Make ethylene and benzene by flash hydropyrolysis of coal in methane. [In controlled atmosphere of methane]
On rapidly reacting methane with coal at short residence times (less than or equal to 10 sec) in an entrained tubular reactor at temperatures in the range of 825/sup 0/C to 900/sup 0/C and pressures of 50 to 100 psi, significant yields of ethylene, BTX and light oils are formed. The yield of ethylene increases strongly with decreasing pressure. There appears to be no net consumption of methane. A preliminary economic analysis of a process for production of the above feedstocks from coal, recycling the methane and using the residual char as boiler fuel, indicates a very ample return on the investment. Analogous to the flash hydropyrolysis process for coal, this process has been termed flash methanolysis.
- Research Organization:
- Brookhaven National Laboratory, Upton, New York
- OSTI ID:
- 6335091
- Journal Information:
- Hydrocarbon Process.; (United States), Vol. 61:11
- Country of Publication:
- United States
- Language:
- English
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Make ethylene and benzene by flash methanolysis of coal
Reaction, process, and cost engineering for the flash hydropyrolysis (FHP) of coal
Related Subjects
BENZENE
PRODUCTION
COAL
PYROLYSIS
ETHYLENE
BOILER FUELS
CHEMICAL REACTION YIELD
CHEMICAL REACTORS
COAL GASIFICATION
COST BENEFIT ANALYSIS
FLASH HYDROPYROLYSIS PROCESS
MEDIUM PRESSURE
PRESSURE DEPENDENCE
TEMPERATURE DEPENDENCE
VERY HIGH TEMPERATURE
ALKENES
AROMATICS
CARBONACEOUS MATERIALS
CHEMICAL REACTIONS
COAL LIQUEFACTION
DECOMPOSITION
ENERGY SOURCES
FOSSIL FUELS
FUELS
GASIFICATION
HYDROCARBONS
LIQUEFACTION
MATERIALS
ORGANIC COMPOUNDS
THERMOCHEMICAL PROCESSES
YIELDS
010404* - Coal
Lignite
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010406 - Coal & Coal Products- Pyrolysis & Cracking- (-1987)