Reduction of efficiency droop in c-plane InGaN/GaN light-emitting diodes using a thick single quantum well with doped barriers
Abstract
We report on c-plane InGaN/GaN single quantum well (QW) light-emitting diodes (LEDs) of different well widths (3 or 9 nm) with and without doped barriers. QW barriers were doped with the aim of reducing the internal electric field (FQW) in the QW to increase the electron-hole overlap, therefore increasing the recombination rates and resulting in the reduction of the efficiency droop. We, indeed, observed, through biased photocurrent spectroscopy, a reduction in FQW with doped barriers, with FQW being in the same direction of the p-n junction field at zero bias as opposed to the junction field for LEDs without doped barriers. Even with the improvement in the ground state wavefunction overlap, the ground state transition rate remains low for thick QWs. Transitions through excited states were observed for both thick QW LEDs with and without doped barriers. Here, the thick QW LED without doped barriers displayed low external quantum efficiency (EQE), likely as a result of the carrier overflow due to the poor confinement of carriers in the excited states. On the other hand, for LEDs with doped barriers, the flatter band in the QW resulting from the lower FQW reduces the energy separation between the eigenstates, leading to bettermore »
- Authors:
-
- Univ. of California, Santa Barbara, CA (United States)
- Univ. of California, Santa Barbara, CA (United States); Ecole Polytechnique, Palaiseau (France)
- Publication Date:
- Research Org.:
- Univ. of California, Santa Barbara, CA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1834371
- Alternate Identifier(s):
- OSTI ID: 1832915
- Grant/Contract Number:
- EE0008204; 2150283
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Physics Letters
- Additional Journal Information:
- Journal Volume: 119; Journal Issue: 22; Journal ID: ISSN 0003-6951
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING; Solid-state lighting; Light-emitting diode; Nitrides; Quantum wells; Doping; Quantum efficiency; Photocurrent spectroscopy; P-N junctions; Electroluminescence; Electronic band structure
Citation Formats
Chow, Y. C., Lynsky, C., Wu, F., Nakamura, S., DenBaars, S. P., Weisbuch, C., and Speck, J. S. Reduction of efficiency droop in c-plane InGaN/GaN light-emitting diodes using a thick single quantum well with doped barriers. United States: N. p., 2021.
Web. doi:10.1063/5.0073741.
Chow, Y. C., Lynsky, C., Wu, F., Nakamura, S., DenBaars, S. P., Weisbuch, C., & Speck, J. S. Reduction of efficiency droop in c-plane InGaN/GaN light-emitting diodes using a thick single quantum well with doped barriers. United States. https://doi.org/10.1063/5.0073741
Chow, Y. C., Lynsky, C., Wu, F., Nakamura, S., DenBaars, S. P., Weisbuch, C., and Speck, J. S. Mon .
"Reduction of efficiency droop in c-plane InGaN/GaN light-emitting diodes using a thick single quantum well with doped barriers". United States. https://doi.org/10.1063/5.0073741. https://www.osti.gov/servlets/purl/1834371.
@article{osti_1834371,
title = {Reduction of efficiency droop in c-plane InGaN/GaN light-emitting diodes using a thick single quantum well with doped barriers},
author = {Chow, Y. C. and Lynsky, C. and Wu, F. and Nakamura, S. and DenBaars, S. P. and Weisbuch, C. and Speck, J. S.},
abstractNote = {We report on c-plane InGaN/GaN single quantum well (QW) light-emitting diodes (LEDs) of different well widths (3 or 9 nm) with and without doped barriers. QW barriers were doped with the aim of reducing the internal electric field (FQW) in the QW to increase the electron-hole overlap, therefore increasing the recombination rates and resulting in the reduction of the efficiency droop. We, indeed, observed, through biased photocurrent spectroscopy, a reduction in FQW with doped barriers, with FQW being in the same direction of the p-n junction field at zero bias as opposed to the junction field for LEDs without doped barriers. Even with the improvement in the ground state wavefunction overlap, the ground state transition rate remains low for thick QWs. Transitions through excited states were observed for both thick QW LEDs with and without doped barriers. Here, the thick QW LED without doped barriers displayed low external quantum efficiency (EQE), likely as a result of the carrier overflow due to the poor confinement of carriers in the excited states. On the other hand, for LEDs with doped barriers, the flatter band in the QW resulting from the lower FQW reduces the energy separation between the eigenstates, leading to better confinement of carriers in the excited states. With doped barriers, we demonstrated a low efficiency droop 9-nm-thick single QW LED with a peak EQE of 42% at 40 A/cm2 and an EQE of 36% at 400 A/cm2.},
doi = {10.1063/5.0073741},
journal = {Applied Physics Letters},
number = 22,
volume = 119,
place = {United States},
year = {Mon Nov 29 00:00:00 EST 2021},
month = {Mon Nov 29 00:00:00 EST 2021}
}
Works referenced in this record:
Effects of macroscopic polarization in III-V nitride multiple quantum wells
journal, September 1999
- Fiorentini, Vincenzo; Bernardini, Fabio; Della Sala, Fabio
- Physical Review B, Vol. 60, Issue 12
Direct measurement of hot-carrier generation in a semiconductor barrier heterostructure: Identification of the dominant mechanism for thermal droop
journal, September 2019
- Myers, Daniel J.; Gelžinytė, Kristina; Alhassan, Abdullah I.
- Physical Review B, Vol. 100, Issue 12
New developments in green LEDs: New developments in green LEDs
journal, March 2009
- Peter, Matthias; Laubsch, Ansgar; Bergbauer, Werner
- physica status solidi (a), Vol. 206, Issue 6
Characterization of blue-green m-plane InGaN light emitting diodes
journal, June 2009
- Lin, You-Da; Chakraborty, Arpan; Brinkley, Stuart
- Applied Physics Letters, Vol. 94, Issue 26
Bandgap determination based on electrical quantum efficiency
journal, July 2013
- Helmers, Henning; Karcher, Christian; Bett, Andreas W.
- Applied Physics Letters, Vol. 103, Issue 3
Exciton localization in InGaN quantum well devices
journal, July 1998
- Chichibu, Shigefusa
- Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 16, Issue 4
Localization landscape theory of disorder in semiconductors. III. Application to carrier transport and recombination in light emitting diodes
journal, April 2017
- Li, Chi-Kang; Piccardo, Marco; Lu, Li-Shuo
- Physical Review B, Vol. 95, Issue 14
Field-assisted Shockley-Read-Hall recombinations in III-nitride quantum wells
journal, December 2017
- David, Aurelien; Hurni, Christophe A.; Young, Nathan G.
- Applied Physics Letters, Vol. 111, Issue 23
Optimal number of quantum wells for blue InGaN/GaN light-emitting diodes
journal, June 2012
- Xia, Chang Sheng; Simon Li, Z. M.; Li, Z. Q.
- Applied Physics Letters, Vol. 100, Issue 26
Localization landscape theory of disorder in semiconductors. II. Urbach tails of disordered quantum well layers
journal, April 2017
- Piccardo, Marco; Li, Chi-Kang; Wu, Yuh-Renn
- Physical Review B, Vol. 95, Issue 14
Polarization field screening in thick (0001) InGaN/GaN single quantum well light-emitting diodes
journal, February 2016
- Young, N. G.; Farrell, R. M.; Oh, S.
- Applied Physics Letters, Vol. 108, Issue 6
Luminescence spectra from InGaN multiquantum wells heavily doped with Si
journal, June 1998
- Deguchi, T.; Shikanai, A.; Torii, K.
- Applied Physics Letters, Vol. 72, Issue 25
The efficiency challenge of nitride light-emitting diodes for lighting: The efficiency challenge of nitride LEDs for lighting
journal, March 2015
- Weisbuch, Claude; Piccardo, Marco; Martinelli, Lucio
- physica status solidi (a), Vol. 212, Issue 5
Influence of polarization fields on carrier lifetime and recombination rates in InGaN-based light-emitting diodes
journal, July 2010
- David, Aurélien; Grundmann, Michael J.
- Applied Physics Letters, Vol. 97, Issue 3
Color shift reduction of a multi-domain IPS-LCD using RGB-LED backlight
journal, January 2006
- Lu, Ruibo; Hong, Qi; Ge, Zhibing
- Optics Express, Vol. 14, Issue 13
Semipolar III–nitride light-emitting diodes with negligible efficiency droop up to ∼1 W
journal, September 2016
- Oh, Sang Ho; Yonkee, Benjamin P.; Cantore, Michael
- Applied Physics Express, Vol. 9, Issue 10
Quantum-Confined Stark Effect due to Piezoelectric Fields in GaInN Strained Quantum Wells
journal, April 1997
- Takeuchi, Tetsuya; Sota, Shigetoshi; Katsuragawa, Maki
- Japanese Journal of Applied Physics, Vol. 36, Issue Part 2, No. 4A
Beyond Quantum Efficiency Limitations Originating from the Piezoelectric Polarization in Light-Emitting Devices
journal, July 2019
- Muziol, Grzegorz; Turski, Henryk; Siekacz, Marcin
- ACS Photonics, Vol. 6, Issue 8
InGaN light-emitting diodes: Efficiency-limiting processes at high injection
journal, September 2013
- Avrutin, Vitaliy; Hafiz, Shopan din Ahmad; Zhang, Fan
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 31, Issue 5
Efficiency droop in light-emitting diodes: Challenges and countermeasures: Efficiency droop in light-emitting diodes: Challenges and countermeasures
journal, January 2013
- Cho, Jaehee; Schubert, E. Fred; Kim, Jong Kyu
- Laser & Photonics Reviews, Vol. 7, Issue 3
Compensation between radiative and Auger recombinations in III-nitrides: The scaling law of separated-wavefunction recombinations
journal, November 2019
- David, Aurelien; Young, Nathan G.; Lund, Cory
- Applied Physics Letters, Vol. 115, Issue 19
Carrier distribution in (0001)InGaN∕GaN multiple quantum well light-emitting diodes
journal, February 2008
- David, Aurélien; Grundmann, Michael J.; Kaeding, John F.
- Applied Physics Letters, Vol. 92, Issue 5
Interplay of polarization fields and Auger recombination in the efficiency droop of nitride light-emitting diodes
journal, December 2012
- Kioupakis, Emmanouil; Yan, Qimin; Van de Walle, Chris G.
- Applied Physics Letters, Vol. 101, Issue 23
Spontaneous polarization and piezoelectric field in quantum wells: Impact on the optical spectra
journal, January 2000
- Cingolani, R.; Botchkarev, A.; Tang, H.
- Physical Review B, Vol. 61, Issue 4
Blue-emitting InGaN–GaN double-heterostructure light-emitting diodes reaching maximum quantum efficiency above 200A∕cm2
journal, December 2007
- Gardner, N. F.; Müller, G. O.; Shen, Y. C.
- Applied Physics Letters, Vol. 91, Issue 24
Photocurrent spectroscopy of GaAs/ As quantum wells in an electric field
journal, March 1986
- Collins, R. T.; Klitzing, K. v.; Ploog, K.
- Physical Review B, Vol. 33, Issue 6
The influence of Al composition on point defect incorporation in AlGaN
journal, January 2012
- Henry, T. A.; Armstrong, A.; Allerman, A. A.
- Applied Physics Letters, Vol. 100, Issue 4
High-power low-droop violet semipolar (303¯1¯) InGaN/GaN light-emitting diodes with thick active layer design
journal, October 2014
- Becerra, Daniel L.; Zhao, Yuji; Oh, Sang Ho
- Applied Physics Letters, Vol. 105, Issue 17
Fully-screened polarization-induced electric fields in blue∕violet InGaN∕GaN light-emitting devices grown on bulk GaN
journal, July 2005
- Franssen, G.; Suski, T.; Perlin, P.
- Applied Physics Letters, Vol. 87, Issue 4