S.; Jacobsen, Eric N.
- Angewandte Chemie International Edition, Vol. 45, Issue 10
Stronger Brønsted Acids
journal, December 2007
- Akiyama, Takahiko
- Chemical Reviews, Vol. 107, Issue 12
Binding Modes in Metal Ion Complexes of Quinones and Semiquinone Radical Anions: Electron-Transfer Reactivity
journal, March 2006
- Yuasa, Junpei; Suenobu, Tomoyoshi; Fukuzumi, Shunichi
- ChemPhysChem, Vol. 7, Issue 4
Setting an Upper Limit on the Myoglobin Iron(IV)Hydroxide p K a : Insight into Axial Ligand Tuning in Heme Protein Catalysis
journal, June 2014
- Yosca, Timothy H.; Behan, Rachel K.; Krest, Courtney M.
- Journal of the American Chemical Society, Vol. 136, Issue 25
Iron(IV)hydroxide pKa and the Role of Thiolate Ligation in C-H Bond Activation by Cytochrome P450
journal, November 2013
- Yosca, T. H.; Rittle, J.; Krest, C. M.
- Science, Vol. 342, Issue 6160
Dramatically Accelerated Selective Oxygen-Atom Transfer by a Nonheme Iron(IV)-Oxo Complex: Tuning of the First and Second Coordination Spheres
journal, February 2014
- Widger, Leland R.; Davies, Casey G.; Yang, Tzuhsiung
- Journal of the American Chemical Society, Vol. 136, Issue 7
Does Hydrogen-Bonding Donation to Manganese(IV)-Oxo and Iron(IV)-Oxo Oxidants Affect the Oxygen-Atom Transfer Ability? A Computational Study
journal, January 2013
- Latifi, Reza; Sainna, Mala A.; Rybak-Akimova, Elena V.
- Chemistry - A European Journal, Vol. 19, Issue 12
Chemical and Electrochemical Electron-Transfer Theory
journal, October 1964
- Marcus, R. A.
- Annual Review of Physical Chemistry, Vol. 15, Issue 1
Electron transfers in chemistry and biology
journal, August 1985
- Marcus, R. A.; Sutin, Norman
- Biochimica et Biophysica Acta (BBA) - Reviews on Bioenergetics, Vol. 811, Issue 3
Electron Transfer Reactions in Chemistry: Theory and Experiment (Nobel Lecture)
journal, August 1993
- Marcus, Rudolph A.
- Angewandte Chemie International Edition in English, Vol. 32, Issue 8
A Mononuclear Non-Heme Manganese(IV)–Oxo Complex Binding Redox-Inactive Metal Ions
journal, January 2013
- Chen, Junying; Lee, Yong-Min; Davis, Katherine M.
- Journal of the American Chemical Society, Vol. 135, Issue 17
Enhanced Electron-Transfer Reactivity of Nonheme Manganese(IV)–Oxo Complexes by Binding Scandium Ions
journal, June 2013
- Yoon, Heejung; Lee, Yong-Min; Wu, Xiujuan
- Journal of the American Chemical Society, Vol. 135, Issue 24
A Highly Reactive Mononuclear Non-Heme Manganese(IV)–Oxo Complex That Can Activate the Strong C–H Bonds of Alkanes
journal, December 2011
- Wu, Xiujuan; Seo, Mi Sook; Davis, Katherine M.
- Journal of the American Chemical Society, Vol. 133, Issue 50
Electron-transfer properties of a nonheme manganese(iv)–oxo complex acting as a stronger one-electron oxidant than the iron(iv)–oxo analogue
journal, January 2012
- Yoon, Heejung; Morimoto, Yuma; Lee, Yong-Min
- Chemical Communications, Vol. 48, Issue 91
Water-soluble hexadentate Schiff-base ligands as sequestrating agents for iron(III) and gallium(III)
journal, January 1988
- Evans, Dennis F.; Jakubovic, David A.
- Journal of the Chemical Society, Dalton Transactions, Issue 12
Electron-transfer properties of high-valent metal-oxo complexes
journal, May 2013
- Fukuzumi, Shunichi
- Coordination Chemistry Reviews, Vol. 257, Issue 9-10
Fundamental Electron-Transfer Properties of Non-heme Oxoiron(IV) Complexes
journal, January 2008
- Lee, Yong-Min; Kotani, Hiroaki; Suenobu, Tomoyoshi
- Journal of the American Chemical Society, Vol. 130, Issue 2
Demonstration of the Heterolytic OO Bond Cleavage of Putative Nonheme Iron(II)OOH(R) Complexes for Fenton and Enzymatic Reactions
journal, June 2014
- Bang, Suhee; Park, Sora; Lee, Yong-Min
- Angewandte Chemie International Edition, Vol. 53, Issue 30
Photochemical Reactions of Coenzyme PQQ (Pyrroloquinolinequinone) and Analogues with Benzyl Alcohol Derivatives via Photoinduced Electron Transfer
journal, September 2000
- Fukuzumi, Shunichi; Itoh, Shinobu; Komori, Takashi
- Journal of the American Chemical Society, Vol. 122, Issue 35
Evidence for an Alternative to the Oxygen Rebound Mechanism in C–H Bond Activation by Non-Heme Fe IV O Complexes
journal, December 2012
- Cho, Kyung-Bin; Wu, Xiujuan; Lee, Yong-Min
- Journal of the American Chemical Society, Vol. 134, Issue 50
Synthetic Models for Non-Heme Carboxylate-Bridged Diiron Metalloproteins: Strategies and Tactics
journal, May 2004
- Tshuva, Edit Y.; Lippard, Stephen J.
- ChemInform, Vol. 35, Issue 21
Dioxygen Activation at Mononuclear Nonheme Iron Active Sites: Enzymes, Models, and Intermediates
journal, May 2004
- Costas, Miquel; Mehn, Mark P.; Jensen, Michael P.
- ChemInform, Vol. 35, Issue 21
Reaction Mechanisms of Mononuclear Non-Heme Iron Oxygenases
journal, September 2005
- Abu-Omar, Mahdi M.; Loaiza, Aristobulo; Hontzeas, Nikos
- ChemInform, Vol. 36, Issue 37
Structure and Chemistry of Cytochrome P450
journal, September 2005
- Denisov, Ilia G.; Makris, Thomas M.; Sligar, Stephen G.
- ChemInform, Vol. 36, Issue 37
The Road to Non-Heme Oxoferryls and Beyond
journal, October 2007
- Que, Lawrence Jr.
- ChemInform, Vol. 38, Issue 40
Non-Heme Fe(IV)—Oxo Intermediates
journal, October 2007
- Krebs, Carsten; Galonic Fujimori, Danica; Walsh, Christopher T.
- ChemInform, Vol. 38, Issue 40
Bioinspired Hydrogen Bond Motifs in Ligand Design: The Role of Noncovalent Interactions in Metal Ion Mediated Activation of Dioxygen
journal, April 2005
- Borovik, A. S.
- ChemInform, Vol. 36, Issue 17
High-Valent Iron(IV)—Oxo Complexes of Heme and Non-Heme Ligands in Oxygenation Reactions
journal, October 2007
- Nam, Wonwoo
- ChemInform, Vol. 38, Issue 40
Asymmetric Catalysis by Chiral Hydrogen-Bond Donors
journal, May 2006
- Taylor, Mark S.; Jacobsen, Eric N.
- ChemInform, Vol. 37, Issue 22
Demonstration of the Heterolytic OO Bond Cleavage of Putative Nonheme Iron(II)OOH(R) Complexes for Fenton and Enzymatic Reactions
journal, June 2014
- Bang, Suhee; Park, Sora; Lee, Yong-Min
- Angewandte Chemie, Vol. 126, Issue 30
Works referencing / citing this record:
Effects of Lewis Acids on Photoredox Catalysis
journal, February 2017
- Fukuzumi, Shunichi; Jung, Jieun; Lee, Yong‐Min
- Asian Journal of Organic Chemistry, Vol. 6, Issue 4
Oxidationsreaktionen mit bioinspirierten einkernigen Nicht-Häm-Oxidometallkomplexen
journal, June 2016
- Engelmann, Xenia; Monte-Pérez, Inés; Ray, Kallol
- Angewandte Chemie, Vol. 128, Issue 27
Oxidation of Naphthalene with a Manganese(IV) Bis(hydroxo) Complex in the Presence of Acid
journal, May 2018
- Jeong, Donghyun; Yan, James J.; Noh, Hyeonju
- Angewandte Chemie, Vol. 130, Issue 26
Oxidation Reactions with Bioinspired Mononuclear Non-Heme Metal-Oxo Complexes
journal, June 2016
- Engelmann, Xenia; Monte-Pérez, Inés; Ray, Kallol
- Angewandte Chemie International Edition, Vol. 55, Issue 27
Mononuclear Nonheme High-Spin ( S =2) versus Intermediate-Spin ( S =1) Iron(IV)-Oxo Complexes in Oxidation Reactions
journal, June 2016
- Bae, Seong Hee; Seo, Mi Sook; Lee, Yong-Min
- Angewandte Chemie International Edition, Vol. 55, Issue 28
Structure and Unprecedented Reactivity of a Mononuclear Nonheme Cobalt(III) Iodosylbenzene Complex
journal, May 2020
- Yang, Jindou; Seo, Mi Sook; Kim, Kyung Ha
- Angewandte Chemie International Edition, Vol. 59, Issue 32
Lewis Acid Coupled Electron Transfer of Metal-Oxygen Intermediates
journal, September 2015
- Fukuzumi, Shunichi; Ohkubo, Kei; Lee, Yong-Min
- Chemistry - A European Journal, Vol. 21, Issue 49
Electronic Structure of Manganese Complexes of the Redox-Non-innocent Tetrazene Ligand and Evidence for the Metal-Azide/Imido Cycloaddition Intermediate
journal, June 2016
- Vaddypally, Shivaiah; McKendry, Ian G.; Tomlinson, Warren
- Chemistry - A European Journal, Vol. 22, Issue 30
Structural Characterization of a Series of N5‐Ligated Mn IV ‐Oxo Species
journal, September 2019
- Massie, Allyssa A.; Denler, Melissa C.; Singh, Reena
- Chemistry – A European Journal, Vol. 26, Issue 4
Generation and Electron‐Transfer Reactivity of the Long‐Lived Photoexcited State of a Manganese(IV)‐Oxo‐Scandium Nitrate Complex
journal, January 2020
- Sharma, Namita; Lee, Yong‐Min; Nam, Wonwoo
- Israel Journal of Chemistry, Vol. 60, Issue 10-11
Chemoselective methylene oxidation in aromatic molecules
journal, December 2018
- Zhao, Jinpeng; Nanjo, Takeshi; de Lucca, Emilio C.
- Nature Chemistry, Vol. 11, Issue 3
Thermal and photocatalytic oxidation of organic substrates by dioxygen with water as an electron source
journal, January 2018
- Fukuzumi, Shunichi; Lee, Yong-Min; Jung, Jieun
- Green Chemistry, Vol. 20, Issue 5
A theoretical study on the oxidation of alkenes to aldehydes catalyzed by ruthenium porphyrins using O 2 as the sole oxidant
journal, January 2018
- Zhang, Lin-Lin; Wang, Xiang-Yun; Jiang, Kun-Yao
- Dalton Transactions, Vol. 47, Issue 15
Fundamental electron-transfer and proton-coupled electron-transfer properties of Ru( iv )-oxo complexes
journal, January 2019
- Kotani, Hiroaki; Shimomura, Hinatsu; Horimoto, Momoka
- Dalton Transactions, Vol. 48, Issue 35
Mononuclear Nonheme High-Spin ( S =2) versus Intermediate-Spin ( S =1) Iron(IV)-Oxo Complexes in Oxidation Reactions
journal, June 2016
- Bae, Seong Hee; Seo, Mi Sook; Lee, Yong-Min
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