Low-efficiency-droop c -plane InGaN/GaN light-emitting diodes through the use of thick single quantum wells and doped barriers
Abstract
Efficiency droop at high current densities is a problem for InGaN-based light-emitting diodes (LEDs), especially for conventional c-plane devices. The large internal electric fields in c-plane quantum wells (QWs) lead to an increase in the active region carrier density ( n), causing the electrical efficiency droop onset to occur at low current densities. Here, we present an approach to reduce the internal electric fields ( E int ) in c-plane QWs by placing doped p-type and n-type GaN barriers close to the QW. The reduced E int also allows a thick QW active region design, which helps to lower n to further reduce the droop. The concept of using doped barriers to control E int is explained using theory and device simulations. Following that, multiple series of thick single QW (SQW) LEDs were grown and characterized. Key parameters in the epitaxial design such as the doping levels and the relative position of the doped barriers were systematically studied and optimized. By using optimized doped barriers and a thick SQW, c-plane LEDs with a low-efficiency droop of 14% at 300 A/cm 2 [with respect to the peak external quantum efficiency (EQE)] and a high peak EQE of 49% were demonstrated.
- Authors:
-
- Materials Department, University of California, Santa Barbara, California 93106, USA
- Materials Department, University of California, Santa Barbara, California 93106, USA, Department of Electrical and Computer Engineering, University of California, Santa Barbara, California 93106, USA
- Materials Department, University of California, Santa Barbara, California 93106, USA, Laboratoire de Physique de la Matière Condensée, École Polytechnique, CNRS, Institut Polytechnique de Paris, 91120 Palaiseau, France
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1968941
- Grant/Contract Number:
- EE0008204; EE0009691; 2150283
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Name: Journal of Applied Physics Journal Volume: 133 Journal Issue: 14; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Chow, Y. C., Lynsky, C., Nakamura, S., DenBaars, S. P., Weisbuch, C., and Speck, J. S. Low-efficiency-droop c -plane InGaN/GaN light-emitting diodes through the use of thick single quantum wells and doped barriers. United States: N. p., 2023.
Web. doi:10.1063/5.0142035.
Chow, Y. C., Lynsky, C., Nakamura, S., DenBaars, S. P., Weisbuch, C., & Speck, J. S. Low-efficiency-droop c -plane InGaN/GaN light-emitting diodes through the use of thick single quantum wells and doped barriers. United States. https://doi.org/10.1063/5.0142035
Chow, Y. C., Lynsky, C., Nakamura, S., DenBaars, S. P., Weisbuch, C., and Speck, J. S. Fri .
"Low-efficiency-droop c -plane InGaN/GaN light-emitting diodes through the use of thick single quantum wells and doped barriers". United States. https://doi.org/10.1063/5.0142035.
@article{osti_1968941,
title = {Low-efficiency-droop c -plane InGaN/GaN light-emitting diodes through the use of thick single quantum wells and doped barriers},
author = {Chow, Y. C. and Lynsky, C. and Nakamura, S. and DenBaars, S. P. and Weisbuch, C. and Speck, J. S.},
abstractNote = {Efficiency droop at high current densities is a problem for InGaN-based light-emitting diodes (LEDs), especially for conventional c-plane devices. The large internal electric fields in c-plane quantum wells (QWs) lead to an increase in the active region carrier density ( n), causing the electrical efficiency droop onset to occur at low current densities. Here, we present an approach to reduce the internal electric fields ( E int ) in c-plane QWs by placing doped p-type and n-type GaN barriers close to the QW. The reduced E int also allows a thick QW active region design, which helps to lower n to further reduce the droop. The concept of using doped barriers to control E int is explained using theory and device simulations. Following that, multiple series of thick single QW (SQW) LEDs were grown and characterized. Key parameters in the epitaxial design such as the doping levels and the relative position of the doped barriers were systematically studied and optimized. By using optimized doped barriers and a thick SQW, c-plane LEDs with a low-efficiency droop of 14% at 300 A/cm 2 [with respect to the peak external quantum efficiency (EQE)] and a high peak EQE of 49% were demonstrated.},
doi = {10.1063/5.0142035},
journal = {Journal of Applied Physics},
number = 14,
volume = 133,
place = {United States},
year = {Fri Apr 14 00:00:00 EDT 2023},
month = {Fri Apr 14 00:00:00 EDT 2023}
}
https://doi.org/10.1063/5.0142035
Works referenced in this record:
Reduction of oscillator strength due to piezoelectric fields in quantum wells
journal, April 1998
- Seo Im, Jin; Kollmer, H.; Off, J.
- Physical Review B, Vol. 57, Issue 16
Effects of macroscopic polarization in III-V nitride multiple quantum wells
journal, September 1999
- Fiorentini, Vincenzo; Bernardini, Fabio; Della Sala, Fabio
- Physical Review B, Vol. 60, Issue 12
Characterization of blue-green m-plane InGaN light emitting diodes
journal, June 2009
- Lin, You-Da; Chakraborty, Arpan; Brinkley, Stuart
- Applied Physics Letters, Vol. 94, Issue 26
First-principles calculations for defects and impurities: Applications to III-nitrides
journal, April 2004
- Van de Walle, Chris G.; Neugebauer, Jörg
- Journal of Applied Physics, Vol. 95, Issue 8
Exciton localization in InGaN quantum well devices
journal, July 1998
- Chichibu, Shigefusa
- Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 16, Issue 4
High Power and High External Efficiency m -Plane InGaN Light Emitting Diodes
journal, February 2007
- Schmidt, Mathew C.; Kim, Kwang-Choong; Sato, Hitoshi
- Japanese Journal of Applied Physics, Vol. 46, Issue No. 7
Efficiency droop in nitride-based light-emitting diodes
journal, July 2010
- Piprek, Joachim
- physica status solidi (a), Vol. 207, Issue 10, p. 2217-2225
Impact of doped barriers on the recombination coefficients of c-plane InGaN/GaN single quantum well light-emitting diodes
journal, October 2022
- Chow, Y. C.; Lynsky, C.; Nakamura, S.
- Applied Physics Letters, Vol. 121, Issue 18
Polarization field screening in thick (0001) InGaN/GaN single quantum well light-emitting diodes
journal, February 2016
- Young, N. G.; Farrell, R. M.; Oh, S.
- Applied Physics Letters, Vol. 108, Issue 6
High efficiency of III-nitride micro-light-emitting diodes by sidewall passivation using atomic layer deposition
journal, August 2018
- Wong, Matthew S.; Hwang, David; Alhassan, Abdullah I.
- Optics Express, Vol. 26, Issue 16
Depletion region effects in Mg-doped GaN
journal, January 2000
- Kozodoy, Peter; DenBaars, Steven P.; Mishra, Umesh K.
- Journal of Applied Physics, Vol. 87, Issue 2
Luminescence spectra from InGaN multiquantum wells heavily doped with Si
journal, June 1998
- Deguchi, T.; Shikanai, A.; Torii, K.
- Applied Physics Letters, Vol. 72, Issue 25
The efficiency challenge of nitride light-emitting diodes for lighting: The efficiency challenge of nitride LEDs for lighting
journal, March 2015
- Weisbuch, Claude; Piccardo, Marco; Martinelli, Lucio
- physica status solidi (a), Vol. 212, Issue 5
White light emitting diodes with super-high luminous efficacy
journal, August 2010
- Narukawa, Yukio; Ichikawa, Masatsugu; Sanga, Daisuke
- Journal of Physics D: Applied Physics, Vol. 43, Issue 35
Influence of polarization fields on carrier lifetime and recombination rates in InGaN-based light-emitting diodes
journal, July 2010
- David, Aurélien; Grundmann, Michael J.
- Applied Physics Letters, Vol. 97, Issue 3
Semipolar III–nitride light-emitting diodes with negligible efficiency droop up to ∼1 W
journal, September 2016
- Oh, Sang Ho; Yonkee, Benjamin P.; Cantore, Michael
- Applied Physics Express, Vol. 9, Issue 10
Optical properties of InGaN quantum wells
journal, May 1999
- Chichibu, S. F.; Abare, A. C.; Mack, M. P.
- Materials Science and Engineering: B, Vol. 59, Issue 1-3
Polarization field effects on the electron-hole recombination dynamics in In0.2Ga0.8N/In1−xGaxN multiple quantum wells
journal, November 1997
- Buongiorno Nardelli, Marco; Rapcewicz, Krzysztof; Bernholc, J.
- Applied Physics Letters, Vol. 71, Issue 21
Quantum-Confined Stark Effect due to Piezoelectric Fields in GaInN Strained Quantum Wells
journal, April 1997
- Takeuchi, Tetsuya; Sota, Shigetoshi; Katsuragawa, Maki
- Japanese Journal of Applied Physics, Vol. 36, Issue Part 2, No. 4A
Evidence of trap-assisted Auger recombination in low radiative efficiency MBE-grown III-nitride LEDs
journal, November 2019
- Espenlaub, Andrew C.; Myers, Daniel J.; Young, Erin C.
- Journal of Applied Physics, Vol. 126, Issue 18
Beyond Quantum Efficiency Limitations Originating from the Piezoelectric Polarization in Light-Emitting Devices
journal, July 2019
- Muziol, Grzegorz; Turski, Henryk; Siekacz, Marcin
- ACS Photonics, Vol. 6, Issue 8
Efficiency droop in light-emitting diodes: Challenges and countermeasures: Efficiency droop in light-emitting diodes: Challenges and countermeasures
journal, January 2013
- Cho, Jaehee; Schubert, E. Fred; Kim, Jong Kyu
- Laser & Photonics Reviews, Vol. 7, Issue 3
Reduction of efficiency droop in c-plane InGaN/GaN light-emitting diodes using a thick single quantum well with doped barriers
journal, November 2021
- Chow, Y. C.; Lynsky, C.; Wu, F.
- Applied Physics Letters, Vol. 119, Issue 22
Compensation between radiative and Auger recombinations in III-nitrides: The scaling law of separated-wavefunction recombinations
journal, November 2019
- David, Aurelien; Young, Nathan G.; Lund, Cory
- Applied Physics Letters, Vol. 115, Issue 19
III-nitride optoelectronic devices containing wide quantum wells—unexpectedly efficient light sources
journal, December 2021
- Muziol, G.; Hajdel, M.; Siekacz, M.
- Japanese Journal of Applied Physics, Vol. 61, Issue SA
Interplay of polarization fields and Auger recombination in the efficiency droop of nitride light-emitting diodes
journal, December 2012
- Kioupakis, Emmanouil; Yan, Qimin; Van de Walle, Chris G.
- Applied Physics Letters, Vol. 101, Issue 23
Control of the Mg doping profile in III-N light-emitting diodes and its effect on the electroluminescence efficiency
journal, May 2005
- Köhler, K.; Stephan, T.; Perona, A.
- Journal of Applied Physics, Vol. 97, Issue 10
Free-carrier screening of polarization fields in wurtzite GaN/InGaN laser structures
journal, April 1999
- Della Sala, Fabio; Di Carlo, Aldo; Lugli, Paolo
- Applied Physics Letters, Vol. 74, Issue 14
Origin of defect-related photoluminescence bands in doped and nominally undoped GaN
journal, February 1999
- Kaufmann, U.; Kunzer, M.; Obloh, H.
- Physical Review B, Vol. 59, Issue 8
High-Power, Low-Efficiency-Droop Semipolar ($20\bar{2}\bar{1}$) Single-Quantum-Well Blue Light-Emitting Diodes
journal, June 2012
- Pan, Chih-Chien; Tanaka, Shinichi; Wu, Feng
- Applied Physics Express, Vol. 5, Issue 6
Toward ultimate efficiency: progress and prospects on planar and 3D nanostructured nonpolar and semipolar InGaN light-emitting diodes
journal, January 2018
- Zhao, Yuji; Fu, Houqiang; Wang, George T.
- Advances in Optics and Photonics, Vol. 10, Issue 1
High-power low-droop violet semipolar (303¯1¯) InGaN/GaN light-emitting diodes with thick active layer design
journal, October 2014
- Becerra, Daniel L.; Zhao, Yuji; Oh, Sang Ho
- Applied Physics Letters, Vol. 105, Issue 17