Pressure Effect on the Boson Peak in Deeply Cooled Confined Water: Evidence of a Liquid-Liquid Transition
Abstract
We studied the boson peak in deeply cooled water confined in nanopores in order to examine the liquid-liquid transition (LLT). Below ~180 K, the boson peaks at pressures P higher than ~3.5 kbar are evidently distinct from those at low pressures by higher mean frequencies and lower heights. Moreover, the higher-P boson peaks can be rescaled to a master curve while the lower-P boson peaks can be rescaled to a different one. Moreover, these phenomena agree with the existence of two liquid phases with different densities and local structures and the associated LLT in the measured (P, T) region. Additionally, the P dependence of the librational band also agrees with the above conclusion.
- Authors:
-
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Spallation Neutron Source (SNS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1265867
- Alternate Identifier(s):
- OSTI ID: 1227692
- Grant/Contract Number:
- AC05-00OR22725; FG02-90ER45429
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Letters
- Additional Journal Information:
- Journal Volume: 115; Journal Issue: 23; Journal ID: ISSN 0031-9007
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS
Citation Formats
Wang, Zhe, Kolesnikov, Alexander I., Ito, Kanae, Podlesnyak, Andrey, and Chen, Sow-Hsin. Pressure Effect on the Boson Peak in Deeply Cooled Confined Water: Evidence of a Liquid-Liquid Transition. United States: N. p., 2015.
Web. doi:10.1103/PhysRevLett.115.235701.
Wang, Zhe, Kolesnikov, Alexander I., Ito, Kanae, Podlesnyak, Andrey, & Chen, Sow-Hsin. Pressure Effect on the Boson Peak in Deeply Cooled Confined Water: Evidence of a Liquid-Liquid Transition. United States. https://doi.org/10.1103/PhysRevLett.115.235701
Wang, Zhe, Kolesnikov, Alexander I., Ito, Kanae, Podlesnyak, Andrey, and Chen, Sow-Hsin. Thu .
"Pressure Effect on the Boson Peak in Deeply Cooled Confined Water: Evidence of a Liquid-Liquid Transition". United States. https://doi.org/10.1103/PhysRevLett.115.235701. https://www.osti.gov/servlets/purl/1265867.
@article{osti_1265867,
title = {Pressure Effect on the Boson Peak in Deeply Cooled Confined Water: Evidence of a Liquid-Liquid Transition},
author = {Wang, Zhe and Kolesnikov, Alexander I. and Ito, Kanae and Podlesnyak, Andrey and Chen, Sow-Hsin},
abstractNote = {We studied the boson peak in deeply cooled water confined in nanopores in order to examine the liquid-liquid transition (LLT). Below ~180 K, the boson peaks at pressures P higher than ~3.5 kbar are evidently distinct from those at low pressures by higher mean frequencies and lower heights. Moreover, the higher-P boson peaks can be rescaled to a master curve while the lower-P boson peaks can be rescaled to a different one. Moreover, these phenomena agree with the existence of two liquid phases with different densities and local structures and the associated LLT in the measured (P, T) region. Additionally, the P dependence of the librational band also agrees with the above conclusion.},
doi = {10.1103/PhysRevLett.115.235701},
journal = {Physical Review Letters},
number = 23,
volume = 115,
place = {United States},
year = {Thu Dec 03 00:00:00 EST 2015},
month = {Thu Dec 03 00:00:00 EST 2015}
}
Web of Science
Works referenced in this record:
Supercooled and glassy water
journal, October 2003
- Debenedetti, Pablo G.
- Journal of Physics: Condensed Matter, Vol. 15, Issue 45
Supercooled and Glassy Water
journal, June 2003
- Debenedetti, Pablo G.; Stanley, H. Eugene
- Physics Today, Vol. 56, Issue 6
Supercooled Water
journal, October 1983
- Angell, C. A.
- Annual Review of Physical Chemistry, Vol. 34, Issue 1
The relationship between liquid, supercooled and glassy water
journal, November 1998
- Mishima, Osamu; Stanley, H. Eugene
- Nature, Vol. 396, Issue 6709
‘Melting ice’ I at 77 K and 10 kbar: a new method of making amorphous solids
journal, August 1984
- Mishima, O.; Calvert, L. D.; Whalley, E.
- Nature, Vol. 310, Issue 5976
An apparently first-order transition between two amorphous phases of ice induced by pressure
journal, March 1985
- Mishima, O.; Calvert, L. D.; Whalley, E.
- Nature, Vol. 314, Issue 6006
Elastic Softening of Amorphous H2O Network prior to the hda-lda Transition in Amorphous State.
journal, January 1998
- Brazhkin, V. V.; Gromnitskaya, E. L.; Stal'gorova, O. V.
- THE REVIEW OF HIGH PRESSURE SCIENCE AND TECHNOLOGY, Vol. 7
Phase behaviour of metastable water
journal, November 1992
- Poole, Peter H.; Sciortino, Francesco; Essmann, Ulrich
- Nature, Vol. 360, Issue 6402
Liquid–liquid transition without macroscopic phase separation in a water–glycerol mixture
journal, March 2012
- Murata, Ken-ichiro; Tanaka, Hajime
- Nature Materials, Vol. 11, Issue 5
General nature of liquid–liquid transition in aqueous organic solutions
journal, November 2013
- Murata, Ken-ichiro; Tanaka, Hajime
- Nature Communications, Vol. 4, Issue 1
Application of polyamorphism in water to spontaneous crystallization of emulsified LiCl‐H2O solution
journal, October 2005
- Mishima, Osamu
- The Journal of Chemical Physics, Vol. 123, Issue 15
Phase separation in dilute LiCl–H2O solution related to the polyamorphism of liquid water
journal, June 2007
- Mishima, Osamu
- The Journal of Chemical Physics, Vol. 126, Issue 24
Experimentally proven liquid-liquid critical point of dilute glycerol-water solution at 150 K
journal, September 2014
- Suzuki, Yoshiharu; Mishima, Osamu
- The Journal of Chemical Physics, Vol. 141, Issue 9
Ultrafast X-ray probing of water structure below the homogeneous ice nucleation temperature
journal, June 2014
- Sellberg, J. A.; Huang, C.; McQueen, T. A.
- Nature, Vol. 510, Issue 7505
Pressure Dependence of Fragile-to-Strong Transition and a Possible Second Critical Point in Supercooled Confined Water
journal, September 2005
- Liu, Li; Chen, Sow-Hsin; Faraone, Antonio
- Physical Review Letters, Vol. 95, Issue 11
Evidence of the existence of the low-density liquid phase in supercooled, confined water
journal, December 2006
- Mallamace, F.; Broccio, M.; Corsaro, C.
- Proceedings of the National Academy of Sciences, Vol. 104, Issue 2
Density hysteresis of heavy water confined in a nanoporous silica matrix
journal, July 2011
- Zhang, Y.; Faraone, A.; Kamitakahara, W. A.
- Proceedings of the National Academy of Sciences, Vol. 108, Issue 30
Evidence of the existence of the high-density and low-density phases in deeply-cooled confined heavy water under high pressures
journal, July 2014
- Wang, Zhe; Liu, Kao-Hsiang; Harriger, Leland
- The Journal of Chemical Physics, Vol. 141, Issue 1
Density and anomalous thermal expansion of deeply cooled water confined in mesoporous silica investigated by synchrotron X-ray diffraction
journal, August 2013
- Liu, Kao-Hsiang; Zhang, Yang; Lee, Jey-Jau
- The Journal of Chemical Physics, Vol. 139, Issue 6
Liquid–Liquid Phase Transition and Its Phase Diagram in Deeply-Cooled Heavy Water Confined in a Nanoporous Silica Matrix
journal, May 2015
- Wang, Zhe; Ito, Kanae; Leão, Juscelino B.
- The Journal of Physical Chemistry Letters, Vol. 6, Issue 11
Experimental Evidence for a Liquid-Liquid Crossover in Deeply Cooled Confined Water
journal, November 2014
- Cupane, Antonio; Fomina, Margarita; Piazza, Irina
- Physical Review Letters, Vol. 113, Issue 21
The new cold neutron chopper spectrometer at the Spallation Neutron Source: Design and performance
journal, August 2011
- Ehlers, G.; Podlesnyak, A. A.; Niedziela, J. L.
- Review of Scientific Instruments, Vol. 82, Issue 8
DAVE: A Comprehensive Software Suite for the Reduction, Visualization, and Analysis of Low Energy Neutron Spectroscopic Data
journal, November 2009
- Azuah, Richard Tumanjong; Kneller, Larry R.; Qiu, Yiming
- Journal of Research of the National Institute of Standards and Technology, Vol. 114, Issue 6
The boson peak of deeply cooled confined water reveals the existence of a low-temperature liquid-liquid crossover
journal, November 2014
- Cupane, Antonio; Fomina, Margarita; Schirò, Giorgio
- The Journal of Chemical Physics, Vol. 141, Issue 18
Boson Peak in Deeply Cooled Confined Water: A Possible Way to Explore the Existence of the Liquid-to-Liquid Transition in Water
journal, June 2014
- Wang, Zhe; Liu, Kao-Hsiang; Le, Peisi
- Physical Review Letters, Vol. 112, Issue 23
Influence of Pressure on the Boson Peak: Stronger than Elastic Medium Transformation
journal, August 2007
- Niss, K.; Begen, B.; Frick, B.
- Physical Review Letters, Vol. 99, Issue 5
Vibrational dynamics of permanently densified GeO2 glasses: Densification-induced changes in the boson peak
journal, March 2010
- Orsingher, L.; Fontana, A.; Gilioli, E.
- The Journal of Chemical Physics, Vol. 132, Issue 12
Density dependence of the boson peak of vitreous silica
journal, July 2000
- Inamura, Y.; Arai, M.; Otomo, T.
- Physica B: Condensed Matter, Vol. 284-288
Understanding the atomic dynamics and thermodynamics of glasses: Status and outlook
journal, January 2015
- Chumakov, Aleksandr I.; Monaco, Giulio
- Journal of Non-Crystalline Solids, Vol. 407
Equivalence of the Boson Peak in Glasses to the Transverse Acoustic van Hove Singularity in Crystals
journal, May 2011
- Chumakov, A. I.; Monaco, G.; Monaco, A.
- Physical Review Letters, Vol. 106, Issue 22
Role of Disorder in the Thermodynamics and Atomic Dynamics of Glasses
journal, January 2014
- Chumakov, A. I.; Monaco, G.; Fontana, A.
- Physical Review Letters, Vol. 112, Issue 2
Effect of Densification on the Density of Vibrational States of Glasses
journal, September 2006
- Monaco, A.; Chumakov, A. I.; Monaco, G.
- Physical Review Letters, Vol. 97, Issue 13
Debye to non-Debye scaling of the Boson peak dynamics: Critical behavior and local disorder in vitreous germania
journal, November 2011
- Zanatta, M.; Baldi, G.; Caponi, S.
- The Journal of Chemical Physics, Vol. 135, Issue 17
Elastic properties of permanently densified silica: A Raman, Brillouin light, and x-ray scattering study
journal, June 2010
- Zanatta, M.; Baldi, G.; Caponi, S.
- Physical Review B, Vol. 81, Issue 21
Effects of pressure on the boson peak of tellurite glasses: Evidence of an elastic glass-to-glass transition
journal, May 2010
- Stavrou, Elissaios; Raptis, Constantine; Syassen, Karl
- Physical Review B, Vol. 81, Issue 17
Effect of temperature on the vibrational density of states in vitreous : A Raman study
journal, September 2007
- Caponi, S.; Fontana, A.; Rossi, F.
- Physical Review B, Vol. 76, Issue 9
Universal link between the boson peak and transverse phonons in glass
journal, October 2008
- Shintani, Hiroshi; Tanaka, Hajime
- Nature Materials, Vol. 7, Issue 11
The low energy excess of vibrational states in v-SiO 2 : the role of transverse dynamics
journal, November 2004
- Pilla, O.; Caponi, S.; Fontana, A.
- Journal of Physics: Condensed Matter, Vol. 16, Issue 47
Origin of the Boson Peak in Systems with Lattice Disorder
journal, February 2001
- Taraskin, S. N.; Loh, Y. L.; Natarajan, G.
- Physical Review Letters, Vol. 86, Issue 7
Harmonic Vibrational Excitations in Disordered Solids and the “Boson Peak”
journal, July 1998
- Schirmacher, Walter; Diezemann, Gregor; Ganter, Carl
- Physical Review Letters, Vol. 81, Issue 1
The Boson peak in supercooled water
journal, June 2013
- Kumar, Pradeep; Wikfeldt, K. Thor; Schlesinger, Daniel
- Scientific Reports, Vol. 3, Issue 1
Liquid-Liquid Critical Point in Heavy Water
journal, July 2000
- Mishima, Osamu
- Physical Review Letters, Vol. 85, Issue 2
Inelastic neutron scattering from amorphous solids. II. Interpretation of measurements
journal, September 1975
- Carpenter, J. M.; Pelizzari, C. A.
- Physical Review B, Vol. 12, Issue 6
Vibrational dynamics of amorphous ice structures studied by high-resolution neutron spectroscopy
journal, August 2008
- Koza, Michael Marek
- Physical Review B, Vol. 78, Issue 6
Hydrogen-Bond Spectroscopy of Water by Neutron Scattering
journal, October 1984
- Chen, Sow-Hsin; Toukan, Khaled; Loong, Chung-Keung
- Physical Review Letters, Vol. 53, Issue 14
Phase separation in confined systems
journal, December 1999
- Gelb, Lev D.; Gubbins, K. E.; Radhakrishnan, R.
- Reports on Progress in Physics, Vol. 62, Issue 12
Structures of High and Low Density Amorphous Ice by Neutron Diffraction
journal, May 2002
- Finney, J. L.; Hallbrucker, A.; Kohl, I.
- Physical Review Letters, Vol. 88, Issue 22
Phonon interpretation of the ‘boson peak’ in supercooled liquids
journal, March 2003
- Grigera, T. S.; Martín-Mayor, V.; Parisi, G.
- Nature, Vol. 422, Issue 6929
Resolution of VISION, a crystal-analyzer spectrometer
journal, June 2009
- Seeger, Philip A.; Daemen, Luke L.; Larese, John Z.
- Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 604, Issue 3
Low temperature phase properties of water confined in mesoporous silica MCM-41: Thermodynamic and neutron scattering study
journal, May 2013
- Kittaka, Shigeharu; Takahara, Shuichi; Matsumoto, Hideyuki
- The Journal of Chemical Physics, Vol. 138, Issue 20
Quasielastic and inelastic neutron scattering investigation of fragile-to-strong crossover in deeply supercooled water confined in nanoporous silica matrices
journal, August 2006
- Liu, Li; Chen, Sow-Hsin; Faraone, Antonio
- Journal of Physics: Condensed Matter, Vol. 18, Issue 36
Dynamic crossover in deeply cooled water confined in MCM-41 at 4 kbar and its relation to the liquid-liquid transition hypothesis
journal, September 2015
- Wang, Zhe; Le, Peisi; Ito, Kanae
- The Journal of Chemical Physics, Vol. 143, Issue 11
Neutron Scattering Studies of Vapor Deposited Amorphous Ice
journal, September 1997
- Kolesnikov, A. I.; Li, J-C.; Dong, S.
- Physical Review Letters, Vol. 79, Issue 10
Vibrational dynamics of amorphous ice
journal, February 1999
- Kolesnikov, A. I.; Li, Jichen; Parker, S. F.
- Physical Review B, Vol. 59, Issue 5
Neutron spectroscopic investigation of dynamics of water ice
journal, June 2002
- Li, Jichen; Kolesnikov, A. I.
- Journal of Molecular Liquids, Vol. 100, Issue 1
Works referencing / citing this record:
Two structural relaxations in protein hydration water and their dynamic crossovers
journal, July 2016
- Camisasca, G.; De Marzio, M.; Corradini, D.
- The Journal of Chemical Physics, Vol. 145, Issue 4
The cold neutron chopper spectrometer at the Spallation Neutron Source—A review of the first 8 years of operation
journal, September 2016
- Ehlers, G.; Podlesnyak, A. A.; Kolesnikov, A. I.
- Review of Scientific Instruments, Vol. 87, Issue 9
Microscopic origin of the fragile to strong crossover in supercooled water: The role of activated processes
journal, February 2017
- De Marzio, M.; Camisasca, G.; Rovere, M.
- The Journal of Chemical Physics, Vol. 146, Issue 8
Electromagnetic-radiation absorption by water
journal, December 2017
- Lunkenheimer, P.; Emmert, S.; Gulich, R.
- Physical Review E, Vol. 96, Issue 6