Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures

Seoung, Donghoon; Cynn, Hyunchae; Park, Changyong; Choi, Kwang -Yong; Blom, Douglas A.; Evans, William J.; Kao, Chi -Chang; Vogt, Thomas; Lee, Yongjae

doi:10.1038/nchem.1997

Title: Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures

Abstract

Pressure drastically alters the chemical and physical properties of materials and allows structural phase transitions and chemical reactions to occur that defy much of our understanding gained under ambient conditions. Particularly exciting is the high-pressure chemistry of xenon, which is known to react with hydrogen and ice at high pressures and form stable compounds. Here, we show that Ag₁₆Al₁₆Si₂₄O₈·16H₂O (Ag-natrolite) irreversibly inserts xenon into its micropores at 1.7 GPa and 250 °C, while Ag⁺ is reduced to metallic Ag and possibly oxidized to Ag²⁺. In contrast to krypton, xenon is retained within the pores of this zeolite after pressure release and requires heat to desorb. This irreversible insertion and trapping of xenon in Ag-natrolite under moderate conditions sheds new light on chemical reactions that could account for the xenon deficiency relative to argon observed in terrestrial and Martian atmospheres.

Authors:

Seoung, Donghoon ^[1]; Cynn, Hyunchae ^[2]; Park, Changyong ^[3]; Choi, Kwang -Yong ^[4]; Blom, Douglas A. ^[5]; Evans, William J. ^[2]; Kao, Chi -Chang ^[6]; Vogt, Thomas ^[5]; Lee, Yongjae ^[1]

Yonsei Univ., Seoul (Korea)
Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Carnegie Institution of Washington, Argonne, IL (United States)
Chung-Ang Univ., Seoul (Korea)
Univ. of South Carolina, Columbia, SC (United States)
SLAC National Accelerator Lab., Menlo Park, CA (United States)

Publication Date:: Mon Sep 01 00:00:00 EDT 2014

Research Org.:: Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1158896

Report Number(s):: LLNL-JRNL-648696
Journal ID: ISSN 1755-4330

Grant/Contract Number:: AC52-07NA27344

Resource Type:: Accepted Manuscript

Journal Name:: Nature Chemistry

Additional Journal Information:: Journal Volume: 6; Journal Issue: 9; Journal ID: ISSN 1755-4330

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND 77 NANOSCIENCE AND NANOTECHNOLOGY; 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats


                    Seoung, Donghoon, Cynn, Hyunchae, Park, Changyong, Choi, Kwang -Yong, Blom, Douglas A., Evans, William J., Kao, Chi -Chang, Vogt, Thomas, and Lee, Yongjae. Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures.  United States: N. p., 2014. 
Web.  doi:10.1038/nchem.1997.

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                    Seoung, Donghoon, Cynn, Hyunchae, Park, Changyong, Choi, Kwang -Yong, Blom, Douglas A., Evans, William J., Kao, Chi -Chang, Vogt, Thomas, & Lee, Yongjae. Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures.  United States.  https://doi.org/10.1038/nchem.1997

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                    Seoung, Donghoon, Cynn, Hyunchae, Park, Changyong, Choi, Kwang -Yong, Blom, Douglas A., Evans, William J., Kao, Chi -Chang, Vogt, Thomas, and Lee, Yongjae. Mon .  
"Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures".  United States.  https://doi.org/10.1038/nchem.1997.  https://www.osti.gov/servlets/purl/1158896.

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@article{osti_1158896,

  title        = {Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures},

  author       = {Seoung, Donghoon and Cynn, Hyunchae and Park, Changyong and Choi, Kwang -Yong and Blom, Douglas A. and Evans, William J. and Kao, Chi -Chang and Vogt, Thomas and Lee, Yongjae},

  abstractNote = {Pressure drastically alters the chemical and physical properties of materials and allows structural phase transitions and chemical reactions to occur that defy much of our understanding gained under ambient conditions. Particularly exciting is the high-pressure chemistry of xenon, which is known to react with hydrogen and ice at high pressures and form stable compounds. Here, we show that Ag16Al16Si24O8·16H2O (Ag-natrolite) irreversibly inserts xenon into its micropores at 1.7 GPa and 250 °C, while Ag+ is reduced to metallic Ag and possibly oxidized to Ag2+. In contrast to krypton, xenon is retained within the pores of this zeolite after pressure release and requires heat to desorb. This irreversible insertion and trapping of xenon in Ag-natrolite under moderate conditions sheds new light on chemical reactions that could account for the xenon deficiency relative to argon observed in terrestrial and Martian atmospheres.},

  doi          = {10.1038/nchem.1997},

  journal      = {Nature Chemistry},

  number       = 9,

  volume       = 6,

  place        = {United States},

  year         = {Mon Sep 01 00:00:00 EDT 2014},

  month        = {Mon Sep 01 00:00:00 EDT 2014}

}

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https://doi.org/10.1038/nchem.1997

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Title: Irreversible xenon insertion into a small-pore zeolite at moderate pressures and temperatures

Abstract

Citation Formats

Atypical compounds of gases, which have been called ‘noble’ journal, January 2007

Unexpected Stable Stoichiometries of Sodium Chlorides journal, December 2013

The Chemical Imagination at Work inVery Tight Places journal, May 2007

Pressure-induced bonding and compound formation in xenon–hydrogen solids journal, November 2009

Reactivity of Xenon with Ice at Planetary Conditions journal, June 2013

Mars and Earth: Origin and Abundance of Volatiles journal, November 1977

The origin of the terrestrial noble-gas signature journal, October 2012

Recycling of oceanic crust and sediments: the noble gas subduction barrier journal, July 1988

Seawater subduction controls the heavy noble gas composition of the mantle journal, May 2006

Non-stoichiometric clathrate compounds of water. Part 2.—Formation and properties of double hydrates journal, January 1962

Crystal Structures of Encapsulates within Zeolites. 3. Xenon in Zeolite A journal, March 1999

129 Xe NMR study of xenon adsorbed on Y zeolites journal, June 1982

Evidence for xenon silicates at high pressure and temperature: XE-SILICATES AT HIGH PRESSURES journal, September 2002

Retention of Xenon in Quartz and Earth's Missing Xenon journal, November 2005

Stability of xenon oxides at high pressures journal, November 2012

The sorption of krypton and xenon in zeolites at high pressures and temperatures I. Chabazite journal, January 1972

The sorption of krypton and xenon in zeolites at high pressures and temperatures II. Comparison and analysis journal, January 1972

Adsorption of Noble Gases on Silver-mordenite journal, September 2003

Xenon Adsorption on Modified ETS-10 journal, February 2007

Xenon Capture on Silver-Loaded Zeolites: Characterization of Very Strong Adsorption Sites journal, July 2013

Theoretical Study on the Interaction between Xenon and Positively Charged Silver Clusters in Gas Phase and on the (001) Chabazite Surface journal, June 2009

Super-Hydrated Zeolites: Pressure-Induced Hydration in Natrolites journal, July 2013

Pressure-Induced Argon Insertion into an Auxetic Small Pore Zeolite journal, March 2010

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Formation of Ag Clusters by Electron Beam Irradiation of Ag-Zeolites journal, January 2009

Sonochemical synthesis of silver nanoparticles in Y-zeolite substrate journal, March 2010

Pressure-Induced Hydration and Insertion of CO 2 into Ag-Natrolite journal, April 2013

Preparation and properties of hydrogen form of stilbite, heulandite and clinoptilolite zeolites journal, January 1979

The Formation of Metallic Silver in Silver-Form Zeolites journal, August 1972

Ligand-induced disproportionation of silver(I) journal, October 1972

Beyond fluorides: Extension of chemistry of divalent silver to oxo ligands journal, February 2008

Electroprecipitation of Ag(II)/Ag(III) tetraphenylsulfonate porphyrin and electrocatalytic behavior of the films journal, November 2002

Generation of nitric oxide by photolysis of silver hyponitrite in suspension induced by LMCT excitation journal, November 2007

Synthesis, characterization and property of a mixed-valent AgI/AgII coordination polymer journal, January 2009

ESR studies of the silver(2+) ion produced in Ag-X zeolite by .gamma.-irradiation journal, October 1978

Xenon as a Mediator of Chemical Reactions? Case of Elusive Gold Monofluoride, AuF, and its Adduct with Xenon, XeAuF journal, June 2008

Stable Ag(II) Coordination Complexes in the Gas Phase journal, May 1999

Natrolite is not a "soda-stone" anymore: Structural study of alkali (Li+), alkaline-earth (Ca2+, Sr2+, Ba2+) and heavy metal (Cd2+, Pb2+, Ag+) cation-exchanged natrolites journal, November 2011

Rietveld refinement of Debye–Scherrer synchrotron X-ray data from Al 2 O 3 journal, April 1987

A profile refinement method for nuclear and magnetic structures journal, June 1969

Employing an Unsaturated Th 4+ Site in a Porous Thorium-Organic Framework for Kr/Xe Uptake and Separation journal, April 2018

A high pressure Raman study on confined individual iodine molecules as molecular probes of structural collapse in the AlPO 4 -5 framework journal, January 2018

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New developments in micro-X-ray diffraction and X-ray absorption spectroscopy for high-pressure research at 16-BM-D at the Advanced Photon Source journal, July 2015

Employing an Unsaturated Th 4+ Site in a Porous Thorium-Organic Framework for Kr/Xe Uptake and Separation journal, April 2018

Formation of xenon-nitrogen compounds at high pressure journal, October 2016

Atypical compounds of gases, which have been called ‘noble’
journal, January 2007

Unexpected Stable Stoichiometries of Sodium Chlorides
journal, December 2013

The Chemical Imagination at Work inVery Tight Places
journal, May 2007

Pressure-induced bonding and compound formation in xenon–hydrogen solids
journal, November 2009

Reactivity of Xenon with Ice at Planetary Conditions
journal, June 2013

Mars and Earth: Origin and Abundance of Volatiles
journal, November 1977

The origin of the terrestrial noble-gas signature
journal, October 2012

Recycling of oceanic crust and sediments: the noble gas subduction barrier
journal, July 1988

Seawater subduction controls the heavy noble gas composition of the mantle
journal, May 2006

Non-stoichiometric clathrate compounds of water. Part 2.—Formation and properties of double hydrates
journal, January 1962

Crystal Structures of Encapsulates within Zeolites. 3. Xenon in Zeolite A
journal, March 1999

¹²⁹ Xe NMR study of xenon adsorbed on Y zeolites
journal, June 1982

Evidence for xenon silicates at high pressure and temperature: XE-SILICATES AT HIGH PRESSURES
journal, September 2002

Retention of Xenon in Quartz and Earth's Missing Xenon
journal, November 2005

Stability of xenon oxides at high pressures
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The sorption of krypton and xenon in zeolites at high pressures and temperatures I. Chabazite
journal, January 1972

The sorption of krypton and xenon in zeolites at high pressures and temperatures II. Comparison and analysis
journal, January 1972

Adsorption of Noble Gases on Silver-mordenite
journal, September 2003

Xenon Adsorption on Modified ETS-10
journal, February 2007

Xenon Capture on Silver-Loaded Zeolites: Characterization of Very Strong Adsorption Sites
journal, July 2013

Theoretical Study on the Interaction between Xenon and Positively Charged Silver Clusters in Gas Phase and on the (001) Chabazite Surface
journal, June 2009

Super-Hydrated Zeolites: Pressure-Induced Hydration in Natrolites
journal, July 2013

Pressure-Induced Argon Insertion into an Auxetic Small Pore Zeolite
journal, March 2010

Metal nanodots formed and supported on chabazite and chabazite-like surfaces
journal, June 2007

Formation of Ag Clusters by Electron Beam Irradiation of Ag-Zeolites
journal, January 2009

Sonochemical synthesis of silver nanoparticles in Y-zeolite substrate
journal, March 2010

Pressure-Induced Hydration and Insertion of CO ₂ into Ag-Natrolite
journal, April 2013

Preparation and properties of hydrogen form of stilbite, heulandite and clinoptilolite zeolites
journal, January 1979

The Formation of Metallic Silver in Silver-Form Zeolites
journal, August 1972

Ligand-induced disproportionation of silver(I)
journal, October 1972

Beyond fluorides: Extension of chemistry of divalent silver to oxo ligands
journal, February 2008

Electroprecipitation of Ag(II)/Ag(III) tetraphenylsulfonate porphyrin and electrocatalytic behavior of the films
journal, November 2002

Generation of nitric oxide by photolysis of silver hyponitrite in suspension induced by LMCT excitation
journal, November 2007

Synthesis, characterization and property of a mixed-valent AgI/AgII coordination polymer
journal, January 2009

ESR studies of the silver(2+) ion produced in Ag-X zeolite by .gamma.-irradiation
journal, October 1978

Xenon as a Mediator of Chemical Reactions? Case of Elusive Gold Monofluoride, AuF, and its Adduct with Xenon, XeAuF
journal, June 2008

Stable Ag(II) Coordination Complexes in the Gas Phase
journal, May 1999

Natrolite is not a "soda-stone" anymore: Structural study of alkali (Li+), alkaline-earth (Ca2+, Sr2+, Ba2+) and heavy metal (Cd2+, Pb2+, Ag+) cation-exchanged natrolites
journal, November 2011

Rietveld refinement of Debye–Scherrer synchrotron X-ray data from Al ₂ O ₃
journal, April 1987

A profile refinement method for nuclear and magnetic structures
journal, June 1969

Employing an Unsaturated Th ⁴⁺ Site in a Porous Thorium-Organic Framework for Kr/Xe Uptake and Separation
journal, April 2018

A high pressure Raman study on confined individual iodine molecules as molecular probes of structural collapse in the AlPO ₄ -5 framework
journal, January 2018

Room temperature O transfer from N ₂ O to CO mediated by the nearest Cd( i ) ions in MFI zeolite cavities
journal, January 2019

New developments in micro-X-ray diffraction and X-ray absorption spectroscopy for high-pressure research at 16-BM-D at the Advanced Photon Source
journal, July 2015

Employing an Unsaturated Th ⁴⁺ Site in a Porous Thorium-Organic Framework for Kr/Xe Uptake and Separation
journal, April 2018

Formation of xenon-nitrogen compounds at high pressure
journal, October 2016