DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Dynamic crossover in deeply cooled water confined in MCM-41 at 4 kbar and its relation to the liquid-liquid transition hypothesis

Authors:
 [1];  [1];  [1];  [2];  [3];  [1]
  1. Department of Nuclear Science and Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, USA
  2. National Institute of Standards and Technology Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA
  3. National Institute of Standards and Technology Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland 20899, USA, Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20742, USA
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1229671
Grant/Contract Number:  
FG02-90ER45429
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
The Journal of Chemical Physics
Additional Journal Information:
Journal Name: The Journal of Chemical Physics Journal Volume: 143 Journal Issue: 11; Journal ID: ISSN 0021-9606
Publisher:
American Institute of Physics
Country of Publication:
United States
Language:
English

Citation Formats

Wang, Zhe, Le, Peisi, Ito, Kanae, Leão, Juscelino B., Tyagi, Madhusudan, and Chen, Sow-Hsin. Dynamic crossover in deeply cooled water confined in MCM-41 at 4 kbar and its relation to the liquid-liquid transition hypothesis. United States: N. p., 2015. Web. doi:10.1063/1.4930855.
Wang, Zhe, Le, Peisi, Ito, Kanae, Leão, Juscelino B., Tyagi, Madhusudan, & Chen, Sow-Hsin. Dynamic crossover in deeply cooled water confined in MCM-41 at 4 kbar and its relation to the liquid-liquid transition hypothesis. United States. https://doi.org/10.1063/1.4930855
Wang, Zhe, Le, Peisi, Ito, Kanae, Leão, Juscelino B., Tyagi, Madhusudan, and Chen, Sow-Hsin. Mon . "Dynamic crossover in deeply cooled water confined in MCM-41 at 4 kbar and its relation to the liquid-liquid transition hypothesis". United States. https://doi.org/10.1063/1.4930855.
@article{osti_1229671,
title = {Dynamic crossover in deeply cooled water confined in MCM-41 at 4 kbar and its relation to the liquid-liquid transition hypothesis},
author = {Wang, Zhe and Le, Peisi and Ito, Kanae and Leão, Juscelino B. and Tyagi, Madhusudan and Chen, Sow-Hsin},
abstractNote = {},
doi = {10.1063/1.4930855},
journal = {The Journal of Chemical Physics},
number = 11,
volume = 143,
place = {United States},
year = {Mon Sep 21 00:00:00 EDT 2015},
month = {Mon Sep 21 00:00:00 EDT 2015}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1063/1.4930855

Citation Metrics:
Cited by: 22 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Density and anomalous thermal expansion of deeply cooled water confined in mesoporous silica investigated by synchrotron X-ray diffraction
journal, August 2013

  • Liu, Kao-Hsiang; Zhang, Yang; Lee, Jey-Jau
  • The Journal of Chemical Physics, Vol. 139, Issue 6
  • DOI: 10.1063/1.4817186

Suppression of the dynamic transition in surface water at low hydration levels: A study of water on rutile
journal, May 2009


Relation between the Widom line and the dynamic crossover in systems with a liquid-liquid phase transition
journal, November 2005

  • Xu, L.; Kumar, P.; Buldyrev, S. V.
  • Proceedings of the National Academy of Sciences, Vol. 102, Issue 46
  • DOI: 10.1073/pnas.0507870102

Viscosity of Several Liquid Hydrocarbons as a Function of Temperature, Pressure, and Free Volume
journal, April 1967

  • Hogenboom, David L.; Webb, Wayne; Dixon, Joseph A.
  • The Journal of Chemical Physics, Vol. 46, Issue 7
  • DOI: 10.1063/1.1841088

Temperature and Pressure Dependence of the Viscosity of the Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluorophosphate
journal, September 2005

  • Harris, Kenneth R.; Woolf, Lawrence A.; Kanakubo, Mitsuhiro
  • Journal of Chemical & Engineering Data, Vol. 50, Issue 5
  • DOI: 10.1021/je050147b

Thermodynamic determination of fragility in liquids and a fragile-to-strong liquid transition in water
journal, April 1999

  • Ito, Kaori; Moynihan, Cornelius T.; Angell, C. Austen
  • Nature, Vol. 398, Issue 6727
  • DOI: 10.1038/19042

The dynamical crossover phenomenon in bulk water, confined water and protein hydration water
journal, January 2012

  • Mallamace, Francesco; Corsaro, Carmelo; Baglioni, Piero
  • Journal of Physics: Condensed Matter, Vol. 24, Issue 6
  • DOI: 10.1088/0953-8984/24/6/064103

X‐ray and neutron scattering studies of the structure of water at a hydrophobic surface
journal, June 1996

  • Bellissent‐Funel, Marie‐Claire; Sridi‐Dorbez, Rachida; Bosio, Louis
  • The Journal of Chemical Physics, Vol. 104, Issue 24
  • DOI: 10.1063/1.471728

Neutron spin echo measurements of monolayer and capillary condensed water in MCM-41 at low temperatures
journal, January 2012


Deeply-cooled water under strong confinement: neutron scattering investigations and the liquid–liquid critical point hypothesis
journal, January 2013

  • Bertrand, Christopher E.; Zhang, Yang; Chen, Sow-Hsin
  • Phys. Chem. Chem. Phys., Vol. 15, Issue 3
  • DOI: 10.1039/C2CP43235H

Phase behaviour of metastable water
journal, November 1992

  • Poole, Peter H.; Sciortino, Francesco; Essmann, Ulrich
  • Nature, Vol. 360, Issue 6402
  • DOI: 10.1038/360324a0

Evidence of the existence of the low-density liquid phase in supercooled, confined water
journal, December 2006

  • Mallamace, F.; Broccio, M.; Corsaro, C.
  • Proceedings of the National Academy of Sciences, Vol. 104, Issue 2
  • DOI: 10.1073/pnas.0607138104

The high-flux backscattering spectrometer at the NIST Center for Neutron Research
journal, May 2003

  • Meyer, A.; Dimeo, R. M.; Gehring, P. M.
  • Review of Scientific Instruments, Vol. 74, Issue 5
  • DOI: 10.1063/1.1568557

Pressure Dependence of Fragile-to-Strong Transition and a Possible Second Critical Point in Supercooled Confined Water
journal, September 2005


Relaxation Processes in Supercooled Confined Water and Implications for Protein Dynamics
journal, June 2006


Fragile-to-strong liquid transition in deeply supercooled confined water
journal, January 2004

  • Faraone, A.; Liu, L.; Mou, C. -Y.
  • The Journal of Chemical Physics, Vol. 121, Issue 22
  • DOI: 10.1063/1.1832595

Density hysteresis of heavy water confined in a nanoporous silica matrix
journal, July 2011

  • Zhang, Y.; Faraone, A.; Kamitakahara, W. A.
  • Proceedings of the National Academy of Sciences, Vol. 108, Issue 30
  • DOI: 10.1073/pnas.1100238108

Model for single-particle dynamics in supercooled water
journal, June 1999


Boson Peak in Deeply Cooled Confined Water: A Possible Way to Explore the Existence of the Liquid-to-Liquid Transition in Water
journal, June 2014


Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures
journal, July 2014

  • Wang, Zhe; Liu, Kao-Hsiang; Harriger, Leland
  • The Journal of Chemical Physics, Vol. 141, Issue 1
  • DOI: 10.1063/1.4885844

Dynamical Transition of Protein-Hydration Water
journal, March 2010


Liquid–Liquid Phase Transition and Its Phase Diagram in Deeply-Cooled Heavy Water Confined in a Nanoporous Silica Matrix
journal, May 2015

  • Wang, Zhe; Ito, Kanae; Leão, Juscelino B.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 11
  • DOI: 10.1021/acs.jpclett.5b00827

Interplay of the Glass Transition and the Liquid-Liquid Phase Transition in Water
journal, May 2012

  • Giovambattista, Nicolas; Loerting, Thomas; Lukanov, Boris R.
  • Scientific Reports, Vol. 2, Issue 1
  • DOI: 10.1038/srep00390

Dynamic Crossover in Supercooled Confined Water: Understanding Bulk Properties through Confinement
journal, January 2010

  • Gallo, P.; Rovere, M.; Chen, S. -H.
  • The Journal of Physical Chemistry Letters, Vol. 1, Issue 4
  • DOI: 10.1021/jz9003125

Hydration-dependent dynamics of deeply cooled water under strong confinement
journal, April 2013


Quasielastic and inelastic neutron scattering investigation of fragile-to-strong crossover in deeply supercooled water confined in nanoporous silica matrices
journal, August 2006


Comment on “Pressure Dependence of Fragile-to-Strong Transition and a Possible Second Critical Point in Supercooled Confined Water”
journal, November 2006


Chen, Liu, and Faraone Reply:
journal, November 2006


The fragile-to-strong dynamic crossover transition in confined water: nuclear magnetic resonance results
journal, April 2006

  • Mallamace, F.; Broccio, M.; Corsaro, C.
  • The Journal of Chemical Physics, Vol. 124, Issue 16
  • DOI: 10.1063/1.2193159