Microstructures and mechanical properties of compositionally complex Co-free FeNiMnCr18 FCC solid solution alloy
Abstract
Recently, a structurally-simple but compositionally-complex FeNiCoMnCr high entropy alloy was found to have excellent mechanical properties (e.g., high strength and ductility). To understand the potential of using high entropy alloys as structural materials for advanced nuclear reactor and power plants, it is necessary to have a thorough understanding of their structural stability and mechanical properties degradation under neutron irradiation. Furthermore, this requires us to develop a similar model alloy without Co because material with Co will make post-neutron-irradiation testing difficult due to the production of the 60Co radioisotope. In order to achieve this goal, a FCC-structured single-phase alloy with a composition of FeNiMnCr18 was successfully developed. This near-equiatomic FeNiMnCr18 alloy has good malleability and its microstructure can be controlled by thermomechanical processing. By rolling and annealing, the as-cast elongated-grained-microstructure is replaced by homogeneous equiaxed grains. The mechanical properties (e.g., strength and ductility) of the FeNiMnCr18 alloy are comparable to those of the equiatomic FeNiCoMnCr high entropy alloy. Both strength and ductility increase with decreasing deformation temperature, with the largest difference occurring between 293 and 77 K. Extensive twin-bands which are bundles of numerous individual twins are observed when it is tensile-fractured at 77 K. No twin bands are detected bymore »
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Univ. of Tennessee, Knoxville, TN (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1185986
- Alternate Identifier(s):
- OSTI ID: 1250153
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing
- Additional Journal Information:
- Journal Volume: 640; Journal Issue: C; Journal ID: ISSN 0921-5093
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Solid solution alloys; Mechanical properties; Hardening; Microstructure; EBSD; High entropy alloy
Citation Formats
Wu, Z., and Bei, H. Microstructures and mechanical properties of compositionally complex Co-free FeNiMnCr18 FCC solid solution alloy. United States: N. p., 2015.
Web. doi:10.1016/j.msea.2015.05.097.
Wu, Z., & Bei, H. Microstructures and mechanical properties of compositionally complex Co-free FeNiMnCr18 FCC solid solution alloy. United States. https://doi.org/10.1016/j.msea.2015.05.097
Wu, Z., and Bei, H. Wed .
"Microstructures and mechanical properties of compositionally complex Co-free FeNiMnCr18 FCC solid solution alloy". United States. https://doi.org/10.1016/j.msea.2015.05.097. https://www.osti.gov/servlets/purl/1185986.
@article{osti_1185986,
title = {Microstructures and mechanical properties of compositionally complex Co-free FeNiMnCr18 FCC solid solution alloy},
author = {Wu, Z. and Bei, H.},
abstractNote = {Recently, a structurally-simple but compositionally-complex FeNiCoMnCr high entropy alloy was found to have excellent mechanical properties (e.g., high strength and ductility). To understand the potential of using high entropy alloys as structural materials for advanced nuclear reactor and power plants, it is necessary to have a thorough understanding of their structural stability and mechanical properties degradation under neutron irradiation. Furthermore, this requires us to develop a similar model alloy without Co because material with Co will make post-neutron-irradiation testing difficult due to the production of the 60Co radioisotope. In order to achieve this goal, a FCC-structured single-phase alloy with a composition of FeNiMnCr18 was successfully developed. This near-equiatomic FeNiMnCr18 alloy has good malleability and its microstructure can be controlled by thermomechanical processing. By rolling and annealing, the as-cast elongated-grained-microstructure is replaced by homogeneous equiaxed grains. The mechanical properties (e.g., strength and ductility) of the FeNiMnCr18 alloy are comparable to those of the equiatomic FeNiCoMnCr high entropy alloy. Both strength and ductility increase with decreasing deformation temperature, with the largest difference occurring between 293 and 77 K. Extensive twin-bands which are bundles of numerous individual twins are observed when it is tensile-fractured at 77 K. No twin bands are detected by EBSD for materials deformed at 293 K and higher. Ultimately the unusual temperature-dependencies of UTS and uniform elongation could be caused by the development of the dense twin substructure, twin-dislocation interactions and the interactions between primary and secondary twinning systems which result in a microstructure refinement and hence cause enhanced strain hardening and postponed necking.},
doi = {10.1016/j.msea.2015.05.097},
journal = {Materials Science and Engineering. A, Structural Materials: Properties, Microstructure and Processing},
number = C,
volume = 640,
place = {United States},
year = {Wed Jul 01 00:00:00 EDT 2015},
month = {Wed Jul 01 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
Metallurgical factors affecting fracture toughness of aluminum alloys
journal, April 1975
- Hahn, G. T.; Rosenfield, A. R.
- Metallurgical Transactions A, Vol. 6, Issue 4
Effects of Er on the microstructure and mechanical properties of an as-extruded Al–Mg alloy
journal, March 2009
- Wu, Z. G.; Song, Min; He, Y. H.
- Materials Science and Engineering: A, Vol. 504, Issue 1-2
Effects of Yb on the mechanical properties and microstructures of an Al–Mg alloy
journal, December 2008
- Song, Min; Wu, Zhenggang; He, Yuehui
- Materials Science and Engineering: A, Vol. 497, Issue 1-2
Microstructural development in an aluminum alloy-SiC whisker composite
journal, July 1988
- Christman, T.; Suresh, S.
- Acta Metallurgica, Vol. 36, Issue 7
Enhanced plasticity of twin-roll cast ZK60 magnesium alloy through differential speed rolling
journal, October 2009
- Gong, Xibing; Kang, Suk Bong; Li, Saiyi
- Materials & Design, Vol. 30, Issue 9
Microstructure and mechanical properties of twin-roll cast Mg–4.5Al–1.0Zn sheets processed by differential speed rolling
journal, March 2010
- Gong, Xibing; Li, Hao; Kang, Suk Bong
- Materials & Design, Vol. 31, Issue 3
Physical fields evolution and microstructures for compound extrusion of AZ31 magnesium alloy
journal, May 2014
- Hu, H. -J.; Fan, J. -Z.; Zhai, Z. -Y.
- Russian Journal of Non-Ferrous Metals, Vol. 55, Issue 3
An experimental study of the (Ti–6Al–4V)–xH phase diagram using in situ synchrotron XRD and TGA/DSC techniques
journal, February 2015
- Sun, Pei; Fang, Z. Zak; Koopman, Mark
- Acta Materialia, Vol. 84
Experimental and modeling results of creep–fatigue life of Inconel 617 and Haynes 230 at 850°C
journal, January 2013
- Chen, Xiang; Sokolov, Mikhail A.; Sham, Sam
- Journal of Nuclear Materials, Vol. 432, Issue 1-3
Low cycle fatigue and creep-fatigue behavior of Ni-based alloy 230 at 850 °C
journal, February 2013
- Chen, Xiang; Yang, Zhiqing; Sokolov, Mikhail A.
- Materials Science and Engineering: A, Vol. 563
The Deformation and Ageing of Mild Steel: III Discussion of Results
journal, September 1951
- Hall, E. O.
- Proceedings of the Physical Society. Section B, Vol. 64, Issue 9
The bainite transformation in a silicon steel
journal, July 1979
- Bhadeshia, H. K. D. H.; Edmonds, D. V.
- Metallurgical Transactions A, Vol. 10, Issue 7
Analysis of corrosion scale structure of pre-oxidized stainless steel 316 in molten lead bismuth eutectic and the relation to impedance spectroscopy response
journal, March 2010
- Chen, Xiang; Stubbins, James F.; Hosemann, Peter
- Journal of Nuclear Materials, Vol. 398, Issue 1-3
Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004
- Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
- Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
Microstructure and room temperature properties of a high-entropy TaNbHfZrTi alloy
journal, May 2011
- Senkov, O. N.; Scott, J. M.; Senkova, S. V.
- Journal of Alloys and Compounds, Vol. 509, Issue 20
Phase stability in high entropy alloys: Formation of solid-solution phase or amorphous phase
journal, December 2011
- Guo, Sheng; Liu, C. T.
- Progress in Natural Science: Materials International, Vol. 21, Issue 6
Prediction of high-entropy stabilized solid-solution in multi-component alloys
journal, February 2012
- Yang, X.; Zhang, Y.
- Materials Chemistry and Physics, Vol. 132, Issue 2-3
Microstructural development in equiatomic multicomponent alloys
journal, July 2004
- Cantor, B.; Chang, I. T. H.; Knight, P.
- Materials Science and Engineering: A, Vol. 375-377
Local Atomic Structure of a High-Entropy Alloy: An X-Ray and Neutron Scattering Study
journal, November 2012
- Guo, Wei; Dmowski, Wojciech; Noh, Ji-Yong
- Metallurgical and Materials Transactions A, Vol. 44, Issue 5
Relative effects of enthalpy and entropy on the phase stability of equiatomic high-entropy alloys
journal, April 2013
- Otto, F.; Yang, Y.; Bei, H.
- Acta Materialia, Vol. 61, Issue 7
Recovery, recrystallization, grain growth and phase stability of a family of FCC-structured multi-component equiatomic solid solution alloys
journal, March 2014
- Wu, Z.; Bei, H.; Otto, F.
- Intermetallics, Vol. 46
Grain growth and the Hall–Petch relationship in a high-entropy FeCrNiCoMn alloy
journal, April 2013
- Liu, W. H.; Wu, Y.; He, J. Y.
- Scripta Materialia, Vol. 68, Issue 7
Sluggish diffusion in Co–Cr–Fe–Mn–Ni high-entropy alloys
journal, August 2013
- Tsai, K. -Y.; Tsai, M. -H.; Yeh, J. -W.
- Acta Materialia, Vol. 61, Issue 13
Temperature dependence of the mechanical properties of equiatomic solid solution alloys with face-centered cubic crystal structures
journal, December 2014
- Wu, Z.; Bei, H.; Pharr, G. M.
- Acta Materialia, Vol. 81
The influences of temperature and microstructure on the tensile properties of a CoCrFeMnNi high-entropy alloy
journal, September 2013
- Otto, F.; Dlouhý, A.; Somsen, Ch.
- Acta Materialia, Vol. 61, Issue 15
Nanoscale phase separation in a fcc-based CoCrCuFeNiAl0.5 high-entropy alloy
journal, February 2015
- Xu, X. D.; Liu, P.; Guo, S.
- Acta Materialia, Vol. 84
Damping behavior of AlxCoCrFeNi high-entropy alloys by a dynamic mechanical analyzer
journal, August 2014
- Ma, S. G.; Liaw, P. K.; Gao, M. C.
- Journal of Alloys and Compounds, Vol. 604
Effect of Nb addition on the microstructure and properties of AlCoCrFeNi high-entropy alloy
journal, January 2012
- Ma, S. G.; Zhang, Y.
- Materials Science and Engineering: A, Vol. 532
Effect of aluminum on the microstructure and properties of two refractory high-entropy alloys
journal, April 2014
- Senkov, O. N.; Senkova, S. V.; Woodward, C.
- Acta Materialia, Vol. 68
A fracture-resistant high-entropy alloy for cryogenic applications
journal, September 2014
- Gludovatz, B.; Hohenwarter, A.; Catoor, D.
- Science, Vol. 345, Issue 6201
Thermal and mechanical properties of the Cr-Mn-(Ni-free) austenitic steels for fusion reactor applications
journal, November 1986
- Piatti, G.; Schiller, P.
- Journal of Nuclear Materials, Vol. 141-143
Effect of manganese on the stability of austenite in Fe-Cr-Ni alloys
journal, February 1995
- Raghavan, V.
- Metallurgical and Materials Transactions A, Vol. 26, Issue 2
Risks of “Cleaning” Electron Backscatter Diffraction Data
journal, March 2010
- Brewer, L. N.; Michael, J. R.
- Microscopy Today, Vol. 18, Issue 2
Measurement of plastic strain of polycrystalline material by electron backscatter diffraction
journal, March 2005
- Kamaya, Masayuki; Wilkinson, Angus J.; Titchmarsh, John M.
- Nuclear Engineering and Design, Vol. 235, Issue 6
Deformation twinning in silver-gold alloys
journal, March 1958
- Suzuki, H.; Barrett, C. S.
- Acta Metallurgica, Vol. 6, Issue 3
Low‐Temperature Deformation of Copper Single Crystals
journal, June 1957
- Blewitt, T. H.; Coltman, R. R.; Redman, J. K.
- Journal of Applied Physics, Vol. 28, Issue 6
Dependence of deformation twinning on grain orientation in a high manganese steel
journal, October 2006
- Yang, P.; Xie, Q.; Meng, L.
- Scripta Materialia, Vol. 55, Issue 7
Tensile properties and twinning behavior of high manganese austenitic steel with fine-grained structure
journal, November 2008
- Ueji, R.; Tsuchida, N.; Terada, D.
- Scripta Materialia, Vol. 59, Issue 9
The effect of grain size and grain orientation on deformation twinning in a Fe–22wt.% Mn–0.6wt.% C TWIP steel
journal, June 2010
- Gutierrez-Urrutia, I.; Zaefferer, S.; Raabe, D.
- Materials Science and Engineering: A, Vol. 527, Issue 15
Microstructural evolution during plastic deformation of twinning-induced plasticity steels
journal, June 2012
- Lee, Young-Kook
- Scripta Materialia, Vol. 66, Issue 12
The dependence of the width of a dissociated dislocation on dislocation velocity
journal, February 1968
- Copley, S. M.; Kear, B. H.
- Acta Metallurgica, Vol. 16, Issue 2
Plastic deformation and phase transformation in textured austenitic stainless steel
journal, November 1970
- Goodchild, D.; Roberts, W. T.; Wilson, D. V.
- Acta Metallurgica, Vol. 18, Issue 11
The effect of applied stress on partial dislocation separation and dislocation substructure in austenitic stainless steel
journal, December 1977
- Kestenbach, H. -J.
- Philosophical Magazine, Vol. 36, Issue 6
Is there a relationship between the stacking fault character and the activated mode of plasticity of Fe–Mn-based austenitic steels?
journal, June 2009
- Idrissi, H.; Ryelandt, L.; Veron, M.
- Scripta Materialia, Vol. 60, Issue 11
Deformation twinning
journal, January 1995
- Christian, J. W.; Mahajan, S.
- Progress in Materials Science, Vol. 39, Issue 1-2
Kinetics of f.c.c. deformation twinning and its relationship to stress-strain behaviour
journal, March 1978
- Remy, L.
- Acta Metallurgica, Vol. 26, Issue 3
Strain hardening regimes and microstructural evolution during large strain compression of low stacking fault energy fcc alloys that form deformation twins
journal, September 1997
- Asgari, Sirous; El-Danaf, Ehab; Kalidindi, Surya R.
- Metallurgical and Materials Transactions A, Vol. 28, Issue 9
The influence of stacking fault energy on the mechanical behavior of Cu and Cu-Al alloys: Deformation twinning, work hardening, and dynamic recovery
journal, January 2001
- Rohatgi, Aashish; Vecchio, Kenneth S.; Gray, George T.
- Metallurgical and Materials Transactions A, Vol. 32, Issue 1
Orientation dependence of twinning and strain hardening behaviour of a high manganese twinning induced plasticity steel with polycrystalline structure
journal, December 2011
- Beladi, H.; Timokhina, I. B.; Estrin, Y.
- Acta Materialia, Vol. 59, Issue 20
Twinning and strain-induced f.c.c. → h.c.p. transformation on the mechanical properties of CoNiCrMo alloys
journal, November 1976
- Rémy, L.; Pineau, A.
- Materials Science and Engineering, Vol. 26, Issue 1
Dislocation and twin substructure evolution during strain hardening of an Fe–22wt.% Mn–0.6wt.% C TWIP steel observed by electron channeling contrast imaging
journal, September 2011
- Gutierrez-Urrutia, I.; Raabe, D.
- Acta Materialia, Vol. 59, Issue 16
Deformation twinning in polycrystalline copper at room temperature and low strain rate
journal, February 2006
- Huang, C. X.; Wang, K.; Wu, S. D.
- Acta Materialia, Vol. 54, Issue 3
Dependence of tensile deformation behavior of TWIP steels on stacking fault energy, temperature and strain rate
journal, September 2010
- Curtze, S.; Kuokkala, V. -T.
- Acta Materialia, Vol. 58, Issue 15
Supra-Ductile and High-Strength Manganese-TRIP/TWIP Steels for High Energy Absorption Purposes.
journal, January 2003
- Frommeyer, Georg; Brüx, Udo; Neumann, Peter
- ISIJ International, Vol. 43, Issue 3
Works referencing / citing this record:
Fabrication of ODS Austenitic Steels and CoCrFeNi High-Entropy Alloys by Spark Plasma Sintering for Nuclear Energy Applications
journal, May 2019
- Yan, Xueliang; Zhang, Xiang; Wang, Fei
- JOM, Vol. 71, Issue 8
Phase Stability and Mechanical Properties of FCC Structural CoCrCu0.5FeNi High-Entropy Alloy with Silicon or Boron Addition
journal, January 2019
- Chen, Chen; Liu, Ning; Zhou, Peng Jie
- Materials Science Forum, Vol. 944
Strong grain-size effect on deformation twinning of an Al 0.1 CoCrFeNi high-entropy alloy
journal, November 2016
- Wu, S. W.; Wang, G.; Yi, J.
- Materials Research Letters, Vol. 5, Issue 4
High-Entropy Alloys: Potential Candidates for High-Temperature Applications - An Overview
journal, October 2017
- Praveen, Sathiyamoorthi; Kim, Hyoung Seop
- Advanced Engineering Materials, Vol. 20, Issue 1
Cold Gas Spraying of a High-Entropy CrFeNiMn Equiatomic Alloy
journal, January 2020
- Lehtonen, Joonas; Koivuluoto, Heli; Ge, Yanling
- Coatings, Vol. 10, Issue 1