DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Ionic liquid versus SiO2 gated a-IGZO thin film transistors: A direct comparison

Abstract

Here, ionic liquid gated field effect transistors have been extensively studied due to their low operation voltage, ease of processing and the realization of high electric fields at low bias voltages. Here, we report ionic liquid (IL) gated thin film transistors (TFTs) based on amorphous Indium Gallium Zinc Oxide (a-IGZO) active layers and directly compare the characteristics with a standard SiO2 gated device. The transport measurements of the top IL gated device revealed the n-channel property of the IGZO thin film with a current ON/OFF ratio ~105, a promising field effect mobility of 14.20 cm2V–1s–1, and a threshold voltage of 0.5 V. Comparable measurements on the bottom SiO2 gate insulator revealed a current ON/OFF ratio >108, a field effect mobility of 13.89 cm2V–1s–1 and a threshold voltage of 2.5 V. Furthermore, temperature-dependent measurements revealed that the ionic liquid electric double layer can be “frozen-in” by cooling below the glass transition temperature with an applied electrical bias. Positive and negative freezing bias locks-in the IGZO TFT “ON” and “OFF” state, respectively, which could lead to new switching and possibly non-volatile memory applications.

Authors:
 [1];  [1];  [2];  [2];  [3];  [3];  [2];  [2]
  1. Univ. of Tennessee, Knoxville, TN (United States)
  2. Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
Sponsoring Org.:
USDOE
OSTI Identifier:
1286908
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
ECS Journal of Solid State Science and Technology
Additional Journal Information:
Journal Volume: 4; Journal Issue: 9; Journal ID: ISSN 2162-8769
Publisher:
Electrochemical Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Pudasaini, Pushpa Raj, Noh, Joo Hyon, Wong, Anthony T., Haglund, Amanda V., Dai, Sheng, Ward, Thomas Zac, Mandrus, David, and Rack, Philip D. Ionic liquid versus SiO2 gated a-IGZO thin film transistors: A direct comparison. United States: N. p., 2015. Web. doi:10.1149/2.0141509jss.
Pudasaini, Pushpa Raj, Noh, Joo Hyon, Wong, Anthony T., Haglund, Amanda V., Dai, Sheng, Ward, Thomas Zac, Mandrus, David, & Rack, Philip D. Ionic liquid versus SiO2 gated a-IGZO thin film transistors: A direct comparison. United States. https://doi.org/10.1149/2.0141509jss
Pudasaini, Pushpa Raj, Noh, Joo Hyon, Wong, Anthony T., Haglund, Amanda V., Dai, Sheng, Ward, Thomas Zac, Mandrus, David, and Rack, Philip D. Wed . "Ionic liquid versus SiO2 gated a-IGZO thin film transistors: A direct comparison". United States. https://doi.org/10.1149/2.0141509jss. https://www.osti.gov/servlets/purl/1286908.
@article{osti_1286908,
title = {Ionic liquid versus SiO2 gated a-IGZO thin film transistors: A direct comparison},
author = {Pudasaini, Pushpa Raj and Noh, Joo Hyon and Wong, Anthony T. and Haglund, Amanda V. and Dai, Sheng and Ward, Thomas Zac and Mandrus, David and Rack, Philip D.},
abstractNote = {Here, ionic liquid gated field effect transistors have been extensively studied due to their low operation voltage, ease of processing and the realization of high electric fields at low bias voltages. Here, we report ionic liquid (IL) gated thin film transistors (TFTs) based on amorphous Indium Gallium Zinc Oxide (a-IGZO) active layers and directly compare the characteristics with a standard SiO2 gated device. The transport measurements of the top IL gated device revealed the n-channel property of the IGZO thin film with a current ON/OFF ratio ~105, a promising field effect mobility of 14.20 cm2V–1s–1, and a threshold voltage of 0.5 V. Comparable measurements on the bottom SiO2 gate insulator revealed a current ON/OFF ratio >108, a field effect mobility of 13.89 cm2V–1s–1 and a threshold voltage of 2.5 V. Furthermore, temperature-dependent measurements revealed that the ionic liquid electric double layer can be “frozen-in” by cooling below the glass transition temperature with an applied electrical bias. Positive and negative freezing bias locks-in the IGZO TFT “ON” and “OFF” state, respectively, which could lead to new switching and possibly non-volatile memory applications.},
doi = {10.1149/2.0141509jss},
journal = {ECS Journal of Solid State Science and Technology},
number = 9,
volume = 4,
place = {United States},
year = {Wed Aug 12 00:00:00 EDT 2015},
month = {Wed Aug 12 00:00:00 EDT 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 20 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Ionic Liquids for Electrolyte-Gating of ZnO Field-Effect Transistors
journal, June 2012

  • Thiemann, S.; Sachnov, S.; Porscha, S.
  • The Journal of Physical Chemistry C, Vol. 116, Issue 25
  • DOI: 10.1021/jp3024233

Suppression of Ionic Liquid Gate-Induced Metallization of SrTiO 3 (001) by Oxygen
journal, September 2013

  • Li, Mingyang; Han, Wei; Jiang, Xin
  • Nano Letters, Vol. 13, Issue 10
  • DOI: 10.1021/nl402088f

High-mobility, low-power, and fast-switching organic field-effect transistors with ionic liquids
journal, March 2008

  • Ono, S.; Seki, S.; Hirahara, R.
  • Applied Physics Letters, Vol. 92, Issue 10
  • DOI: 10.1063/1.2898203

High-Speed, Low-Voltage, and Environmentally Stable Operation of Electrochemically Gated Zinc Oxide Nanowire Field-Effect Transistors
journal, November 2012

  • Nasr, Babak; Wang, Di; Kruk, Robert
  • Advanced Functional Materials, Vol. 23, Issue 14
  • DOI: 10.1002/adfm.201202500

Liquid-gated interface superconductivity on an atomically flat film
journal, November 2009

  • Ye, J. T.; Inoue, S.; Kobayashi, K.
  • Nature Materials, Vol. 9, Issue 2
  • DOI: 10.1038/nmat2587

Electrolyte Gate-Controlled Kondo Effect in SrTiO 3
journal, December 2011


High Mobility WSe 2 p - and n - Type Field-Effect Transistors Contacted by Highly Doped Graphene for Low-Resistance Contacts
journal, May 2014

  • Chuang, Hsun-Jen; Tan, Xuebin; Ghimire, Nirmal Jeevi
  • Nano Letters, Vol. 14, Issue 6
  • DOI: 10.1021/nl501275p

High-performance organic field-effect transistors with binary ionic liquids
journal, December 2009


High transconductance organic electrochemical transistors
journal, July 2013

  • Khodagholy, Dion; Rivnay, Jonathan; Sessolo, Michele
  • Nature Communications, Vol. 4, Issue 1
  • DOI: 10.1038/ncomms3133

Ionic liquids and catalysis: Recent progress from knowledge to applications
journal, January 2010


Transition Metal Nanoparticle Catalysis in Ionic Liquids
journal, December 2011

  • Scholten, Jackson D.; Leal, Bárbara Caroline; Dupont, Jairton
  • ACS Catalysis, Vol. 2, Issue 1
  • DOI: 10.1021/cs200525e

Ionic Liquids in Electrochemical Devices and Processes: Managing Interfacial Electrochemistry
journal, November 2007

  • MacFarlane, Douglas R.; Forsyth, Maria; Howlett, Patrick C.
  • Accounts of Chemical Research, Vol. 40, Issue 11
  • DOI: 10.1021/ar7000952

Suppression of Metal-Insulator Transition in VO2 by Electric Field-Induced Oxygen Vacancy Formation
journal, March 2013


Collective bulk carrier delocalization driven by electrostatic surface charge accumulation
journal, July 2012


Electric-field-induced superconductivity at 9.4 K in a layered transition metal disulphide MoS 2
journal, July 2012

  • Taniguchi, Kouji; Matsumoto, Akiyo; Shimotani, Hidekazu
  • Applied Physics Letters, Vol. 101, Issue 4
  • DOI: 10.1063/1.4740268

Ionic liquid gating reveals trap-filled limit mobility in low temperature amorphous zinc oxide
journal, October 2013

  • Bubel, S.; Meyer, S.; Kunze, F.
  • Applied Physics Letters, Vol. 103, Issue 15
  • DOI: 10.1063/1.4824022

Electrolyte-gated polymer thin film transistors making use of ionic liquids and ionic liquid-solvent mixtures
journal, March 2015

  • Sayago, Jonathan; Meng, Xiang; Quenneville, Francis
  • Journal of Applied Physics, Vol. 117, Issue 11
  • DOI: 10.1063/1.4913835

Solvothermal Synthesis of Gallium–Indium-Zinc-Oxide Nanoparticles for Electrolyte-Gated Transistors
journal, December 2014

  • Santos, Lídia; Nunes, Daniela; Calmeiro, Tomás
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 1
  • DOI: 10.1021/am506814t

Room-temperature fabrication of transparent flexible thin-film transistors using amorphous oxide semiconductors
journal, November 2004

  • Nomura, Kenji; Ohta, Hiromichi; Takagi, Akihiro
  • Nature, Vol. 432, Issue 7016, p. 488-492
  • DOI: 10.1038/nature03090

Stable room temperature deposited amorphous InGaZnO[sub 4] thin film transistors
journal, January 2008

  • Lim, Wantae; Kim, S. -H.; Wang, Yu-Lin
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 26, Issue 3
  • DOI: 10.1116/1.2917075

Effects of gate insulators on the performance of a-IGZO TFT fabricated at room-temperature
journal, July 2011

  • Chun, Yoon Soo; Chang, Seongpil; Lee, Sang Yeol
  • Microelectronic Engineering, Vol. 88, Issue 7
  • DOI: 10.1016/j.mee.2011.01.076

Low-voltage InGaZnO thin-film transistors with Al2O3 gate insulator grown by atomic layer deposition
journal, April 2009

  • Kim, J. B.; Fuentes-Hernandez, C.; Potscavage, W. J.
  • Applied Physics Letters, Vol. 94, Issue 14
  • DOI: 10.1063/1.3118575

Printable ion-gel gate dielectrics for low-voltage polymer thin-film transistors on plastic
journal, October 2008

  • Cho, Jeong Ho; Lee, Jiyoul; Xia, Yu
  • Nature Materials, Vol. 7, Issue 11, p. 900-906
  • DOI: 10.1038/nmat2291

Impact of Oxygen Plasma Treatment on the Device Performance of Zinc Oxide Nanoparticle-Based Thin-Film Transistors
journal, February 2012

  • Faber, Hendrik; Hirschmann, Johannes; Klaumünzer, Martin
  • ACS Applied Materials & Interfaces, Vol. 4, Issue 3
  • DOI: 10.1021/am2018223

Printed and Electrochemically Gated, High-Mobility, Inorganic Oxide Nanoparticle FETs and Their Suitability for High-Frequency Applications
journal, July 2012

  • Dasgupta, Subho; Stoesser, Ganna; Schweikert, Nina
  • Advanced Functional Materials, Vol. 22, Issue 23
  • DOI: 10.1002/adfm.201200951

Physical Properties of Ionic Liquids: Database and Evaluation
journal, December 2006

  • Zhang, Suojiang; Sun, Ning; He, Xuezhong
  • Journal of Physical and Chemical Reference Data, Vol. 35, Issue 4, p. 1475-1517
  • DOI: 10.1063/1.2204959

Electric field gating with ionic liquids
journal, January 2007

  • Misra, Rajiv; McCarthy, Mitchell; Hebard, Arthur F.
  • Applied Physics Letters, Vol. 90, Issue 5
  • DOI: 10.1063/1.2437663

A self‐consistent analysis of temperature‐dependent field‐effect measurements in hydrogenated amorphous silicon thin‐film transistors
journal, July 1986

  • Schropp, R. E. I.; Snijder, J.; Verwey, J. F.
  • Journal of Applied Physics, Vol. 60, Issue 2
  • DOI: 10.1063/1.337407

Electronic Transport in Amorphous Silicon Films
journal, August 1970


Back-channel-oxidized a-Si:H thin-film transistors
journal, October 1998

  • Takechi, Kazushige; Hirano, Naoto; Hayama, Hiroshi
  • Journal of Applied Physics, Vol. 84, Issue 7
  • DOI: 10.1063/1.368579

“Ionic liquids-in-salt” – a promising electrolyte concept for high-temperature lithium batteries?
journal, January 2014

  • Marczewski, Maciej J.; Stanje, Bernhard; Hanzu, Ilie
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 24
  • DOI: 10.1039/c4cp01133c

Works referencing / citing this record:

Ionic Gating of Ultrathin and Leaky Ferroelectrics
journal, January 2019

  • Sharma, Yogesh; Wong, Anthony T.; Herklotz, Andreas
  • Advanced Materials Interfaces, Vol. 6, Issue 5
  • DOI: 10.1002/admi.201801723

Ultralow Voltage Driving Circuits Based on Coplanar a‐InGaZnO TFTs with Photopatternable Ionic Polymer Gate Dielectric
journal, July 2019

  • Lee, Dayoon; Kim, Yongchan; Kim, So Young
  • Advanced Electronic Materials, Vol. 5, Issue 10
  • DOI: 10.1002/aelm.201900359

Direct Inkjet Printing of Silver Source/Drain Electrodes on an Amorphous InGaZnO Layer for Thin-Film Transistors
journal, January 2017

  • Ning, Honglong; Chen, Jianqiu; Fang, Zhiqiang
  • Materials, Vol. 10, Issue 1
  • DOI: 10.3390/ma10010051

Frequency-Stable Ionic-Type Hybrid Gate Dielectrics for High Mobility Solution-Processed Metal-Oxide Thin-Film Transistors
journal, June 2017

  • Heo, Jae; Choi, Seungbeom; Jo, Jeong-Wan
  • Materials, Vol. 10, Issue 6
  • DOI: 10.3390/ma10060612