Building intermixed donor–acceptor architectures for water-processable organic photovoltaics
Abstract
A modified synthesis method for aqueous nanoparticle printing inks, based upon vacuum-assisted solvent removal, is reported. Poly(3-hexylthiophene):phenyl C61 butyric acid methyl ester nanoparticle inks were prepared via this modified miniemulsion method, leading to both an improvement in photoactive layer morphology and a substantial reduction in the ink fabrication time. A combination of UV-visible spectroscopy, photoluminescence spectroscopy and scanning transmission X-ray microscopy measurements revealed a nanoparticle morphology comprising highly intermixed donor–acceptor domains. Consistent with these measurements, dynamic mechanical thermal analysis of the nanoparticles showed a glass transition temperature (Tg) of 104 °C, rather than a pure polymer phase or pure fullerene phase Tg. Together the spectroscopy, microscopy and thermomechanical data indicate that rapid solvent removal generates a more blended nanoparticle morphology. As such, this study highlights a new experimental lever for optimising nanostructure in the photoactive layer of nanoparticulate organic photovoltaic devices by enabling highly intermixed donor–acceptor architectures to be built from customised nanoparticulate inks.
- Authors:
-
[1];
[2];
[4];
[5];
[3];
- Univ. of Newcastle, Callaghan, NSW (Australia). Centre for Organic Electronics
- Flinders Univ., Adelaide, SA (Australia). Flinders Inst. for Nanoscale Science and Technology; Univ. of Bordeaux (France). Lab. de Chimie des Polymères Organiques (LCPO)
- Flinders Univ., Adelaide, SA (Australia). Flinders Inst. for Nanoscale Science and Technology
- Univ. of Newcastle, Callaghan, NSW (Australia). Centre for Organic Electronics; CSIRO Energy Centre, Mayfield West, NSW (Australia)
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)
- Publication Date:
- Research Org.:
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); Australian Research Council (ARC)
- OSTI Identifier:
- 1603507
- Grant/Contract Number:
- AC02-05CH11231
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Chemistry Chemical Physics. PCCP
- Additional Journal Information:
- Journal Volume: 21; Journal Issue: 10; Journal ID: ISSN 1463-9076
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Nanostructure; morphology; organic photovoltaic; scanning transmission X-ray microscopy; exciton dissociation; colloidal inks; eco-friendly processing
Citation Formats
Marks, Melissa, Holmes, Natalie P., Sharma, Anirudh, Pan, Xun, Chowdhury, Riku, Barr, Matthew G., Fenn, Coralie, Griffith, Matthew J., Feron, Krishna, Kilcoyne, A. L. David, Lewis, David A., Andersson, Mats R., Belcher, Warwick J., and Dastoor, Paul C. Building intermixed donor–acceptor architectures for water-processable organic photovoltaics. United States: N. p., 2019.
Web. doi:10.1039/c8cp07137c.
Marks, Melissa, Holmes, Natalie P., Sharma, Anirudh, Pan, Xun, Chowdhury, Riku, Barr, Matthew G., Fenn, Coralie, Griffith, Matthew J., Feron, Krishna, Kilcoyne, A. L. David, Lewis, David A., Andersson, Mats R., Belcher, Warwick J., & Dastoor, Paul C. Building intermixed donor–acceptor architectures for water-processable organic photovoltaics. United States. https://doi.org/10.1039/c8cp07137c
Marks, Melissa, Holmes, Natalie P., Sharma, Anirudh, Pan, Xun, Chowdhury, Riku, Barr, Matthew G., Fenn, Coralie, Griffith, Matthew J., Feron, Krishna, Kilcoyne, A. L. David, Lewis, David A., Andersson, Mats R., Belcher, Warwick J., and Dastoor, Paul C. Tue .
"Building intermixed donor–acceptor architectures for water-processable organic photovoltaics". United States. https://doi.org/10.1039/c8cp07137c. https://www.osti.gov/servlets/purl/1603507.
@article{osti_1603507,
title = {Building intermixed donor–acceptor architectures for water-processable organic photovoltaics},
author = {Marks, Melissa and Holmes, Natalie P. and Sharma, Anirudh and Pan, Xun and Chowdhury, Riku and Barr, Matthew G. and Fenn, Coralie and Griffith, Matthew J. and Feron, Krishna and Kilcoyne, A. L. David and Lewis, David A. and Andersson, Mats R. and Belcher, Warwick J. and Dastoor, Paul C.},
abstractNote = {A modified synthesis method for aqueous nanoparticle printing inks, based upon vacuum-assisted solvent removal, is reported. Poly(3-hexylthiophene):phenyl C61 butyric acid methyl ester nanoparticle inks were prepared via this modified miniemulsion method, leading to both an improvement in photoactive layer morphology and a substantial reduction in the ink fabrication time. A combination of UV-visible spectroscopy, photoluminescence spectroscopy and scanning transmission X-ray microscopy measurements revealed a nanoparticle morphology comprising highly intermixed donor–acceptor domains. Consistent with these measurements, dynamic mechanical thermal analysis of the nanoparticles showed a glass transition temperature (Tg) of 104 °C, rather than a pure polymer phase or pure fullerene phase Tg. Together the spectroscopy, microscopy and thermomechanical data indicate that rapid solvent removal generates a more blended nanoparticle morphology. As such, this study highlights a new experimental lever for optimising nanostructure in the photoactive layer of nanoparticulate organic photovoltaic devices by enabling highly intermixed donor–acceptor architectures to be built from customised nanoparticulate inks.},
doi = {10.1039/c8cp07137c},
journal = {Physical Chemistry Chemical Physics. PCCP},
number = 10,
volume = 21,
place = {United States},
year = {Tue Feb 19 00:00:00 EST 2019},
month = {Tue Feb 19 00:00:00 EST 2019}
}
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