Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation
Abstract
New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or [beta]-pyrrolic positions.
- Inventors:
- Issue Date:
- OSTI Identifier:
- 6676514
- Patent Number(s):
- 5382662
- Application Number:
- PPN: US 7-997815
- Assignee:
- Sun Company, Inc., Philadelphia, PA (United States)
- DOE Contract Number:
- FC21-90MC26029
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 29 Dec 1992
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 02 PETROLEUM; ALKANES; OXIDATION; CATALYSTS; CHEMICAL COMPOSITION; CATALYTIC EFFECTS; CHROMIUM COMPOUNDS; COBALT COMPOUNDS; COPPER COMPOUNDS; IRON COMPOUNDS; MANGANESE COMPOUNDS; ORGANOMETALLIC COMPOUNDS; PORPHYRINS; RUTHENIUM COMPOUNDS; CARBOXYLIC ACIDS; CHEMICAL REACTIONS; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; REFRACTORY METAL COMPOUNDS; TRANSITION ELEMENT COMPOUNDS; 020500* - Petroleum- Products & By-Products
Citation Formats
Ellis, Jr, P E, and Lyons, J E. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation. United States: N. p., 1995.
Web.
Ellis, Jr, P E, & Lyons, J E. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation. United States.
Ellis, Jr, P E, and Lyons, J E. Tue .
"Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation". United States.
@article{osti_6676514,
title = {Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation},
author = {Ellis, Jr, P E and Lyons, J E},
abstractNote = {New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or [beta]-pyrrolic positions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Jan 17 00:00:00 EST 1995},
month = {Tue Jan 17 00:00:00 EST 1995}
}
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