Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation
Abstract
New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso- and/or [beta]-pyrrolic positions.
- Inventors:
- Issue Date:
- OSTI Identifier:
- 6298393
- Patent Number(s):
- 5212300
- Application Number:
- PPN: US 7-892107
- Assignee:
- Sun Co., Inc. (R and M), Philadelphia, PA (United States)
- DOE Contract Number:
- FC21-90MC26029
- Resource Type:
- Patent
- Resource Relation:
- Patent File Date: 2 Jun 1992
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; 02 PETROLEUM; ALKANES; OXIDATION; CATALYSTS; CHEMICAL COMPOSITION; PORPHYRINS; CATALYTIC EFFECTS; CHROMIUM COMPLEXES; COBALT COMPLEXES; COPPER COMPLEXES; CYANIDES; IRON COMPLEXES; MANGANESE COMPLEXES; ORGANOMETALLIC COMPOUNDS; RUTHENIUM COMPLEXES; CARBOXYLIC ACIDS; CHEMICAL REACTIONS; COMPLEXES; HETEROCYCLIC ACIDS; HETEROCYCLIC COMPOUNDS; HYDROCARBONS; ORGANIC ACIDS; ORGANIC COMPOUNDS; ORGANIC NITROGEN COMPOUNDS; TRANSITION ELEMENT COMPLEXES; 400201* - Chemical & Physicochemical Properties; 020400 - Petroleum- Processing
Citation Formats
Ellis, Jr, P E, and Lyons, J E. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation. United States: N. p., 1993.
Web.
Ellis, Jr, P E, & Lyons, J E. Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation. United States.
Ellis, Jr, P E, and Lyons, J E. Tue .
"Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation". United States.
@article{osti_6298393,
title = {Cyano- and polycyanometallo-porphyrins as catalysts for alkane oxidation},
author = {Ellis, Jr, P E and Lyons, J E},
abstractNote = {New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso- and/or [beta]-pyrrolic positions.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue May 18 00:00:00 EDT 1993},
month = {Tue May 18 00:00:00 EDT 1993}
}
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