Superelasticity by reversible variant reorientation in a Ni-Mn-Ga microwire with bamboo grains
Abstract
The link between microstructure and mechanical properties is investigated for a superelastic Ni–Mn–Ga microwire with 226 μm diameter, created by solidification via the Taylor method. The wire, which consists of bamboo grains with tetragonal martensite matrix and coarse γ precipitates, exhibits fully reversible superelastic behavior up to 4% tensile strain. Upon multiple tensile load–unload cycles, reproducible stress fluctuations of ~3 MPa are measured on the loading superelastic stress plateau of ~50 MPa. During cycles at various temperatures spanning -70 to 55 °C, the plateau stress decreases from 58 to 48 MPa near linearly with increasing temperature. Based on in situ synchrotron X-ray diffraction measurements, we conclude that this superelastic behavior is due to reversible martensite variants reorientation (i.e., reversible twinning) with lattice rotation of ~13°. The reproducible stress plateau fluctuations are assigned to reversible twinning at well-defined locations along the wire. The strain recovery during unloading is attributed to reverse twinning, driven by the internal stress generated on loading between the elastic γ precipitates and the twinning martensite matrix. Lastly, the temperature dependence of the twining stress on loading is related to the change in tetragonality of the martensite, as measured by X-ray diffraction.
- Authors:
-
- Northwestern Univ., Evanston, IL (United States); Beijing Inst. of Technology, Beijing (China)
- Northwestern Univ., Evanston, IL (United States)
- Beijing Inst. of Technology, Beijing (China)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Univ. of Science and Technology, Beijing (China)
- Boise State Univ., ID (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- National Science Foundation (NSF); National Key Basic Research Program of China; USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1245144
- Alternate Identifier(s):
- OSTI ID: 1251455
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Acta Materialia
- Additional Journal Information:
- Journal Volume: 99; Journal ID: ISSN 1359-6454
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Ni2MnGa; oligocrystalline materials; shape-memory effect; size effect; superelasticity; twinning
Citation Formats
Wang, Z. L., Zheng, P., Nie, Z. H., Ren, Y., Wang, Y. D., Mullner, P., and Dunand, D. C. Superelasticity by reversible variant reorientation in a Ni-Mn-Ga microwire with bamboo grains. United States: N. p., 2015.
Web. doi:10.1016/j.actamat.2015.08.002.
Wang, Z. L., Zheng, P., Nie, Z. H., Ren, Y., Wang, Y. D., Mullner, P., & Dunand, D. C. Superelasticity by reversible variant reorientation in a Ni-Mn-Ga microwire with bamboo grains. United States. https://doi.org/10.1016/j.actamat.2015.08.002
Wang, Z. L., Zheng, P., Nie, Z. H., Ren, Y., Wang, Y. D., Mullner, P., and Dunand, D. C. Wed .
"Superelasticity by reversible variant reorientation in a Ni-Mn-Ga microwire with bamboo grains". United States. https://doi.org/10.1016/j.actamat.2015.08.002. https://www.osti.gov/servlets/purl/1245144.
@article{osti_1245144,
title = {Superelasticity by reversible variant reorientation in a Ni-Mn-Ga microwire with bamboo grains},
author = {Wang, Z. L. and Zheng, P. and Nie, Z. H. and Ren, Y. and Wang, Y. D. and Mullner, P. and Dunand, D. C.},
abstractNote = {The link between microstructure and mechanical properties is investigated for a superelastic Ni–Mn–Ga microwire with 226 μm diameter, created by solidification via the Taylor method. The wire, which consists of bamboo grains with tetragonal martensite matrix and coarse γ precipitates, exhibits fully reversible superelastic behavior up to 4% tensile strain. Upon multiple tensile load–unload cycles, reproducible stress fluctuations of ~3 MPa are measured on the loading superelastic stress plateau of ~50 MPa. During cycles at various temperatures spanning -70 to 55 °C, the plateau stress decreases from 58 to 48 MPa near linearly with increasing temperature. Based on in situ synchrotron X-ray diffraction measurements, we conclude that this superelastic behavior is due to reversible martensite variants reorientation (i.e., reversible twinning) with lattice rotation of ~13°. The reproducible stress plateau fluctuations are assigned to reversible twinning at well-defined locations along the wire. The strain recovery during unloading is attributed to reverse twinning, driven by the internal stress generated on loading between the elastic γ precipitates and the twinning martensite matrix. Lastly, the temperature dependence of the twining stress on loading is related to the change in tetragonality of the martensite, as measured by X-ray diffraction.},
doi = {10.1016/j.actamat.2015.08.002},
journal = {Acta Materialia},
number = ,
volume = 99,
place = {United States},
year = {Wed Aug 26 00:00:00 EDT 2015},
month = {Wed Aug 26 00:00:00 EDT 2015}
}
Web of Science
Works referenced in this record:
6% magnetic-field-induced strain by twin-boundary motion in ferromagnetic Ni–Mn–Ga
journal, August 2000
- Murray, S. J.; Marioni, M.; Allen, S. M.
- Applied Physics Letters, Vol. 77, Issue 6
Giant magnetic-field-induced strain in NiMnGa seven-layered martensitic phase
journal, March 2002
- Sozinov, A.; Likhachev, A. A.; Lanska, N.
- Applied Physics Letters, Vol. 80, Issue 10
12% magnetic field-induced strain in Ni-Mn-Ga-based non-modulated martensite
journal, January 2013
- Sozinov, A.; Lanska, N.; Soroka, A.
- Applied Physics Letters, Vol. 102, Issue 2
A 1% magnetostrain in polycrystalline 5M Ni–Mn–Ga
journal, January 2009
- Gaitzsch, U.; Pötschke, M.; Roth, S.
- Acta Materialia, Vol. 57, Issue 2
Size Effects on Magnetic Actuation in Ni-Mn-Ga Shape-Memory Alloys
journal, October 2010
- Dunand, David C.; Müllner, Peter
- Advanced Materials, Vol. 23, Issue 2, p. 216-232
Magnetic field-induced twin boundary motion in polycrystalline Ni–Mn–Ga fibres
journal, July 2008
- Scheerbaum, N.; Heczko, O.; Liu, J.
- New Journal of Physics, Vol. 10, Issue 7
Giant magnetic-field-induced strains in polycrystalline Ni–Mn–Ga foams
journal, September 2009
- Chmielus, M.; Zhang, X. X.; Witherspoon, C.
- Nature Materials, Vol. 8, Issue 11
Ni–Mn–Ga ferromagnetic shape memory wires
journal, June 2010
- Gómez-Polo, C.; Pérez-Landazábal, J. I.; Recarte, V.
- Journal of Applied Physics, Vol. 107, Issue 12
Magnetic Properties of Heusler-Type Microwires and Thin Films
journal, November 2014
- Zhukova, Valentina; Rodionova, Valeria; Fetisov, Leonid
- IEEE Transactions on Magnetics, Vol. 50, Issue 11
Magnetic properties and magnetocaloric effect in Heusler-type glass-coated NiMnGa microwires
journal, October 2013
- Zhukov, A.; Rodionova, V.; Ilyn, M.
- Journal of Alloys and Compounds, Vol. 575
Internal stress induced texture in Ni-Mn-Ga based glass-covered microwires
journal, September 2013
- Rodionova, V.; Ilyn, M.; Granovsky, A.
- Journal of Applied Physics, Vol. 114, Issue 12
The effect of mechanical stress on Ni63.8Mn11.1Ga25.1 microwire crystalline structure and properties
journal, December 2013
- Aronin, A. S.; Abrosimova, G. E.; Kiselev, A. P.
- Intermetallics, Vol. 43
Magnetic and transport properties of granular and Heusler-type glass-coated microwires
journal, October 2012
- Zhukov, Arcady; Garcia, Carlos; Ilyn, Maxim
- Journal of Magnetism and Magnetic Materials, Vol. 324, Issue 21
Magnetic and structural properties of Ni–Mn–Ga Heusler-type microwires
journal, October 2011
- Varga, R.; Ryba, T.; Vargova, Z.
- Scripta Materialia, Vol. 65, Issue 8
Magnetic properties of Ni-Mn-In-Co Heusler-type glass-coated microwires
journal, May 2014
- Zhukova, V.; Ipatov, M.; Granovsky, A.
- Journal of Applied Physics, Vol. 115, Issue 17
Superelasticity and shape memory effects in polycrystalline Ni–Mn–Ga microwires
journal, November 2013
- Qian, M. F.; Zhang, X. X.; Witherspoon, C.
- Journal of Alloys and Compounds, Vol. 577
Superelasticity and Serration Behavior in Small-Sized NiMnGa Alloys: Superelasticity and Serration Behavior …
journal, June 2014
- Zhang, Yong; Li, Min; Wang, Yan Dong
- Advanced Engineering Materials, Vol. 16, Issue 8
Structural, physical and damping properties of melt-spun Ni–Mn–Ga wire-epoxy composites
journal, August 2014
- Glock, S.; Zhang, X. X.; Kucza, N. J.
- Composites Part A: Applied Science and Manufacturing, Vol. 63
Martensite transformation and magnetic properties of Ni 50 Mn 25 Ga 25- x Fe x ferromagnetic microwires for application in microdevices: Martensite transformation and magnetic properties ferromagnetic of Ni 50 Mn 25 Ga 25- x Fe x MWs
journal, February 2015
- Liu, Yanfen; Zhang, Xuexi; Xing, Dawei
- physica status solidi (a), Vol. 212, Issue 4
Mechanical and magnetic behavior of oligocrystalline Ni–Mn–Ga microwires
journal, March 2015
- Zheng, Peiqi; Kucza, Nikole J.; Patrick, Charles L.
- Journal of Alloys and Compounds, Vol. 624
Magnetic-field-induced bending and straining of Ni–Mn–Ga single crystal beams with high aspect ratios
journal, August 2015
- Kucza, Nikole J.; Patrick, Charles L.; Dunand, David C.
- Acta Materialia, Vol. 95
Microstructure and twinning in epitaxial NiMnGa films
journal, July 2008
- Mahnke, Guido J.; Seibt, M.; Mayr, S. G.
- Physical Review B, Vol. 78, Issue 1
Study of Ni50+xMn25Ga25−x (x=2–11) as high-temperature shape-memory alloys
journal, March 2007
- Ma, Y.; Jiang, C.; Li, Y.
- Acta Materialia, Vol. 55, Issue 5
EXPGUI , a graphical user interface for GSAS
journal, April 2001
- Toby, Brian H.
- Journal of Applied Crystallography, Vol. 34, Issue 2
Deformation twinning in Ni2MnGa
journal, May 2012
- Pond, R. C.; Muntifering, B.; Müllner, P.
- Acta Materialia, Vol. 60, Issue 9
In situ TEM study of deformation twinning in Ni–Mn–Ga non-modulated martensite
journal, August 2013
- Zárubová, N.; Ge, Y.; Heczko, O.
- Acta Materialia, Vol. 61, Issue 14
Intra-variant substructure in Ni–Mn–Ga martensite: Conjugation boundaries
journal, June 2014
- Muntifering, B.; Pond, R. C.; Kovarik, L.
- Acta Materialia, Vol. 71
Evidence for preferential rearrangements of martensite variants by magnetic field in antiferromagnetic CoO crystal
journal, August 2009
- Nie, Z. H.; Ren, Y.; Terai, T.
- Applied Physics Letters, Vol. 95, Issue 5
A method to enhance cyclic reversibility of NiTiHf high temperature shape memory alloys
journal, June 2006
- Kockar, B.; Karaman, I.; Kim, J. I.
- Scripta Materialia, Vol. 54, Issue 12
Thermomechanical cycling, two way memory and concomitant effects in Cu-Zn-Al alloys
journal, March 1992
- Stalmans, R.; Van Humbeeck, J.; Delaey, L.
- Acta Metallurgica et Materialia, Vol. 40, Issue 3
Two-Way Shape Memory Properties of a Ni-Rich Ti–Ni Alloy Aged under Tensile-Stress
journal, January 1997
- Fukuda, Takashi; Deguchi, Akiyoshi; Kakeshita, Tomoyuki
- Materials Transactions, JIM, Vol. 38, Issue 6
Vickers Indentation Induced One-Way and Two-Way Shape Memory Effect in Austenitic NiTi: Vickers Indentation Induced One-Way and Two-Way Shape Memory Effect
journal, December 2013
- Qin, Enwei; Peter, Nicolas J.; Frensemeier, Mareike
- Advanced Engineering Materials, Vol. 16, Issue 1
Key Properties of NiMnGa Based Single Crystals Grown with the SLARE Technique
journal, July 2012
- Rolfs, Katharina; Chmielus, Markus; Guldbakke, Jan M.
- Advanced Engineering Materials, Vol. 14, Issue 8
Highly mobile twinned interface in 10M modulated Ni–Mn–Ga martensite: Analysis beyond the tetragonal approximation of lattice
journal, December 2011
- Straka, L.; Heczko, O.; Seiner, H.
- Acta Materialia, Vol. 59, Issue 20
Effects of surface damage on twinning stress and the stability of twin microstructures of magnetic shape memory alloys
journal, May 2011
- Chmielus, Markus; Witherspoon, Cassie; Ullakko, Kari
- Acta Materialia, Vol. 59, Issue 8
Thermomechanical properties of Ni–Ti shape memory wires containing nanoscale precipitates induced by stress-assisted ageing
journal, December 2014
- Cong, D. Y.; Saha, G.; Barnett, M. R.
- Acta Biomaterialia, Vol. 10, Issue 12
Twin interaction and large magnetoelasticity in Ni-Mn-Ga single crystals
journal, March 2011
- Straka, L.; Hänninen, H.; Lanska, N.
- Journal of Applied Physics, Vol. 109, Issue 6
On the role of deformation twinning in domain reorganization and grain reorientation in ferroelastic crystals
journal, July 1997
- Müllner, Peter; Kriven, Waltraud M.
- Journal of Materials Research, Vol. 12, Issue 7
Temperature stability of martensite and magnetic field induced strain in Ni–Mn–Ga
journal, April 2002
- Glavatska, N.; Mogylny, G.; Glavatskiy, I.
- Scripta Materialia, Vol. 46, Issue 8
Temperature dependence of twinning stress of Type I and Type II twins in 10M modulated Ni–Mn–Ga martensite
journal, July 2012
- Straka, L.; Soroka, A.; Seiner, H.
- Scripta Materialia, Vol. 67, Issue 1
Works referencing / citing this record:
Giant tensile superelasticity originating from two-step phase transformation in a Ni-Mn-Sn-Fe magnetic microwire
journal, September 2018
- Li, F. Q.; Qu, Y. H.; Yan, H. L.
- Applied Physics Letters, Vol. 113, Issue 11
Magnetic and structural properties of glass-coated Heusler-type microwires exhibiting martensitic transformation
journal, January 2018
- Zhukov, A.; Ipatov, M.; del Val, J. J.
- Scientific Reports, Vol. 8, Issue 1
Effect of annealing on magnetic properties of Ni–Mn–Ga glass-coated microwires
journal, May 2018
- Zhukov, Arcady; Ipatov, Mihail; del Val, Juan J.
- Journal of Materials Research, Vol. 33, Issue 15
Magnetic and structural properties of glass-coated Heusler-type microwires exhibiting martensitic transformation
journal, January 2018
- Zhukov, A.; Ipatov, M.; del Val, J. J.
- Scientific Reports, Vol. 8, Issue 1