Title: Hyperpolarizable compounds and devices fabricated therefrom

Abstract

Substituted compounds having relatively large molecular first order hyperpolarizabilities are provided, along with devices and materials containing them. In general, the compounds bear electron-donating and electron-withdrawing chemical substituents on a polyheterocyclic core.

Inventors:

Therien, Michael J ^[1]; DiMagno, Stephen G ^[2]

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+ Show Inventor Affiliations

1. Philadelphia, PA
2. Lincoln, NE

Issue Date:

Tue Jul 21 00:00:00 EDT 1998

Research Org.:

Univ. of Pennsylvania, Philadelphia, PA (United States)

OSTI Identifier:

871723

Patent Number(s):

5783306

Assignee:

Trustees of University of Pennsylvania (Philadelphia, PA)

Patent Classifications (CPCs):

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61P - SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS

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A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61K - PREPARATIONS FOR MEDICAL, DENTAL, OR TOILET PURPOSES

A61K31/555 - containing heavy metals, e.g. hemin, hematin, melarsoprol
A61K41/0071 - {PDT with porphyrins having exactly 20 ring atoms, i.e. based on the non-expanded tetrapyrrolic ring system, e.g. bacteriochlorin, chlorin-e6, or phthalocyanines}
A61K41/0076 - {PDT with expanded
A61K47/54 - the modifying agent being an organic compound
A61K47/546 - {Porphyrines
A61K51/0485 - {Porphyrins, texaphyrins wherein the nitrogen atoms forming the central ring system complex the radioactive metal}

A - HUMAN NECESSITIES A61 - MEDICAL OR VETERINARY SCIENCE A61P - SPECIFIC THERAPEUTIC ACTIVITY OF CHEMICAL COMPOUNDS OR MEDICINAL PREPARATIONS

A61P31/04 - Antibacterial agents

B - PERFORMING OPERATIONS B01 - PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL B01J - CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY

B01J2231/42 - Catalytic cross-coupling, i.e. connection of previously not connected C-atoms or C- and X-atoms without rearrangement
B01J2531/025 - Ligands with a porphyrin ring system or analogues thereof, e.g. phthalocyanines, corroles
B01J2531/26 - Zinc
B01J2531/824 - Palladium
B01J31/0244 - {with nitrogen contained as ring member in aromatic compounds or moieties, e.g. pyridine}
B01J31/1805 - {the ligands containing nitrogen}
B01J31/1815 - {with more than one complexing nitrogen atom, e.g. bipyridyl, 2-aminopyridine}
B01J31/2409 - {with more than one complexing phosphine-P atom}

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07D - HETEROCYCLIC COMPOUNDS

C07D207/33 - with substituted hydrocarbon radicals, directly attached to ring carbon atoms
C07D207/333 - Radicals substituted by oxygen or sulfur atoms
C07D487/22 - in which the condensed system contains four or more hetero rings
C07D513/22 - in which the condensed system contains four or more hetero rings
C07D519/00 - Heterocyclic compounds containing more than one system of two or more relevant hetero rings condensed among themselves or condensed with a common carbocyclic ring system not provided for in groups C07D453/00 or C07D455/00

C - CHEMISTRY C07 - ORGANIC CHEMISTRY C07F - ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM

C07F7/0803 - {Compounds with Si-C or Si-Si linkages}
C07F7/0832 - {Other preparations}

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08F - MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS

C08F30/04 - containing a metal

C - CHEMISTRY C08 - ORGANIC MACROMOLECULAR COMPOUNDS C08G - MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS

C08G73/0611 - {with only one nitrogen atom in the ring, e.g. polypyrroles
C08G79/00 - Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon {with or without the latter elements in the main chain of the macromolecule}

C - CHEMISTRY C09 - DYES C09B - ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES {, e.g. PIGMENTS},

C09B47/00 - Porphines
C09B69/10 - Polymeric dyes
C09B69/108 - {containing a phthalocyanine dye}

G - PHYSICS G01 - MEASURING G01N - INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES

G01N27/126 - {comprising organic polymers}

G - PHYSICS G03 - PHOTOGRAPHY G03G - ELECTROGRAPHY

G03G5/0696 - {Phthalocyanines}
G03G5/076 - {having a photoconductive moiety in the polymer backbone}

Y - NEW / CROSS SECTIONAL TECHNOLOGIES Y10 - TECHNICAL SUBJECTS COVERED BY FORMER USPC Y10T - TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

Y10T428/31504 - Composite [nonstructural laminate]

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DOE Contract Number:  

FG02-94ER14494

Resource Type:

Patent

Country of Publication:

United States

Language:

English

Subject:

hyperpolarizable; compounds; devices; fabricated; therefrom; substituted; relatively; molecular; hyperpolarizabilities; provided; materials; containing; bear; electron-donating; electron-withdrawing; chemical; substituents; polyheterocyclic; core; materials containing; fabricated therefrom; compounds bear; devices fabricated; /428/327/427/514/999/